Copper-63 and copper-65 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Cu-63 3/2 69.09 -22.0 9.31E-2 6.43E-2 -26.505 [Cu(CH3CN)4][ClO4]
Cu-65 3/2 30.91 -20.4 0.11 3.52E-2 -28.394

Solid-state copper NMR references

  1. Huaguang Yu, Xiuzhen Tan, Guy M. Bernard, Victor V. Terskikh, Jinglin Chen, and Roderick E. Wasylishen
    Solid-state 63Cu, 65Cu and 31P NMR spectroscopy of photoluminescent copper(I) triazole phosphine complexes,
    J. Phys. Chem. A 119, 8279-8293 (2015).
  2. Léo Choubrac, Michaël Paris, Alain Lafond, Catherine Guillot-Deudon, Xavier Rocquefelte, and Stéphane Jobic
    Multinuclear (67Zn, 119Sn and 65Cu) NMR spectroscopy – an ideal technique to probe the cationic ordering in Cu2ZnSnS4 photovoltaic materials,
    Phys. Chem. Chem. Phys. 15, 10722-10725 (2013).
  3. J. A. Lehmann-Horn, D. G. Miljak, and T. J. Bastow
    75As, 63Cu NMR and NQR characterization of selected arsenic minerals,
    Solid State Nucl. Magn. Reson. 54, 8-12 (2013).
  4. Bryan E. G. Lucier, Joel A. Tang, Robert W. Schurko, Graham A. Bowmaker, Peter C. Healy, and John V. Hanna
    Solid-state 65Cu and 31P NMR spectroscopy of bis(triphenylphosphine) copper species,
    J. Phys. Chem. C 114, 7949-7962 (2010).
  5. J. P. Yesinowski, H. D. Ladouceur, A. P. Purdy, and J. B. Miller
    Electrical and ionic conductivity effects on magic-angle spinning nuclear magnetic resonance parameters of CuI,
    J. Chem. Phys. 133, 234509/1-234509/18 (2010).
  6. Luke A. O’Dell, Aaron J. Rossini, and Robert W. Schurko
    Acquisition of ultra-wideline NMR spectra from quadrupolar nuclei by frequency stepped WURST–QCPMG,
    Chem. Phys. Lett. 468, 330-335 (2009).
  7. T. J. Bastow and S. Celotto
    25Mg NMR site analysis in metals and intermetallics,
    Solid State Nucl. Magn. Reson. 35, 217-222 (2009).
  8. T. F. Kemp and M. E. Smith
    QuadFit—A new cross-platform computer program for simulation of NMR line shapes from solids with distributions of interaction parameters,
    Solid State Nucl. Magn. Reson. 35, 243-252 (2009).
  9. R. R. Gainov, A. V. Dooglav, I. N. Pen’kov, I. R. Mukhamedshin, A. V. Savinkov, and N. N. Mozgova
    Copper valence, structural separation and lattice dynamics in tennantite (fahlore): NMR, NQR and SQUID studies,
    Phys. Chem. Miner. 35, 37-48 (2008).
  10. E. N. Muhamad, R. Irmawati, Y. H. Tautiq-Yap, A. H. Abdullah, B. L. Kniep, F. Girgsdies, and T. Ressler
    Comparative study of Cu/ZnO catalysts derived from different precursors as a function of aging,
    Catal. Today 131, 118-124 (2008).
  11. J. A. Tang, B. D. Ellis, T. H. Warren, J. V. Hanna, C. L. B. Macdonald, and R. W. Schurko
    Solid-state 63Cu and 65Cu NMR spectroscopy of inorganic and organometallic copper(I) complexes,
    J. Am. Chem. Soc. 129, 13049-13065 (2007).
  12. F. Haarmann, M. Armbruster, and Y. Grin
    Local ordering in the intermetallic compound Cu1-xAl2 studied by NMR spectroscopy,
    Chem. Mater. 19, 1147-1153 (2007).
  13. D. Rusanova, K. J. Pike, I. Persson, R. Dupree, M. Lindberg, J. V. Hanna, O. N. Antzutkin, and W. Forsling
    Solid-state static 65Cu and 31P CP/MAS NMR, and liquid-state EXAFS studies on copper(I) O,O'-dialkyldithiophosphate cluster compounds: Formation of the copper(I) O,O'-di-iso-amyldlthiophosphate cluster compound on the surface of,
    Polyhedron 25, 3569-3580 (2007).
  14. D. Rusanova, K. J. Pike, R. Dupree, J. V. Hanna, O. N. Antzutkin, I. Persson, and W. Forsling
    Spectroscopic characterization of the polycrystalline copper(I) di-n-butyldithlophosphate cluster - Cu8[S2P(O-n-Bu)2]6(mu8-S): Solid-state 31P CP/MAS and static 65Cu NMR studies,
    Inorg. Chim. Acta 359, 3903-3910 (2006).
  15. D. Rusanova, W. Forsling, O. N. Antzutkin, K. J. Pike, and R. Dupree
    Solid-state 31P CP/MAS and static 65Cu NMR characterization of polycrystalline copper(I) dialkyldithiophosphate clusters,
    J. Magn. Reson. 179, 140-145 (2006).
  16. Gunther Brunklaus, Jerry C. C. Chan, Hellmut Eckert, Sara Reiser, Tom Nilges, and Arno Pfitzner
    NMR studies of phosphorus chalcogenide–copper iodide coordination compounds,
    Phys. Chem. Chem. Phys. 5, 3768-3776 (2003).
  17. T. Shimizu, T. Matsumoto, A. Goto, T. V. C. Rao, K. Yoshimura, and K. Kosuge
    Spin susceptibility and superexchange interaction in the antiferromagnet CuO,
    Phys. Rev. B 68, 224433/1-224433/8 (2003).
  18. T. J. Bastow and S. Celotto
    Clustering and formation of nano-precipitates in dilute aluminium and magnesium alloys,
    Mater. Sci. Eng. C 23, 757-762 (2003).
  19. A. Egorov, I. R. Mukhamedshin, and H. Suzuki
    NMR powder spectra in case of strong quadrupole interaction,
    Physica B 329-333, 1397-1398 (2003).
  20. T. J. Bastow and S. Celotto
    Structure evolution in dilute Al(Cu) alloys observed by 63Cu NMR,
    Acta Mater. 51, 4621-4630 (2003).
  21. Sara Reiser, Gunther Brunklaus, Jung Hoon Hong, Jerry C. C. Chan, Hellmut Eckert, and Arno Pfitzner
    (CuI)3P4S4 : Preparation, structural, and NMR spectroscopic characterization of a copper(I) halide adduct with β-P4S4,
    Chem. Eur. J. 8, 4228-4233 (2002).
  22. Y. Furukawa, S. Takada, K. Kumagai, T. Kawashima, E. Takayama-Muromachi, N. Kobayashi, T. Fukase, K. Chiba, and T. Goto
    NMR studies of magnetic superconductor RuSr2RECu2O8 (RE = Gd, Eu and Y),
    J. Phys. Chem. Solids 63, 2315-2318 (2002).
  23. S. Sakida, N. Kato, and Y. Kawamoto
    63Cu magic angle spinning (MAS) nuclear magnetic resonance (NMR) study of CuX crystals (X = Cl, Br, and I) and CuX-based glasses (X = Cl, Br, and I),
    Mater. Res. Bull. 37, 2263-2274 (2002).
  24. P. E. Stallwortha, J.-F. Guillemoles, J. Flowers, J. Vedel, and S. G. Greenbaum
    NMR studies of CuInS2 and CuInSe2 crystals grown by the Bridgman method,
    Solid State Commun. 113, 527-532 (2000).
  25. P. R. Bodart, J.-P. Amoureux, Y. Dumazy, and R. Lefort
    Theoretical and experimental study of quadrupolar echoes for half-integer spins in static solid-state NMR,
    Mol. Phys. 98, 1545-1551 (2000).
  26. A. A. Gippius, E. V. Antipov, W. Hoffmann, K. Lüders, and G. Buntkowsky
    Low-frequency spin dynamics as probed by 63Cu and 199Hg NMR in HgBa2CuO4+delta superconductors with different oxygen content,
    Phys. Rev. B 59, 654-660 (1999).
  27. V. N. Berzhanskii, A. I. Gorbovanov, and S. N. Polulyakh
    Multiquantum triple-pulse spin-echo signals from quadrupole nuclei in magnetically ordered substances,
    JETP 88, 1151-1154 (1999).
  28. J. Haase, N. J. Curro, R. Stern, and C. P. Slichter
    New double resonance technique for quadrupolar nuclei,
    Mol. Phys. 95, 891-896 (1998).
  29. S. Hayashi and K. Hayamizu
    Effect of spinning on chemical shifts in magic-angle-spinning nuclear magnetic resonance,
    J. Chem. Phys. 92, 2818-2827 (1990).
  30. D. Köngeter, F. Hentsch, H. Seidel, M. Mehring, P. Erk, and S. Hünig
    Metal like 13C and 63Cu Knight shifts in the organic conductor (2,5-dimethyl-dicyanoquinonediimine)2Cu,
    Solid. State Commun. 65, 453-456 (1988).

