Krypton-83 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Kr-83 9/2 11.55 25.9 1.88E-3 2.17E-4 3.847 Kr gas

Solid-state krypton NMR references

  1. Z. I. Cleveland and T. Meersmann
    Studying porous materials with krypton-83 NMR spectroscopy,
    Magn. Reson. Chem. 45, S12-S23 (2007).
  2. Z. I. Cleveland, K. F. Stupic, G. E. Pavlovskaya, J. E. Repine, J. B. Wooten, and T. Meersmann
    Hyperpolarized 83Kr and 129Xe NMR relaxation measurements of hydrated surfaces: Implications for materials science and pulmonary diagnostics,
    J. Am. Chem. Soc. 129, 1784-1792 (2007).
  3. Z. I. Cleveland, G. E. Pavlovskaya, K. F. Stupic, C. F. LeNoir, and T. Meersmann
    Exploring hyperpolarized 83Kr by remotely detected NMR relaxometry,
    J. Chem. Phys. 124, 44312/1-44312/7 (2006).
  4. K. F. Stupic, Z. I. Cleveland, G. E. Pavlovskaya, and T. Meersmann
    Quadrupolar relaxation of hyperpolarized krypton-83 as a probe for surfaces,
    Solid State Nucl. Magn. Reson. 29, 79-84 (2006).
  5. C. F. Horton-Garcia, G. E. Pavlovskaya, and T. Meersmann
    Introducing krypton NMR spectroscopy as a probe of void space in solids,
    J. Am. Chem. Soc. 127, 1958-1962 (2005).
  6. R. Butscher, G. Wäckerle, and M. Mehring
    Nuclear quadrupole surface interaction of gas phase 83Kr: comparison with 131Xe,
    Chem. Phys. Lett. 249, 444-450 (1996).
  7. P. Ingman, J. Jokisaari, and P. Diehl
    83Kr and 131Xe NMR of the noble gases dissolved in nematic liquid crystals. Determination of quadrupole couplings and electric field gradients,
    J. Magn. Reson. 92, 163-169 (1991).
    Abstract
  8. D. F. Cowgill and R. E. Norberg
    Pulsed NMR studies of self-diffusion and defect structure in liquid and solid krypton,
    Phys. Rev. B 13, 2773-2781 (1976).
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