Sulfur-33 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
S-33 3/2 0.76 -6.78 2.26E-3 1.72E-5 -7.670 (NH4)2SO4

Solid-state sulfur NMR references

  1. Michael J. Jaroszewicz, Adam R. Altenhof, Robert W. Schurko, and Lucio Frydman
    Sensitivity enhancement by progressive saturation of the proton reservoir: A solid-state NMR analogue of chemical exchange saturation transfer,
    J. Am. Chem. Soc. 143, 19778-19784 (2021).
    Open access
  2. Akiko Sasaki, Luis Baquerizo Ibarra, and Stephen Wimperis
    A high-resolution natural abundance 33S MAS NMR study of the cementitious mineral ettringite,
    Phys. Chem. Chem. Phys. 19, 24082-24089 (2017).
    Open access
  3. L. A. O'Dell and C. I. Ratcliffe
    Crystal structure based design of signal enhancement schemes for solid-state NMR of insensitive half-integer quadrupolar nuclei,
    J. Phys. Chem. A 115, 747-752 (2011).
  4. L. A. O'Dell and I. L. Moudrakovski
    Testing the sensitivity limits of 33S NMR: An ultra-wideline study of elemental sulfur,
    J. Magn. Reson. 207, 345-347 (2010).
  5. I. Moudrakovski, S. Lang, S. Patchkovskii, and J. Ripmeester
    High field 33S solid state NMR and first-principles calculations in potassium sulfates,
    J. Phys. Chem. A 114, 309-316 (2010).
  6. Hans J. Jakobsen, Henrik Bildsøe, Jørgen Skibsted, Michael Brorson, Peter Gor’kov, and Zhehong Gan
    A strategy for acquisition and analysis of complex natural abundance 33S solid-state NMR spectra of a disordered tetrathio transition-metal anion,
    J. Magn. Reson. 202, 173-179 (2010).
  7. Hans J. Jakobsen, Henrik Bildsøe, Jørgen Skibsted, Michael Brorson, Bikshandarkoil R. Srinivasan, Christian Nätherd, and Wolfgang Bensch
    New opportunities in acquisition and analysis of natural abundance complex solid-state 33S MAS NMR spectra: (CH3NH3)2WS4,
    Phys. Chem. Chem. Phys. 11, 6981-6986 (2009).
  8. Andre Sutrisno, Victor V. Terskikhb, and Yining Huang
    A natural abundance 33S solid-state NMR study of layered transition metal disulfides at ultrahigh magnetic field,
    Chem. Commun.186-188 (2009).
  9. L. A. O’Dell, K. Klimm, J. C. C. Freitas, S. C. Kohn, and M. E. Smith
    33S MAS NMR of a disordered sulfur-doped silicate: Signal enhancement via RAPT, QCPMG and adiabatic pulses,
    Appl. Magn. Reson. 35, 247-259 (2008).
  10. M. R. Hansen, M. Brorson, H. Bildsoe, J. Skibsted, and H. J. Jakobsen
    Sensitivity enhancement in natural-abundance solid-state 33S MAS NMR spectroscopy employing adiabatic inversion pulses to the satellite transitions,
    J. Magn. Reson. 190, 316-326 (2008).
  11. J. B. D. de-Lacaillerie, F. Barberon, B. Bresson, P. Fonollosa, H. Zanni, V. E. Fedorov, N. G. Naumov, and Z. H. Gan
    Applicability of natural abundance 33S solid-state NMR to cement chemistry,
    Cem. Concr . Res. 36, 1781-1783 (2006).
  12. H. J. Jakobsen, A. R. Hove, H. Bildsøe, and J. Skibsted
    Satellite transitions in natural abundance solid-state 33S MAS NMR of alums - Sign change with zero-crossing of CQ in a variable temperature study,
    J. Magn. Reson. 180, 170-177 (2006).
  13. S. Couch, A. P. Howes, S. C. Kohn, and M. E. Smith
    33S solid state NMR of sulphur speciation in silicate glasses,
    Solid State Nucl. Magn. Reson. 26, 203-208 (2004).
  14. T. A. Wagler, W. A. Daunch, M. Panzner, W. J. Youngs, and P. L. Rinaldi
    Solid-state 33S MAS NMR of inorganic sulfates,
    J. Magn. Reson. 170, 336-344 (2004).
  15. Todd A. Wagler, William A. Daunch, Peter L. Rinaldi, and Allen R. Palmer
    Solid state 33S NMR of inorganic sulfides,
    J. Magn. Reson. 161, 191-197 (2003).
  16. R. Musio and O. Sciacovelli
    Detection of taurine in biological tissues by 33S NMR spectroscopy,
    J. Magn. Reson. 153, 259-261 (2002).
  17. R. A. Aitken, S. Arumugam, S. T. E. Mesher, and F. G. Riddell
    Natural abundance 33S NMR spectroscopy. The first spectra of several major compound types,
    J. Chem. Soc., Perkin Trans. 2 225-226 (2002).
  18. W. A. Daunch and P. L. Rinaldi
    Natural-abundance solid-state 33S NMR with high-speed MAS,
    J. Magn. Reson. A 123, 219-221 (1996).
  19. H. Eckert and J. P. Yesinowski
    Sulfur-33 NMR at natural abundance in solids,
    J. Am. Chem. Soc. 108, 2140-2146 (1986).
  20. P. S. Belton, I. J. Cox, and R. K. Harris
    Experimental sulfur-33 nuclear magnetic resonance spectroscopy,
    J. Chem. Soc., Faraday Trans. 2 81, 63-75 (1985).
  21. Bernard Ancian, Bernard Tiffon, and Jacques-Emile Dubois
    Molecular reorientation of CCl4 and CS2 in alkanes: a 13C and 33S NMR relaxation study,
    Chem. Phys. Lett. 65, 281-286 (1979).
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