Related bibliography

  1. M. J. Willans, D. N. Sears, and R. E. Wasylishen
    The effectiveness of 1H decoupling in the 13C MAS NMR of paramagnetic solids: An experimental case study incorporating copper(II) amino acid complexes,
    J. Magn. Reson. 191, 31-46 (2008).
  2. H. Fukazawa, N. Yamatoji, Y. Kohori, C. Terakura, N. Takeshita, Y. Tokura, and H. Takagi
    Manometer extension for high pressure measurement: Nuclear quadrupole resonance study of Cu2O with a modified Bridgman anvil cell up to 10 GPa,
    Rev. Sci. Instr. 78, 15160-1/15160-4 (2007).
  3. Scott Kroeker, John V. Hanna, Roderick E. Wasylishen, Eric W. Ainscough, and Andrew M. Brodie
    Anisotropy in the 31P, 63/65Cu indirect spin–spin coupling and 31P nuclear shielding tensors of linear copper(I) phosphines,
    J. Magn. Reson. 135, 208-215 (1998).
  4. F. Asaro, A. Camus, R. Gobetto, A. C.Olivieri, and G. Pellizer
    63Cu-31P coupling constants and 63Cu quadrupole couplings from 31P CP/MAS spectra of copper (I)—phosphine complexes with aryldithiocarboxylates or benzoate,
    Solid State Nucl. Magn. Reson. 8, 81-88 (1997).
  5. Kazunaka Endo, Kyonosuke Yamamoto, Kenzo Deguchi, and Kazuhiro Matsushita
    63Cu high resolution NMR of Cu(I) halides in aqueous solution and suspension,
    Bull. Chem. Soc. Jpn 60, 2803-2807 (1987).

More solid-state Cu-63/65 NMR references.

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