Cobalt-59 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Co-59 7/2 100 42.0 0.28 0.28 -23.614 K3[Co(CN)6]

Directory of solid-state Co-59 NMR references
Single Crystal Crystalline Powder
Metallic Cluster

Solid-state cobalt NMR references

  1. Marie Duffiet , Maxime Blangero, Pierre Etienne Cabelguen, Kyeong Se Song, François Fauth, Claude Delmas, and Dany Carlier
    Probing Al distribution in LiCo0.96Al0.04O2 materials using 7Li, 27Al, and 59Co MAS NMR combined with synchrotron X-ray diffraction,
    Inorg. Chem. 59, 2890-2899 (2020).
  2. Jiahui Shen, Victor Terskikh, and Gang Wu
    A quadrupole-central-transition 59Co NMR study of cobalamins in solution,
    ChemPhysChem 20, 268-275 (2019).
  3. Andrey S. Andreev, Dmitry V. Krasnikov, Vladimir I. Zaikovskii, Svetlana V. Cherepanova, Mariya A. Kazakova, Olga B. Lapina, Vladimir L. Kuznetsov, and Jean–Baptiste d’Espinose de Lacaillerie
    Internal field 59Co NMR study of cobalt-iron nanoparticles during the activation of CoFe2/CaO catalyst for carbon nanotube synthesis,
    J. Catal. 358, 62-70 (2018).
  4. I. R. Mukhamedshin and H. Alloul
    59Co NMR evidence for charge and orbital order in the kagome like structure of Na2/3CoO2,
    Phys. Rev. B 84, 155112/20 (2011).
  5. Y. Millot, R. Hajjar, and P. P. Man
    NMR cogwheel phase cycling determination with web tools: Amplitude-modulated z-filter MQMAS sequence,
    Solid State Nucl. Magn. Reson. 38, 19-26 (2010).
  6. T. Pathmalingam, F. Habib, C. M. Widdifield, F. Loiseau, T. J. Burchell, S. I. Gorelsky, A. M. Beauchemin, D. L. Bryce, and M. Murugesu
    Combining oximes with azides to create a novel 1D chain [NaCoIII2] system: synthesis, structure, and solid-state NMR,
    Dalton Trans. 39, 1504-1510 (2010).
  7. Luke A. O’Dell, Aaron J. Rossini, and Robert W. Schurko
    Acquisition of ultra-wideline NMR spectra from quadrupolar nuclei by frequency stepped WURST–QCPMG,
    Chem. Phys. Lett. 468, 330-335 (2009).
  8. Kristopher J. Ooms, Guy M. Bernard, Anders Kadziola, Pauli Kofod, and Roderick E. Wasylishen
    Solid-state 13C and 59Co NMR spectroscopy of 13C-methylcobalt(III) complexes with amine ligands,
    Phys. Chem. Chem. Phys. 11, 2690-2699 (2009).
  9. Joel A. Tang, Luke A. O’Dell, Pedro M. Aguiar, Bryan E. G. Lucier, Dimitris Sakellariou, and Robert W. Schurko
    Application of static microcoils and WURST pulses for solid-state ultra-wideline NMR spectroscopy of quadrupolar nuclei ,
    Chem. Phys. Lett. 466, 227-234 (2008).
  10. Luke A. O’Dell and Robert W. Schurko
    QCPMG using adiabatic pulses for faster acquisition of ultra-wideline NMR spectra,
    Chem. Phys. Lett. 464, 97-102 (2008).
  11. S. Wurmehl, J. T. Kohlhepp, H. J. M. Swagten, and B. Koopmans
    Hyperfine field distribution in the Heusler compound Co2FeAl probed by 59Co nuclear magnetic resonance,
    J. Phys. D: Appl. Phys. 41, 115007/1-115007/7 (2008).
  12. P. Crewdson, D. L. Bryce, F. Rominger, and P. Hofmann
    Application of ultrahigh-field 59Co solid-state NMR spectroscopy in the investigation of the 1,2-polybutadiene catalyst [Co(C8H13)(C4H6)],
    Angew. Chem. Int. Ed. 47, 3454-3457 (2008).
  13. K. J. Ooms, V. V. Terskikh, and R. E. Wasylishen
    Ultrahigh-field solid-state 59Co NMR studies of Co(C2B9H11)2- and Co(C5H5)2+ salts,
    J. Am. Chem. Soc. 129, 6704-6705 (2007).
  14. P. Kempgens, K. Elbayed, J. Raya, P. Granger, J. Rosé, and P. Braunstein
