Copper-63 and copper-65 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Cu-63 3/2 69.09 -22.0 9.31E-2 6.43E-2 -26.505 [Cu(CH3CN)4][ClO4]
Cu-65 3/2 30.91 -20.4 0.11 3.52E-2 -28.394

Solid-state copper NMR references

  1. Huaguang Yu, Xiuzhen Tan, Guy M. Bernard, Victor V. Terskikh, Jinglin Chen, and Roderick E. Wasylishen
    Solid-state 63Cu, 65Cu and 31P NMR spectroscopy of photoluminescent copper(I) triazole phosphine complexes,
    J. Phys. Chem. A 119, 8279-8293 (2015).
  2. Léo Choubrac, Michaël Paris, Alain Lafond, Catherine Guillot-Deudon, Xavier Rocquefelte, and Stéphane Jobic
    Multinuclear (67Zn, 119Sn and 65Cu) NMR spectroscopy – an ideal technique to probe the cationic ordering in Cu2ZnSnS4 photovoltaic materials,
    Phys. Chem. Chem. Phys. 15, 10722-10725 (2013).
  3. J. A. Lehmann-Horn, D. G. Miljak, and T. J. Bastow
    75As, 63Cu NMR and NQR characterization of selected arsenic minerals,
    Solid State Nucl. Magn. Reson. 54, 8-12 (2013).
  4. Bryan E. G. Lucier, Joel A. Tang, Robert W. Schurko, Graham A. Bowmaker, Peter C. Healy, and John V. Hanna
    Solid-state 65Cu and 31P NMR spectroscopy of bis(triphenylphosphine) copper species,
    J. Phys. Chem. C 114, 7949-7962 (2010).
  5. J. P. Yesinowski, H. D. Ladouceur, A. P. Purdy, and J. B. Miller
    Electrical and ionic conductivity effects on magic-angle spinning nuclear magnetic resonance parameters of CuI,
    J. Chem. Phys. 133, 234509/1-234509/18 (2010).
  6. Luke A. O’Dell, Aaron J. Rossini, and Robert W. Schurko
    Acquisition of ultra-wideline NMR spectra from quadrupolar nuclei by frequency stepped WURST–QCPMG,
    Chem. Phys. Lett. 468, 330-335 (2009).
  7. T. J. Bastowa and S. Celotto
    25Mg NMR site analysis in metals and intermetallics,
    Solid State Nucl. Magn. Reson. 35, 217-222 (2009).
  8. T. F. Kemp and M. E. Smith
    QuadFit—A new cross-platform computer program for simulation of NMR line shapes from solids with distributions of interaction parameters,
    Solid State Nucl. Magn. Reson. 35, 243-252 (2009).
  9. E. N. Muhamad, R. Irmawati, Y. H. Tautiq-Yap, A. H. Abdullah, B. L. Kniep, F. Girgsdies, and T. Ressler
    Comparative study of Cu/ZnO catalysts derived from different precursors as a function of aging,
    Catal. Today 131, 118-124 (2008).
  10. J. A. Tang, B. D. Ellis, T. H. Warren, J. V. Hanna, C. L. B. Macdonald, and R. W. Schurko
    Solid-state 63Cu and 65Cu NMR spectroscopy of inorganic and organometallic copper(I) complexes,
    J. Am. Chem. Soc. 129, 13049-13065 (2007).
  11. F. Haarmann, M. Armbruster, and Y. Grin
    Local ordering in the intermetallic compound Cu1-xAl2 studied by NMR spectroscopy,
    Chem. Mater. 19, 1147-1153 (2007).
  12. D. Rusanova, K. J. Pike, I. Persson, R. Dupree, M. Lindberg, J. V. Hanna, O. N. Antzutkin, and W. Forsling
    Solid-state static 65Cu and 31P CP/MAS NMR, and liquid-state EXAFS studies on copper(I) O,O'-dialkyldithiophosphate cluster compounds: Formation of the copper(I) O,O'-di-iso-amyldlthiophosphate cluster compound on the surface of,
    Polyhedron 25, 3569-3580 (2007).
  13. D. Rusanova, K. J. Pike, R. Dupree, J. V. Hanna, O. N. Antzutkin, I. Persson, and W. Forsling
    Spectroscopic characterization of the polycrystalline copper(I) di-n-butyldithlophosphate cluster - Cu8[S2P(O-n-Bu)2]6(mu8-S): Solid-state 31P CP/MAS and static 65Cu NMR studies,
