Boron-10 and boron-11 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
B-10 3 19.58 8.459 1.99E-2 3.90E-3 -10.746 BF3 Et2O
B-11 3/2 80.42 4.059 0.17 0.13 -32.084

Directory of solid-state B-10 and B-11 NMR references
Crystalline Powder Amorphous Powder

Solid-state boron NMR references

  1. Mingji Zheng, Shaohui Xin, Qiang Wang, Julien Trébosc, Jun Xu, Guodong Qi, Ningdong Feng, Olivier Lafon, and Feng Deng
    Through-space 11B–27Al correlation: Influence of the recoupling channel,
    Magn. Reson. Chem. 59, 1062-1076 (2021).
  2. Grégory Tricot, Lazzat Alpysbay, and Bertrand Doumert
    Solid state NMR: A powerful tool for the characterization of borophosphate glasses,
    Molecules 25, 428/1-428/15 (2020).
    Open access
  3. Yang Yu, Philipp Keil, Michael Ryan Hansen, and Mattias Edén
    Improved magnetization transfers among quadrupolar nuclei in two-dimensional homonuclear correlation NMR experiments applied to inorganic network structures,
    Molecules 25, 337/1-337/23 (2020).
    Open access
  4. Hiroki Nagashima, Aany Sofia Lilly Thankamony, Julien Trébosc, Lionel Montagne, Gwendal Kerven, Jean-Paul Amoureux, and Olivier Lafon
    Observation of proximities between spin-1/2 and quadrupolar nuclei in solids: Improved robustness to chemical shielding using adiabatic symmetry-based recoupling,
    Solid State Nucl. Magn. Reson. 94, 7-19 (2018).
  5. K. Seleznyova, N. A. Sergeev, M. Olszewski, P. Stępień, S. V. Yagupov, M. B. Strugatsky, and J. Kliava
    Fitting MAS NMR spectra in crystals with local disorder: Czjzek's vs. Maurer's model for 11B and 71Ga in polycrystalline gallium borate,
    Solid State Nucl. Magn. Reson. 85-86, 12-18 (2017).
  6. Flaviu R. V. Turcu, Ago Samoson, Maria Maier, Diana L. Trandafir, and Simion Simon
    High fraction of penta-coordinated aluminum and gallium in lanthanum–aluminum–gallium borates,
    J. Am. Ceram. Soc. 99, 2795-2800 (2016).
  7. K. Seleznyova, N. A. Sergeev, M. Olszewski, P. Stępień, S. V. Yagupov, M. B. Strugatsky, and J. Kliava
    11B MAS NMR study of Ga1-xFexBO3 mixed crystals,
    Solid State Nucl. Magn. Reson. 70, 38-42 (2015).
  8. Fenfen Wang, Rongchun Zhang, Qiang Wu, Tiehong Chen, Pingchuan Sun, and An-Chang Shi
    Probing the nanostructure, interfacial interaction, and dynamics of Chitosan-based nanoparticles by multiscale solid-state NMR,
    Appl. Mater. Interfaces 6, 21397-21407 (2014).
  9. Lars H. Jepsen, Voraksmy Ban, Kasper T. Møller, Young-Su Lee, Young Whan Cho, Flemming Besenbacher, Yaroslav Filinchuk, Jørgen Skibsted, and Torben R. Jensen
    Synthesis, crystal structure, thermal decomposition, and 11B MAS NMR characterization of Mg(BH4)2(NH3BH3)2,
    J. Phys. Chem. C 118, 12141-12153 (2014).
  10. Bing Zhou, Vladimir K. Michaelis, Scott Kroeker, John E. C. Wren, Yefeng Yao, Barbara L. Sherriffe, and Yuanming Pan
    11B and 23Na solid-state NMR and density functional theory studies of electric field gradients at boron sites in ulexite,
    CrystEngComm 15, 8739-8747 (2013).
  11. M. Sajid, G. Kehr, T. Wiegand, H. Eckert, C. Schwickert, R. Pöttgen, A. J. P. Cardenas, T. H. Warren, R. Fröhlich, C. G. Daniliuc, and G. Erker
    Non-interacting vicinal frustrated P/B-Lewis pair at the norbornane framework: Synthesis, characterization, and reactions,
    J. Am. Chem. Soc. 135, 8882-8895 (2013).
  12. Oliver L. G. Alderman, Dinu Iuga, Andrew P. Howes, Kevin J. Pike, Diane Holland, and Ray Dupree
    Spectral assignments and NMR parameter–structure relationships in borates using high-resolution 11B NMR and density functional theory,
    Phys. Chem. Chem. Phys. 15, 8208-8221 (2013).
