Gallium 69-71 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Ga-69 3/2 60.4 17.1 6.91E-2 4.17E-2 -24.003 Ga(NO3)3
Ga-71 3/2 39.6 10.7 0.14 5.62E-2 -30.495

Solid-state gallium NMR references

  1. Andrii Mahun, Sabina Abbrent, Jiri Czernek, Jan Rohlicek, Hana Macková, Weihua Ning, Rafał Konefał, Jiří Brus, and Libor Kobera
    Reconstructing reliable powder patterns from spikelets (Q)CPMG NMR spectra: Simplification of UWNMR crystallography analysis,
    Molecules 26, 6051/1-6051/13 (2021).
    Open access
  2. Kent J. Griffith, Fenghua Ding, and Steven Flynn
    Solid-state nuclear magnetic resonance of spin-9/2 nuclei 115In and 209Bi in functional inorganic complex oxides,
    Magn. Reson. Chem. 59, 1077-1088 (2021).
  3. Masataka Tansho, Takayuki Suehiro, and Tadashi Shimizu
    Constancy of the quadrupolar interaction product in nanocrystalline gallium nitride revealed by 71Ga MAS NMR shift distribution,
    Solid State Nucl. Magn. Reson. 97, 25-30 (2019).
  4. Henri Colaux, Daniel M. Dawson, and Sharon E. Ashbrook
    Investigating FAM-N pulses for signal enhancement in MQMAS NMR of quadrupolar nuclei,
    Solid State Nucl. Magn. Reson. 84, 89-102 (2017).
    Open access
  5. K. Seleznyova, N. A. Sergeev, M. Olszewski, P. Stępień, S. V. Yagupov, M. B. Strugatsky, and J. Kliava
    Fitting MAS NMR spectra in crystals with local disorder: Czjzek's vs. Maurer's model for 11B and 71Ga in polycrystalline gallium borate,
    Solid State Nucl. Magn. Reson. 85-86, 12-18 (2017).
  6. J. P. Yesinowski, Z. J. Berkson, S. Cadars, A. P. Purdy, and B. F. Chmelka
    Spatially correlated distributions of local metallic properties in bulk and nanocrystalline GaN,
    Phys. Rev. B 95, 235201-1-235201-9 (2017).
  7. P. J. Knijn, P. J. M. van Bentum, C. M. Fang, G. J. Bauhuis, G. A. de Wijs, and A. P. M. Kentgens
    A multi-nuclear magnetic resonance and density functional theory investigation of epitaxially grown InGaP2,
    Phys. Chem. Chem. Phys. 18, 21296-21304 (2016).
  8. Aaron J. Rossini, Michael P. Hanrahan, and Martin Thuo
    Rapid acquisition of wideline MAS solid-state NMR spectra with fast MAS, proton detection, and dipolar HMQC pulse sequences,
    Phys. Chem. Chem. Phys. 18, 25284-25295 (2016).
    Open access
  9. Flaviu R. V. Turcu, Ago Samoson, Maria Maier, Diana L. Trandafir, and Simion Simon
    High fraction of penta-coordinated aluminum and gallium in lanthanum–aluminum–gallium borates,
    J. Am. Ceram. Soc. 99, 2795-2800 (2016).
  10. J. P. Yesinowski
    Finding the true spin-lattice relaxation time for half-integral nuclei with non-zero quadrupole couplings,
    J. Magn. Reson. 252, 135-144 (2015).
  11. B. A. Hammann, Z. L. Ma, K. M. Wentz, M. K. Kamunde-Devonish, D. W. Johnson, and S. E. Hayes
    Structural study by solid-state 71Ga NMR of thin film transistor precursors,
    Dalton Trans. 44, 17652-17659 (2015).