    Inorg. Chim. Acta 359, 3903-3910 (2006).
  14. D. Rusanova, W. Forsling, O. N. Antzutkin, K. J. Pike, and R. Dupree
    Solid-state 31P CP/MAS and static 65Cu NMR characterization of polycrystalline copper(I) dialkyldithiophosphate clusters,
    J. Magn. Reson. 179, 140-145 (2006).
  15. T. Shimizu, T. Matsumoto, A. Goto, T. V. C. Rao, K. Yoshimura, and K. Kosuge
    Spin susceptibility and superexchange interaction in the antiferromagnet CuO,
    Phys. Rev. B 68, 224433/1-224433/8 (2003).
  16. T. J. Bastow and S. Celotto
    Clustering and formation of nano-precipitates in dilute aluminium and magnesium alloys,
    Mater. Sci. Eng. C 23, 757-762 (2003).
  17. A. Egorov, I. R. Mukhamedshin, and H. Suzuki
    NMR powder spectra in case of strong quadrupole interaction,
    Physica B 329-333, 1397-1398 (2003).
  18. T. J. Bastow and S. Celotto
    Structure evolution in dilute Al(Cu) alloys observed by 63Cu NMR,
    Acta Mater. 51, 4621-4630 (2003).
  19. Y. Furukawa, S. Takada, K. Kumagai, T. Kawashima, E. Takayama-Muromachi, N. Kobayashi, T. Fukase, K. Chiba, and T. Goto
    NMR studies of magnetic superconductor RuSr2RECu2O8 (RE = Gd, Eu and Y),
    J. Phys. Chem. Solids 63, 2315-2318 (2002).
  20. S. Sakida, N. Kato, and Y. Kawamoto
    63Cu magic angle spinning (MAS) nuclear magnetic resonance (NMR) study of CuX crystals (X = Cl, Br, and I) and CuX-based glasses (X = Cl, Br, and I),
    Mater. Res. Bull. 37, 2263-2274 (2002).
  21. P. R. Bodart, J.-P. Amoureux, Y. Dumazy, and R. Lefort
    Theoretical and experimental study of quadrupolar echoes for half-integer spins in static solid-state NMR,
    Mol. Phys. 98, 1545-1551 (2000).
  22. A. A. Gippius, E. V. Antipov, W. Hoffmann, K. Lüders, and G. Buntkowsky
    Low-frequency spin dynamics as probed by 63Cu and 199Hg NMR in HgBa2CuO4+delta superconductors with different oxygen content,
    Phys. Rev. B 59, 654-660 (1999).
  23. V. N. Berzhanskii, A. I. Gorbovanov, and S. N. Polulyakh
    Multiquantum triple-pulse spin-echo signals from quadrupole nuclei in magnetically ordered substances,
    JETP 88, 1151-1154 (1999).
  24. S. Hayashi and K. Hayamizu
    Effect of spinning on chemical shifts in magic-angle-spinning nuclear magnetic resonance,
    J. Chem. Phys. 92, 2818-2827 (1990).
  25. D. Köngeter, F. Hentsch, H. Seidel, M. Mehring, P. Erk, and S. Hünig
    Metal like 13C and 63Cu Knight shifts in the organic conductor (2,5-dimethyl-dicyanoquinonediimine)2Cu,
    Solid. State Commun. 65, 453-456 (1988).

Related bibliography

  1. M. J. Willans, D. N. Sears, and R. E. Wasylishen
    The effectiveness of 1H decoupling in the 13C MAS NMR of paramagnetic solids: An experimental case study incorporating copper(II) amino acid complexes,
    J. Magn. Reson. 191, 31-46 (2008).
  2. H. Fukazawa, N. Yamatoji, Y. Kohori, C. Terakura, N. Takeshita, Y. Tokura, and H. Takagi
    Manometer extension for high pressure measurement: Nuclear quadrupole resonance study of Cu2O with a modified Bridgman anvil cell up to 10 GPa,
    Rev. Sci. Instr. 78, 15160-1/15160-4 (2007).
  3. Kazunaka Endo, Kyonosuke Yamamoto, Kenzo Deguchi, and Kazuhiro Matsushita
    63Cu high resolution NMR of Cu(I) halides in aqueous solution and suspension,
    Bull. Chem. Soc. Jpn 60, 2803-2807 (1987).

More solid-state Cu-63/65 NMR references.

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