  13. P. Kiraly
    Background-free solution boron NMR spectroscopy,
    Magn. Reson. Chem. 50, 620-626 (2012).
  14. T. Braeuniger, T. Pilz, C. Vinod Chandran, and M. Jansen
    Full differentiation and assignment of boron species in the electrolytes Li2B6O9F2 and Li2B3O4F3 by solid-state 11B NMR spectroscopy,
    J. Solid State Chem. 194, 245-249 (2012).
  15. J. W. E. Weiss and D. L. Bryce
    A solid-state 11B NMR and computational study of boron electric field gradient and chemical shift tensors in boronic acids and boronic esters,
    J. Phys. Chem. A 114, 5119-5131 (2010).
  16. C. Martineau, V. K. Michaelis, S. Schuller, and S. Kroeker
    Liquid-liquid phase separation in model nuclear waste glasses: A solid-state double resonance NMR study,
    Chem. Mater. 22, 4896-4903 (2010).
  17. A. Kuhn, E. Tobschall, and P. Heitjans
    Li ion diffusion in nanocrystalline and nanoglassy LiAlSi2O6 and LiBO2 – Structure-dynamics relations in two glass forming compounds ,
    Z. Phys. Chem. 223, 1359-1377 (2009).
  18. Takafumi Takahashi, Shunsuke Kashiwakura, Koji Kanehashi, and Tetsuya Nagasaka
    First high-resolution 11B nuclear magnetic resonance (NMR) spectra of coal fly ash by satellite-transition magic angle spinning (STMAS) NMR,
    Energy Fuels 23, 1778-1780 (2009).
  19. Luke A. O’Dell, Aaron J. Rossini, and Robert W. Schurko
    Acquisition of ultra-wideline NMR spectra from quadrupolar nuclei by frequency stepped WURST–QCPMG,
    Chem. Phys. Lett. 468, 330-335 (2009).
  20. A. J. Lussier, P. M. Aguiar, V. K. Michaelis, S. Kroeker, and F. C. Hawthorne
    The occurence of tetrahedrally coordinated Al and B in tourmaline: An 11B and 27Al MAS NMR study,
    Am. Mineral. 94, 785-792 (2009).
  21. Amanpreet Saini, Atul Khanna, Vladimir K. Michaelis, Scott Kroeker, Fernando González, and David Hernández
    Structure-property correlations in lead borate and borosilicate glasses doped with aluminium oxide,
    J. Non-Cryst. Solids 355, 2323-2332 (2009).
  22. Teresa Kurkiewicz, Michael J. Thrippleton, and Stephen Wimperis
    Second-order quadrupolar shifts as an NMR probe of fast molecular-scale dynamics in solids,
    Chem. Phys. Lett. 467, 412-416 (2009).
  23. T. F. Kemp and M. E. Smith
    QuadFit—A new cross-platform computer program for simulation of NMR line shapes from solids with distributions of interaction parameters,
    Solid State Nucl. Magn. Reson. 35, 243-252 (2009).
  24. Jerome Cuny, Sabri Messaoudi, Veronique Alonzo, Eric Furet, Jean-François Halet, Eric Le Fur, Sharon E. Ashbrook, Chris J. Pickard, Regis Gautier, and Laurent Le Polles
    DFT calculations of quadrupolar solid-state NMR properties: Some examples in solid-state inorganic chemistry,
    J. Comput. Chem. 29, 2279-2287 (2008).
  25. D. Raskar, M. T. Rinke, and H. Eckert
    The mixed-network former effect in phosphate glasses: NMR and XPS studies of the connectivity distribution in the glass system (NaPO3)1-x(B2O3)x,
    J. Phys. Chem. C 112, 12530-12539 (2008).
  26. A. S. Cattaneo, R. P. Lima, C. E. Tambelli, C. J. Magon, V. R. Mastelaro, A. Garcia, J. E. de-Souza, A. S. S. de-Camargo, C. C. de-Araujo, J. F. Schneider, J. P. Donoso, and H. Eckert
    Structural role of fluoride in the ion-conducting glass system B2O3-PbO-LiF studied by single- and double-resonance NMR,
    J. Phys. Chem. C 112, 10462-10471 (2008).
  27. M. R. Hansen, H. J. Jakobsen, and J. Skibsted
    Structural environments for boron and aluminum in alumina-boria catalysts and their precursors from 11B and 27Al single- and double-resonance MAS NMR experiments,
    J. Phys. Chem. C 112, 7210-7222 (2008).
  28. J. P. Amoureux, J. Trebosc, and G. Tricot
    Measurement of through-space connectivities between spin-1/2 and quadrupolar nuclei in solid-state NMR: the TEDOR-MQMAS method,
    Magn. Reson. Chem. 45, S187-S191 (2008).