  12. Patricia Hee, Randi Christensen, Yannick Ledemi, John E. C. Wren, Marc Dussauze, Thierry Cardinal, Evelyne Fargin, Scott Kroeker, and Younès Messaddeq
    Properties and structural investigation of gallophosphate glasses by 71Ga and 31P nuclear magnetic resonance and vibrational spectroscopies,
    J. Mater. Chem. C 2, 7906-7917 (2014).
  13. Frédéric A. Perras and David L. Bryce
    Direct characterization of metal-metal bonds between nuclei with strong quadrupolar interactions via NMR spectroscopy,
    J. Phys. Chem. Lett. 5, 4049-40547 (2014).
    Open Access
  14. Z. L. Ma, K. M. Wentz, B. A. Hammann, I-Ya Chang, M. K. Kamunde-Devonish, P. H.-Y Cheong, D. W. Johnson, V. V. Terskikh, and S. E. Hayes
    Solid-State 69Ga and 71Ga NMR study of the nanoscale inorganic cluster [Ga133-OH)62-OH)18(H2O)24](NO3)15,
    Chem. Mater. 26, 4978-4983 (2014).
  15. Fu Chen, Guibin Ma, Guy M. Bernard, Roderick E. Wasylishen, Ronald G. Cavell, Robert McDonald, and Michael J. Ferguson
    An investigation of 1:1 adducts of gallium trihalides with triarylphosphines by solid-state 69/71Ga and 31P NMR spectroscopy,
    Chem. Eur. J. 19, 2826-2838 (2013).
  16. A. Buzlukov, A. Trokiner, V. Kozhevnikov, S. Verkhovskii, A. Yakubovsky, I. Leonidov, A. Gerashenko, A. Stepanov, I. Baklanova, and A. Tankeyev
    Vacancy ordering and oxygen dynamics in oxide ion conducting La1-xSrxGa1-xMgxO3-x ceramics: 71Ga, 25Mg and 17O NMR,
    J. Solid State Chem. 184, 36-43 (2011).
  17. F. Haarmann, K. Koch, P. Jeglič, O. Pecher, H. Rosner, and Yu. Grin
    NMR spectroscopy of intermetallic compounds: An experimental and theoretical approach to local atomic arrangements in binary gallides,
    Chem. Eur. J. 17, 7560-7568 (2011).
  18. Gérard Le Caër, Bruno Bureau, and Dominique Massiot
    An extension of the Czjzek model for the distributions of electric field gradients in disordered solids and an application to NMR spectra of 71Ga in chalcogenide glasses,
    J. Phys.: Condens. Matter 22, 65402-17pp (2010).
  19. Paulus J. Knijn, P. Jan M. van Bentum, Ernst R. H. van Eck, Changming Fang, Dennis L. A. G. Grimminck, Robert A. de Groot, Remco W. A. Havenith, Martijn Marsman, W. Leo Meerts, Gilles A. de Wijs and Arno P. M. Kentgens
    A solid-state NMR and DFT study of compositional modulations in AlxGa1-xAs,
    Phys. Chem. Chem. Phys. 12, 11517-11535 (2010).
  20. R. P. Chapman and D. L. Bryce
    Application of multinuclear magnetic resonance and gauge-including projector-augmented wave calculations to the study of solid group 13 chlorides,
    Phys. Chem. Chem. Phys. 11, 6987-6998 (2009).
  21. F. Haarmann, K. Koch, D. Grüner, W. Schnelle, O. Pecher, R. Cardoso-Gil, H. Borrmann, H. Rosner, and Yu. Grin
    Electronic structure, chemical bonding, and solid-state NMR spectroscopy of the digallides of Ca, Sr, and Ba,
    Chem. Eur. J. 15, 1673-1684 (2009).
  22. Seen-Ae Chae, Oc Hee Han, and Woo-Sik Jung
    Solid-state NMR characterization of six-coordinated Ga(III) complexes with sulfur-donor ligands,
    Bull. Korean Chem. Soc. 30, 2762-2764 (2009).
    PDF file
  23. Flaviu Turcu, Simion Simon, Serban Constantinescu, Nicoleta Grecu, and Dinu Iuga
    Structural changes of piezoelectric La3Ga5SiO14 induced by paramagnetic ions revealed by 71Ga multiple quantum magic angle spinning,
    Solid State Nucl. Magn. Reson. 36, 92-95 (2009).
  24. F. Haarmann, K. Koch, D. Grüner, W. Schnelle, O. Pecher, R. Cardoso-Gil, H. Borrmann, H. Rosner, and Yu. Grin
    Electronic structure, chemical bonding, and solid-state NMR spectroscopy of the digallides of Ca, Sr, and Ba,
    Chem. Eur. J. 15, 1673-1684 (2009).
