Manganese-55 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Mn-55 5/2 100 33.0 0.18 0.18 -24.664 KMnO4

Solid-state manganese NMR references

  1. W. M. J. Franssen, E. S. Blaakmeer, and A. P. M. Kentgens
    Satellite nutation of half integer quadrupolar nuclei: Theory and practice,
    J. Magn. Reson. 300, 41-50 (2019).
    Open access
  2. Paul D. Ellis, Jesse A. Sears, Ping Yang, Michel Dupuis, Thaddeus T. Boron, Vincent L. Pecoraro, Troy A. Stich, R. David Britt, and Andrew S. Lipton
    Solid-state 55Mn NMR spectroscopy of bis(μ-oxo)dimanganese(IV) [Mn2O2(salpn)2], a model for the oxygen evolving complex in photosystem II,
    J. Am. Chem. Soc. 132, 16727-16729 (2010).
  3. S. Wurmehl, J. T. Kohlhepp, H. J. M. Swagten, B. Koopmans, M. Wojcik, B. Balke, C. G. F. Blum, V. Ksenofontov, G. H. Fecher, and C. Felser
    Effects of random distribution of Mn,Fe in Co2Mn1-xFexSi Heusler compounds probed by 55Mn nuclear magnetic resonance,
    J. Appl. Phys. 103, 7D706/1-7D706/3 (2008).
  4. K. W. Feindel, K. J. Ooms, and R. E. Wasylishen
    A solid-state 55Mn NMR spectroscopy and DFT investigation of manganese pentacarbonyl compounds,
    Phys. Chem. Chem. Phys. 9, 1226-1238 (2007).
  5. Kristopher J. Ooms, Kirk W. Feindel, Victor V. Terskikh, and Roderick E. Wasylishen
    Ultrahigh-field NMR spectroscopy of quadrupolar transition metals: 55Mn NMR of several solid manganese carbonyls,
    Inorg. Chem. 45, 8492-8499 (2006).
  6. Z. H. Han, J. I. Budnick, W. A. Hines, B. Dabrowski, and T. Maxwell
    Nuclear magnetic resonance study of the Ru/Mn valence states and magnetic interactions in SrRu0.9Mn0.1O3,
    Appl. Phys. Lett. 89, 102501/1-102501/3 (2006).
  7. M. Pattabiraman, P. Murugaraj, G. Rangarajan, C. Dimitropoulos, J. P. Ansermet, G. Papavassiliou, G. Balakrishnan, D. M. Paul, and M. R. Lees
    55Mn NMR investigation of Nd1-xSrxMnO3 (0.1 <= x <= 0.5),
    Phys. Rev. B 66, 224415/1-22415/7 (2002).
  8. R. W. Schurko, S. Wi, and L. Frydman
    Dynamic effects on the powder line shapes of half-integer quadrupolar nuclei: a solid-state NMR study of XO4- groups,
    J. Phys. Chem. A 106, 51-62 (2002).
  9. T. Kubo, T. Goto, T. Koshiba, K. Takeda, and K. Awaga
    55Mn NMR in Mn12 acetate: Hyperfine interaction and magnetic relaxation of the cluster,
    Phys. Rev. B 65, 224425/1-224425/12 (2002).
  10. S. N. Polulyakh, N. A. Sergeev, and A. A. Shemyakov
    Spectra of multiquantum echo signals from quadrupole nuclei with half-integral spin in magnetically ordered materials,
    Phys. Solid State 42, 1675-1679 (2000).
  11. G. Papavassiliou, M. Fardis, F. Milia, M. Pissas, G. Kallias, D. Niarchos, C. Dimitropoulos, and P. Scherrer
    NMR in manganese perovskites: Detection of spatially varying electron states in domain walls,
    Phys. Rev. B 58, 12237-12241 (1998).
  12. I. G. Kiliptari and V. I. Tsifrinovich
    Single-pulse nuclear spin echo in magnets,
    Phys. Rev. B 57, 11554-11564 (1998).
  13. T. Sh. Abesadze, A. M. Akhalkatsi, I. G. Kiliptari, M. G. Melikiya, and T. M. Shavishvili
    Multiquantum effects in NMR of 55Mn in an Mn1+δ system,
    Sov. Phys. JETP 69, 103-106 (1989).
  14. E. Lippmaa, A. Samoson, and M. Mägi
    High-resolution 27Al NMR of aluminosilicates,
    J. Am. Chem. Soc. 108, 1730-1735 (1986).

Related bibliography

  1. Y. X. Wei, Y. L. He, D. H. Zhang, L. Xu, S. H. Meng, Z. M. Liu, and B. L. Su
    Study of Mn incorporation into SAPO framework: Synthesis, characterization and catalysis in chloromethane conversion to light olefins,
    Microporous Mesoporous Mater. 90, 188-197 (2006).
  2. Q. Feng, H. Kanoh, and K. Ooi
    Manganese oxide porous crystals (no NMR data),
    J. Mater. Chem. 9, 319-333 (1999).
  3. José C. Vites and Mary M. Lynam
    Manganese 1993,
    Coord. Chem. Rev. 146, A167-A189 (1995).

More solid-state Mn-55 NMR references.

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