  29. A. Quintas, T. Charpentier, O. Majérus, D. Caurant, J.-L. Dussossoy, and P. Vermaut
    NMR study of a rare-earth aluminoborosilicate glass with varying CaO-to-Na2O ratio,
    Appl. Magn. Reson. 32, 613-634 (2007).
  30. W. Stroiek, C. M. Felise, H. Eckert, B. Ewald, and R. Kniep
    Site discrimination in the crystalline borophosphate Na5B2P3O13 using advanced solid-state NMR techniques,
    Solid State Nucl. Magn. Reson. 32, 89-98 (2007).
  31. G. Guella, B. Patton, and A. Miotello
    Kinetic features of the platinum catalyzed hydrolysis of sodium borohydride from 11B NMR measurements,
    J. Phys. Chem. C 111, 18744-18750 (2007).
  32. Y. H. Sehlleier, A. Verhoeven, and M. Jansen
    NMR studies of short and intermediate range ordering of amorphous Si-B-N-C-H pre-ceramic at the pyrolysis stage of 600 °C,
    J. Mater. Chem. 17, 4316-4319 (2007).
  33. Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
    Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
    J. Non-Cryst. Solids 353, 2582-2590 (2007).
  34. D. Zielniok, C. Cramer, and H. Eckert
    Structure/property correlations in ion-conducting mixed-network former glasses: Solid-state NMR studies of the system Na2O-B2O3-P2O5,
    Chem. Mater. 19, 3162-3170 (2007).
  35. S. Indris, P. Heitjans, J. Hattendorf, W.-D. Zeitz, and T. Bredow
    Local electronic structure in MgB2 from 12B β-NMR,
    Phys. Rev. B 75, 024502/1-024502/6 (2007).
  36. T. Emmler, O. Tsetsgee, G. Buntkowsky, M. Weinmann, F. Aldinger, and K. Muller
    11B{15N} redor and 11B spin echo studies for structural characterization of Si-B-C-N precursor ceramics,
    Soft Mater. 4, 207-225 (2007).
  37. L. van-Wullen, S. Wegner, and G. Tricot
    Structural changes above the glass transition and crystallization in aluminophosphate glasses: An in situ high-temperature MAS NMR study,
    J. Phys. Chem. B 111, 7529-7534 (2007).
  38. A. C. Stowe, W. J. Shaw, J. C. Linehan, B. Schmid, and T. Autrey
    In situ solid state 11B MAS-NMR studies of the thermal decomposition of ammonia borane: mechanistic studies of the hydrogen release pathways from a solid state hydrogen storage material,
    Phys. Chem. Chem. Phys. 9, 1831-1836 (2007).
  39. D. Caurant, O. Majerus, E. Fadel, M. Lenoir, C. Gervais, and O. Pinet
    Effect of molybdenum on the structure and on the crystallization of SiO2-Na2O-CaO-B2O3 glasses,
    J. Am. Ceram. Soc. 90, 774-783 (2007).
  40. P. Florian, E. M. Anghel, and C. Bessada
    Structural description of the Na2B4O7-Na3AlF6-TiO2 system. 2. A multinuclear NMR approach of melts and solids,
    J. Phys. Chem. B 111, 968-978 (2007).
  41. Z. Szalay and J. Rohonczy
    A multinuclear NMR study of sodium-borovanadophosphate glasses,
    J. Non-Cryst. Solids 353, 295-301 (2007).
  42. D. S. Mao and G. H. Lu
    The effect of B2O3 addition on the crystallization of amorphous TiO2-ZrO2 mixed oxide,
    Solid State Chem. 180, 484-488 (2007).
  43. G. Guella, C. Zanchetta, B. Patton, and A. Miotello
    New insights on the mechanism of palladium-catalyzed hydrolysis of sodium borohydride from 11B NMR measurements,
    J. Phys. Chem. B 110, 17024-17033 (2006).
  44. S. I. Lee, K. Saito, K. Kanehashi, M. Hatakeyama, S. Mitani, S. H. Yoon, Y. Korai, and I. Mochida
    11B NMR study of the BF4- anion in activated carbons at various stages of charge of EDLCs in organic electrolyte,
    Carbon 44, 2578-2586 (2006).