  25. Charlotte Martineau, Franck Fayon, Christophe Legein, Jean-Yves Buzaré, François Goutenoire, and Emmanuelle Suard
    Neutron powder diffraction, multinuclear, and multidimensional NMR structural investigation of Pb5Ga3F19,
    Inorg. Chem. 47, 10895-10905 (2008).
  26. Joel A. Tang, Luke A. O’Dell, Pedro M. Aguiar, Bryan E. G. Lucier, Dimitris Sakellariou, and Robert W. Schurko
    Application of static microcoils and WURST pulses for solid-state ultra-wideline NMR spectroscopy of quadrupolar nuclei ,
    Chem. Phys. Lett. 466, 227-234 (2008).
  27. Luke A. O’Dell and Robert W. Schurko
    QCPMG using adiabatic pulses for faster acquisition of ultra-wideline NMR spectra,
    Chem. Phys. Lett. 464, 97-102 (2008).
  28. M. Selvaraj and S. Kawi
    Direct synthesis and catalytic performance of ultralarge pore GaSBA-15 mesoporous molecular sieves with high gallium content,
    Catal. Today 131, 82-89 (2008).
  29. L. A. O'Dell, S. L. P. Savin, A. V. Chadwick, and M. E. Smith
    Multinuclear MAS NMR investigation of sol-gel and ball-milled nanocrystalline Ga2O3,
    Appl. Magn. Reson. 32, 527-546 (2007).
  30. C. Volkringer, T. Loiseau, G. Ferey, C. M. Morais, F. Taulelle, V. Montouillout, and D. Massiot
    Synthesis, crystal structure and 71Ga solid state NMR of a MOF-type gallium trimesate (MIL-96) with μ3-oxo bridged trinuclear units and a hexagonal 18-ring network,
    Microporous Mesoporous Mater. 105, 111-117 (2007).
  31. Y. Piskunov, K. Mikhalev, Y. Zuev, S. Verkhovskii, V. Arkhipov, I. Svyatov, I. Podgornova, A. Shestakov, V. Ogloblichev, A. Pogudin, and A. Buzlukov
    69Ga NMR in Pu1-xGax (x < 0.01) alloy,
    J. Alloys Compounds 444-445, 325-328 (2007).
  32. N. A. Mahadik, S. B. Qadri, M. V. Rao, and J. P. Yesinowski
    Depth resolved X-Ray determination of surface strain in free standing films of HVPE-grown GaN and 71Ga NMR characterization,
    Appl. Phys. A 86, 67-71 (2007).
  33. T. Vosegaard and D. Massiot
    High-resolution two-dimensional NMR spectra of half-integer-spin quadrupolar nuclei from one-dimensional projections,
    Chem. Phys. Lett. 437, 120-125 (2007).
  34. B. Schwenzer, J. Hu, Y. Wu, and U. K. Mishra
    Elucidation of the correlation between atomic-level defects in GaN nanoparticles and photoluminescence properties by NMR, XRD and TEM,
    Solid State Sci. 8, 1193-1201 (2006).
  35. W. S. Jung, O. H. Han, and S. A. Chae
    Solid-state gallium NMR characterization of cubic gallium nitride prepared by the reaction of gallium arsenide with ammonia,
    Mater. Chem. Phys. 100, 199-202 (2006).
  36. V. Montouillout, C. M. Morais, A. Douy, F. Fayon, and D. Massiot
    Toward a better description of gallo-phosphate materials in solid-state NMR: 1D and 2D correlation studies,
    Magn. Reson. Chem. 44, 770-775 (2006).
  37. J. P. Yesinowski, A. P. Purdy, H. Q. Wu, M. G. Spencer, J. Hunting, and F. J. DiSalvo
    Distributions of conduction electrons as manifested in MAS NMR of gallium nitride,
    J. Am. Chem. Soc. 128, 4952-4953 (2006).
  38. J. P. Yesinowski
    Magnetization-recovery experiments for static and MAS-NMR of I = 3/2 nuclei,
    J. Magn. Reson. 180, 147-161 (2006).
  39. J. P. Yesinowski
    69,71Ga and 14N high-field NMR of gallium nitride films,
    phys. stat. sol. (c) 2, 2399-2402 (2005).
