Arsenic-75 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
As-75 3/2 100 31.4 2.51E-2 2.51E-2 -17.126 NaAsF6

Solid-state arsenic NMR references

  1. Alexandra Faucher, Victor V. Terskikh, and Roderick E. Wasylishen
    Assessing distortion of the AF-6 (A=As, Sb) octahedra in solid hexafluorometallates(V) via NMR spectroscopy,
    Can. J. Chem. 93, 938-944 (2015).
  2. Alexandra Faucher, Victor V. Terskikh, and Roderick E. Wasylishen
    Feasibility of arsenic and antimony NMR spectroscopy in solids: An investigation of some group 15 compounds,
    Solid State Nucl. Magn. Reson. 61, 54-61 (2014).
  3. J. A. Lehmann-Horn, D. G. Miljak, and T. J. Bastow
    75As, 63Cu NMR and NQR characterization of selected arsenic minerals,
    Solid State Nucl. Magn. Reson. 54, 8-12 (2013).
  4. Dennis L. A. G. Grimminck, Ben J. W. Polman, Arno P. M. Kentgens, and W. Leo Meerts
    EASY-GOING deconvolution: Combining accurate simulation and evolutionary algorithms for fast deconvolution of solid-state quadrupolar NMR spectra,
    J. Magn. Reson. 211, 114-120 (2011).
  5. Paulus J. Knijn, P. Jan M. van Bentum, Ernst R. H. van Eck, Changming Fang, Dennis L. A. G. Grimminck, Robert A. de Groot, Remco W. A. Havenith, Martijn Marsman, W. Leo Meerts, Gilles A. de Wijs and Arno P. M. Kentgens
    A solid-state NMR and DFT study of compositional modulations in AlxGa1-xAs,
    Phys. Chem. Chem. Phys. 12, 11517-11535 (2010).
  6. A. P. M. Kentgens, J. Bart, P. J. M. van Bentum, A. Brinkmann, E. R. H. van Eck, J. G. E. Gardeniers, J. W. G. Janssen, P. Knijn, S. Vasa, and M. H. W. Verkuijlen
    High-resolution liquid- and solid-state nuclear magnetic resonance of nanoliter sample volumes using microcoil detectors,
    J Chem. Phys. 128, 052202/1-052202/17 (2008).
  7. G. M. Bowers and R. J. Kirkpatrick
    High-field 75As NMR study of arsenic oxysalts,
    J. Magn. Reson. 188, 311-321 (2007).
  8. A. Egorov, I. R. Mukhamedshin, and H. Suzuki
    NMR powder spectra in case of strong quadrupole interaction,
    Physica B 329-333, 1397-1398 (2003).
  9. P. C. Taylor, T. Su, P. Hari, E. Ahn, A. Kleinhammes, P. L. Kuhns, W. G. Moulton, and N. S. Sullivan
    Structural and photostructural properties of chalcogenide glasses: recent results from magnetic resonance measurements,
    J. Non-Cryst. Solids 326-327, 193-198 (2003).
  10. P. Hari, S. Guzel, T. Su, P. C. Taylor, P. L. Kuhns, W. G. Moulton, and N. S. Sullivan
    Photodarkening effect in glassy As2S3 and As2O3,
    J. Non-Cryst. Solids 326-327, 199-204 (2003).
  11. R. W. Schurko, S. Wi, and L. Frydman
    Dynamic effects on the powder line shapes of half-integer quadrupolar nuclei: a solid-state NMR study of XO4- groups,
    J. Phys. Chem. A 106, 51-62 (2002).
  12. R. Blinc and T. Apih
    NMR in multidimensionally modulated incommensurate and CDW systems,
    Prog. Nucl. Magn. Reson. Spectrosc. 41, 49-82 (2002).
  13. T. J. Bastow
    Arsenic-75 NMR: Knight shifts in arsenic metal,
    J. Phys.: Condens. Matter 11, 569-574 (1999).
  14. P. C. Taylor, P. Hari, A. Kleinhammes, P. L. Kuhns, and W. G. Moulton
    Asymmetries in local bonding sites in amorphous semiconductors: very high field NMR of 75As,
    J. Non-Cryst. Solids 227-230, 770-774 (1998).
  15. J. Takeuchi, H. Nakamura, H. Yamada, E. Kita, A. Tasaki, and T. Erata
    Quadrupolar nutation NMR on a compound semiconductor gallium-arsenide,
    Solid State Nucl. Magn. Reson. 8, 123-128 (1997).
  16. L. D. Potter and Y. Wu
    NMR measurements of homonuclear indirect couplings in GaAs,
    J. Magn. Reson. A 116, 107-112 (1995).
  17. L. D. Potter, A. A. Guzelian, A. P. Alivisatos, and Y. Wu
    Structure of chemically synthesized nanophase GaAs studied by NMR and x-ray diffraction,
    J. Chem. Phys. 103, 4834-4840 (1995).
  18. David C. Newitt and Erwin L. Hahn
    Detection of two-quantum nuclear coherence by nuclear-quadrupole-induced electric polarization,
    J. Magn. Reson. A 106, 140-143 (1994).
  19. M. Suemitsu and N. Nakajo
    Charged point defects in GaAs crystals evaluated by NMR spin echo,
    J. Appl. Phys. 66, 3178-3186 (1989).

Related bibliography

  1. D. L. Sastry, A. Naito, and C. A. McDowell
    75As quadrupolar effects in the CP MAS 13C NMR spectra of cacodylic acid and its sodium salt,
    Chem. Phys. Lett. 146, 422-427 (1988).

More solid-state As-75 NMR references.

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