    Investigation of tetrahedral mixed-metal carbonyl clusters by two-dimensional 59Co COSY and DQFCOSY NMR experiments,
    Inorg. Chem. 45, 3378-3383 (2006).
  15. M. D. Jones and M. J. Duer
    29Si cross polarisation magic angle spinning spectroscopic studies on MCM-41 supported with metal carbonyl clusters,
    Inorg. Chim. Acta 354, 75-78 (2003).
  16. T. Ueda, G. M. Bernard, R. McDonald, and R. E. Wasylishen
    Cobalt-59 NMR and X-ray diffraction studies of hydrated and dehydrated (±)-tris(ethylenediamine) cobalt(III) chloride,
    Solid State Nucl. Magn. Reson. 24, 163-183 (2003).
  17. S. E. Ashbrook and S. Wimperis
    SCAM-STMAS: satellite-transition MAS NMR of quadrupolar nuclei with self-compensation for magic-angle misset,
    J. Magn. Reson. 162, 402-416 (2003).
  18. R. Siegel, J. Hirschinger, D. Carlier, M. Ménétrier, and C. Delmas
    59Co, 23Na NMR and electric field gradient calculations in the layered cobalt oxides NaCoO2 and HCoO2,
    Solid State Nucl. Magn. Reson. 23, 243-262 (2003).
  19. S. Wi, S. E. Ashbrook, S. Wimperis, and L. Frydman
    Second-order quadrupole-shielding effects in magic-angle spinning solid-state nuclear magnetic resonance,
    J. Chem. Phys. 118, 3131-3140 (2003).
  20. Sungsool Wi and Lucio Frydman
    Quadrupolar-shielding cross-correlations in solid state nuclear magnetic resonance: Detecting antisymmetric components in chemical shift tensors,
    J. Chem. Phys. 116, 1551-1561 (2002).
  21. S. E. Ashbrook and S. Wimperis
    Satellite-transition MAS NMR of spin I = 3/2, 5/2, 7/2, and 9/2 nuclei: sensitivity, resolution, and practical implementation,
    J. Magn. Reson. 156, 269-281 (2002).
  22. C. V. Grant, V. Frydman, J. S. Harwood, and L. Frydman
    59Co solid-state NMR as a new probe for elucidating metal binding in polynucleotides,
    J. Am. Chem. Soc. 124, 4458-4462 (2002).
  23. E. Jedryka, M. Wójcik, S. Nadolski, D. Kubinski, M. Parsons, and H. Holloway
    Effect of deposition sequence on interface intermixing in Cu/Co/Ru and Ru/Co/Cu multilayers studied by NMR,
    J. App. Phys. 91, 7191-7193 (2002).
  24. E. Gaudin, F. Taulelle, R. Stoyanova, E. Zhecheva, R. Alcántara, P. Lavela, and J. L. Tirado
    Cobalt(III) effect on 27Al NMR chemical shifts in LiAlxCo1-xO2,
    J. Phys. Chem. B 105, 8081-8087 (2001).
  25. U. G. Nielsen, H. J. Jakobsen, and J. Skibsted
    59Co chemical shift anisotropy and quadrupole coupling for K3Co(CN)6 from MQMAS and MAS NMR spectroscopy,
    Solid State Nucl. Magn. Reson. 20, 23-34 (2001).
  26. C. W. Kirby and W. P. Power
    Cobalt-59 chemical shift and quadrupolar tensors of simple octahedral cobalt(III) complexes,
    Can. J. Chem. 79, 296-303 (2001).
  27. Jerry C. C. Chan and Steve C. F. Au-Yeung
    Cobalt-59 NMR spectroscopy,
    in Annual Reports on NMR Spectroscopy, Graham A. Webb (Ed.), Elsevier, Amsterdam, vol. 41, pages 1-54 (2000).

Related bibliography

  1. G. Mali, A. Ristic, V. Kaucic
    31P NMR as a tool for studying incorporation of Ni, Co, Fe, and Mn into aluminophosphate zeotypes,
    J. Phys. Chem. B 41, 10711-10716 (2005).
  2. P. Granger, T. Richert, K. Elbayed, P. Kempgens, J. Hirschinger, J. Raya, J. Rosé, and P. Braunstein
    Microdynamic motion of tetrahedral clusters studied by 59Co and 99Ru NMR relaxations,
    Mol. Phys. 92, 895-902 (1997).
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