  40. A. P. Purdy, J. P. Yesinowski, and A. T. Hanbicki
    Synthesis, solid-state NMR, and magnetic characterization of h-GaN containing magnetic ions,
    phys. stat. sol. (c) 2, 2437-2440 (2005).
  41. Weiping Gou, Yang Li, Ji Chi, Joseph H. Ross, Jr., M. Beekman, and G. S. Nolas
    NMR study of slow atomic motion in Sr8Ga16Ge30 clathrate,
    Phys. Rev. B 71, 174307/1-174307/6 (2005).
  42. T. J. Bastow, T. Mathews, and J. R. Sellar
    69,71Ga and 139La NMR characterisation of LaGaO3 and La1-xSrxGa1-xMgxO3-x,
    Solid State Ionics 175, 129-133 (2004).
  43. J. P. Yesinowski and A. P. Purdy
    Defect dynamics observed by NMR of quadrupolar nuclei in gallium nitride,
    J. Am. Chem. Soc. 126, 9166-9167 (2004).
  44. E. V. Charnaya, D. Michel, C. Tien, Y. A. Kumzerov, and D. Yaskov
    The Knight shift in liquid gallium confined within porous glasses and opals,
    J. Phys.: Condens. Matter 15, 5469-5477 (2003).
  45. T. J. Bastow and G. W. West
    Defects and hyperfine interactions in Ni-Y intermetallics (Y = Al, Ga, In, Ti) via 27Al, 47Ti, 61Ni, 69,67Ga and 115In nuclear resonance,
    J. Phys.: Condens. Matter 15, 8389-8406 (2003).
  46. H. Kato, H. Sakai, Y. Tokunaga, Y. Tokiwa, S. Ikeda, Y. Onuki, S. Kambe, and R. E. Walstedt
    Ga and Pt NMR study of UPtGa5 and UNiGa5,
    J. Phys. Soc. Jpn. 72, 2357-2363 (2003).
  47. H. Kato, H. Sakai, Y. Tokiwa, S. Kambe, R. E. Walstedt, and Y. Onuki
    Ga and Pt NMR study of UPtGa5,
    J. Phys. Chem. Solids 63, 1197-1200 (2002).
  48. S. Antonijevic, S. E. Ashbrook, R. I. Walton, and S. Wimperis
    A multiple-quantum 23Na MAS NMR study of amorphous sodium gallium silicate zeolite precursors,
    J. Mater. Chem. 12, 1469-1474 (2002).
  49. M.-C. Hsien, H.-M. Kao, and K.-H. Lii
    Synthesis, crystal structure, and solid-state NMR spectroscopy of (4-HAP)2[Ga4O(PO4)4(H2O)4] (AP = Aminopyridine), a gallophosphate containing discrete double-four-ring units,
    Chem. Mater. 13, 2584-2588 (2001).
  50. B Bureau, G Silly, J Y Buzaré, B Boulard, and C Legein
    Nuclear magnetic resonance quadrupolar parameters and short range order in disordered ionic fluorides,
    J. Phys.: Condens. Matter 12, 5775-5788 (2000).
  51. J. Takeuchi, H. Nakamura, H. Yamada, E. Kita, A. Tasaki, and T. Erata
    Quadrupolar nutation NMR on a compound semiconductor gallium-arsenide,
    Solid State Nucl. Magn. Reson. 8, 123-128 (1997).
  52. D. Massiot, V. Montouillout, F. Fayon, P. Florian, and C. Bessada
    Order-resolved sideband separation in MAS NMR of half integer quadrupolar nuclei,
    Chem. Phys. Lett. 272, 295-300 (1997).
  53. A. Breuer and D. Siebert
    69Ga NMR and 115In NMR in AB2X4 crystals,
    Ber. Bunsenges. Phys. Chem. 100, 1736-1739 (1996).
  54. L. D. Potter and Y. Wu
    NMR measurements of homonuclear indirect couplings in GaAs,
    J. Magn. Reson. A 116, 107-112 (1995).

More solid-state Ga-69/71 NMR references.

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