  45. I. Eswaramoorthi and A. K. Dalai
    Synthesis, characterisation and catalytic performance of boron substituted SBA-15 molecular sieves,
    Microporous Mesoporous Mater. 93, 1-11 (2006).
  46. F. Muñoz, L. Montagne, L. Delevoye, A. Duran, L. Pascual, S. Cristol, and J. F. Paul
    Phosphate speciation in sodium borosilicate glasses studied by nuclear magnetic resonance,
    J. Non-Cryst. Solids 352, 2958-2968 (2006).
  47. S. Prasad, T. M. Clark, T. H. Sefzik, H. T. Kwak, Z. H. Gan, and P. J. Grandinetti
    Solid-state multinuclear magnetic resonance investigation of Pyrex,
    J. Non-Cryst. Solids 352, 2834-2840 (2006).
  48. T. I. Koranyi and J. B. Nagy
    Distribution of aluminum and boron in the periodical building units of boron-containing beta zeolites,
    J. Phys. Chem. B 110, 14728-14735 (2006).
  49. M. Jansen, J. C. Schön, and L. van-Wüllen
    The route to the structure determination of amorphous solids: A case study of the ceramic Si3B3N7,
    Angew. Chem. Int. Ed. 45, 4244-4263 (2006).
  50. S. E. Ashbrook, N. G. Dowell, I. Prokes, and S. Wimperis
    Nuclear overhauser effect (NOE) enhancement of 11B NMR spectra of borane adducts in the solid state,
    J. Am. Chem. Soc. 128, 6782-6783 (2006).
  51. Y. Kim and R. J. Kirkpatrick
    11B NMR investigation of boron interaction with mineral surfaces: Results for boehmite, silica gel and illite,
    Geochim. Cosmochim. Acta 70, 3231-3238 (2006).
  52. Y. N. Huang, Z. M. Yan, and R. Richer
    Characterization of BAPO- and SAPO-based mesoporous materials by solid-state NMR spectroscopy,
    Chem. Mater. 17, 6545-6554 (2005).
  53. J. Yang, A. M. Zheng, M. J. Zhang, Q. Luo, Y. Yue, C. H. Ye, X. Lu, and F. Deng
    Bronsted and Lewis acidity of the BF3/gamma-Al2O3 alkylation catalyst as revealed by solid-state NMR spectroscopy and DFT quantum chemical calculations,
    J. Phys. Chem. B 109, 13124-13131 (2005).
  54. J. D. Epping, H. Eckert, A. W. Imre, and H. Mehrer
    Structural manifestations of the mixed-alkali effect: NMR studies of sodium rubidium borate glasses,
    J. Non-Cryst. Solids 351, 3521-3529 (2005).
  55. J. D. Epping, W. Strojek, and H. Eckert
    Cation environments and spatial distribution in Na2O-B2O3 glasses: New results from solid state NMR,
    Phys. Chem. Chem. Phys. 7, 2384-2389 (2005).
  56. S. Elbers, W. Strojek, L. Koudelka, and H. Eckert
    Site connectivities in silver borophosphate glasses: new results from 11B{31P} and 31P{11B} rotational echo double resonance NMR spectroscopy,
    Solid State Nucl. Magn. Reson. 27, 65-76 (2005).
  57. M. Zeyer-Dusterer, L. Montagne, G. Palavit, and C. Jager
    Combined 17O NMR and 11B-31P double resonance NMR studies of sodium borophosphate glasses,
    Solid State Nucl. Magn. Reson. 27, 50-64 (2005).
  58. L. S. Du and J. F. Stebbins
    Site connectivities in sodium aluminoborate glasses: multinuclear and multiple quantum NMR results,
    Solid State Nucl. Magn. Reson. 27, 37-49 (2005).
  59. P. M. Aguiar and S. Kroeker
    Medium-range order in cesium borate glasses probed by double-resonance NMR,
    Solid State Nucl. Magn. Reson. 27, 10-15 (2005).
  60. S. J. Hwang, C. Y. Chen, and S. I. Zones
    Boron sites in borosilicate zeolites at various stages of hydration studied by solid state NMR spectroscopy,
    J. Phys. Chem. B 108, 18535-18546 (2004).
  61. L. Chen, M. J. Zhang, Y. Yue, C. H. Ye, and F. Deng
    NMR and theoretical studies of boron-modified mordenite,
    Microporous Mesoporous Mater. 76, 151-156 (2004).
  62. D. Holland, A. C. Hannon, M. E. Smith, C. E. Johnson, M. F. Thomas, and A. M. Beesley
    The role of Sb5+ in the structure of Sb2O3-B2O3 binary glasses-an NMR and Mössbauer spectroscopy study,
    Solid State Nucl. Magn. Reson. 26, 172-179 (2004).
  63. M. R. Hansen, T. Vosegaard, H. J. Jakobsen, and J. Skibsted
    11B chemical shift anisotropies in borates from 11B MAS, MQMAS, and single-crystal NMR spectroscopy,
    J. Phys. Chem. A 108, 586-594 (2004).
  64. M. Edén and L. Frydman
    Homonuclear NMR correlations between half-integer quadrupolar nuclei undergoing magic-angle spinning,
    J. Phys. Chem. B 107, 14598-14611 (2003).
  65. L. S. Du and J. F. Stebbins
    Nature of silicon-boron mixing in sodium borosilicate glasses: A high-resolution 11B and 17O NMR study,
    J. Phys. Chem. B 107, 10063-10076 (2003).
  66. M. A. M. Forgeron, D. L. Bryce, R. E. Wasylishen, and R. Rösler
    A solid-state multinuclear magnetic resonance investigation of hexamethylborazine,
    J. Phys. Chem. A 107, 726-735 (2003).
  67. J. Grinshtein and L. Frydman
    Solid state separated-local-field NMR spectroscopy on half-integer quadrupolar nuclei: Principles and applications to borane analysis,
    J. Am. Chem. Soc. 125, 7451-7460 (2003).
  68. K. Müller
    Spin relaxation in isolated and coupled non-integer quadrupolar nuclei: Theory and application for I=3/2 nuclei,
    Phys. Chem. Chem. Phys. 4, 5515-5523 (2002).
  69. L. van Wüllen and G. Schwering
    11B-MQMAS and 29Si-{11B} double-resonance NMR studies on the structure of binary B2O3-SiO2 glasses,
    Solid State Nucl. Magn. Reson. 21, 134-144 (2002).
  70. S. Wi, J. W. Logan, D. Sakellariou, J. D. Walls, and A. Pines
    Rotary resonance recoupling for half-integer quadrupolar nuclei in solid-state nuclear magnetic resonance spectroscopy,
    J. Chem. Phys. 117, 7024-7033 (2002).
  71. R. W. Schurko, I. Hung, S. Schauff, C. L. B. Macdonald, and A. H. Cowley
    Anisotropic 11B and 13C NMR interaction tensors in decamethylcyclopentadienyl boron complexes,
    J. Phys. Chem. A 106, 10096-10107 (2002).
  72. K. Kanehashi and K. Saito
    Structural analysis of boron compounds using 11B-3QMAS solid state NMR,
    J. Mol. Struct. 602-603, 105-113 (2002).
  73. J.-P. Amoureux and M. Pruski
    Theoretical and experimental assessment of single- and multiple-quantum cross-polarization in solid state NMR,
    Mol. Phys. 100, 1595-1613 (2002).
  74. S. Kroeker and J. F. Stebbins
    Three-coordinated Boron-11 chemical shifts in Borates,
    Inorg. Chem. 40, 6239-6246 (2001).
  75. D. L. Bryce, R. E. Wasylishen, and M. Gee
    Characterization of tricoordinate boron chemical shift tensors: definitive high-field solid-state NMR evidence for anisotropic boron shielding,
    J. Phys. Chem. A 105, 3633-3640 (2001).
  76. A. J. Woo, D.-Y. Han, and K. H. Yang
    11B nutation NMR study of powdered borosilicates,
    Bull. Korean Chem. Soc. 19, 519-524 (1998).
  77. G. E. Jellison, Jr. and P. J. Bray
    A determination of the distributions of quadrupole coupling constants in borate glasses using B10 NMR,
    Solid State Commun. 19, 517-520 (1976).

Related bibliography

  1. L. Regli, S. Bordiga, C. Lamberti, K. P. Lillerud, S. I. Zones, and A. Zecchinese
    Effect of boron substitution in chabazite framework: IR studies on the acidity properties and reactivity towards methanol,
    J. Phys. Chem. C 111, 2992-2999 (2007).
  2. G. Kordas
    HYSCORE spectroscopy in the borate glasses,
    J. Non-Cryst. Solids 331, 122-127 (2003).
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