Nitrogen-14 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
N-14 1 99.63 2.044 1.01E-3 1.01E-3 -7.224 CH3NO2
N-15 1/2 0.37 0 1.04E-3 3.85E-6 10.133 MeNO2

Solid-state nitrogen NMR references

  1. Michael J. Jaroszewicz, Adam R. Altenhof, Robert W. Schurko, and Lucio Frydman
    Sensitivity enhancement by progressive saturation of the proton reservoir: A solid-state NMR analogue of chemical exchange saturation transfer,
    J. Am. Chem. Soc. 143, 19778-19784 (2021).
    Open access
  2. Otto E. O. Zeman, Igor L. Moudrakovski, Carsten Hartmann, Sylvio Indris, and Thomas Bräuniger
    Local electronic structure in AlN studied by single-crystal 27Al and 14N NMR and DFT calculations,
    Molecules 25, 469-469 (2020).
    Open access
  3. Diego Carnevale, Xiao Ji, and Geoffrey Bodenhausen
    Double cross polarization for the indirect detection of nitrogen-14 nuclei in magic angle spinning NMR spectroscopy,
    J. Chem. Phys. 147, 184201-8pp (2017).
  4. Eddy Dib, Tzonka Mineva, and Bruno Alonso
    Recent advances in 14N solid-state NMR,
    Annu. Rep. Nucl. Magn. Reson. Spectrosc. 87, 175-235 (2016).
  5. Ibraheem M. Haies, James A. Jarvis, Harry Bentley, Ivo Heinmaa, Ilya Kuprov, Philip T. F. Williamson, and Marina Carravetta
    14N overtone NMR under MAS: signal enhancement using symmetry-based sequences and novel simulation strategies,
    Phys. Chem. Chem. Phys., 17, 6577--6587 (2015).
  6. Luke A. O'Dell
    The WURST kind of pulses in solid-state NMR,
    Solid State Nucl. Magn. Reson. 55-56, 28-41 (2013).
  7. Frédéric A. Perras, Cory M. Widdifield, and David L. Bryce
    QUEST—QUadrupolar Exact SofTware: A fast graphical program for the exact simulation of NMR and NQR spectra for quadrupolar nuclei,
    Solid State Nucl. Magn. Reson. 45-46, 36-44 (2012).
  8. L. A. O'Dell
    Direct detection of nitrogen-14 in solid-state NMR spectroscopy,
    Prog. Nucl. Magn. Reson. Spectrosc. 59, 295-318 (2011).
  9. L. A. O'Dell and C. I. Ratcliffe
    14N magic angle spinning overtone NMR spectra,
    Chem. Phys. Lett. 514, 168-173 (2011).
  10. L. A. O'Dell, R. W. Schurko, K. J. Harris, J. Autschbach, and C. I. Ratcliffe
    Interaction tensors and local dynamics in common structural motifs of nitrogen: A solid-state 14N NMR and DFT study,
    J. Am. Chem. Soc. 133, 527-546 (2011).
  11. Yusuke Nishiyama, Yuki Endo, Takahiro Nemoto, Hiroaki Utsumi, Kazuo Yamauchi, Katsuya Hioka, and Tetsuo Asakura
    Very fast magic angle spinning 1H-14N 2D solid-state NMR: Sub-micro-liter sample data collection in a few minutes,
    J. Magn. Reson. 208, 44-48 (2011).
  12. Lei Chen, Qiang Wang, Bingwen Hu, Olivier Lafon, Julien Trébosc, Feng Deng, and Jean-Paul Amoureux
    Measurement of hetero-nuclear distances using a symmetry-based pulse sequence in solid-state NMR,
    Phys. Chem. Chem. Phys. 12, 9395-9405 (2010).
  13. Simone Cavadini, Veronika Vitzthum, Simone Ulzega, Anuji Abraham, and Geoffrey Bodenhausen
    Line-narrowing in proton-detected nitrogen-14 NMR,
    J. Magn. Reson. 209, 57-63 (2010).
  14. L. A. O'Dell and C. I. Ratcliffe
    Ultra-wideline 14N NMR spectroscopy as a probe of molecular dynamics,
    Chem. Commun. 46, 6774-6776 (2010).
  15. Chunqi Qian, Riqiang Fu, Peter Gor’kov, William W. Brey, Timothy A. Cross, and Zhehong Gan
    14N Polarization Inversion Spin Exchange at Magic Angle (PISEMA),
    J. Magn. Reson. 196, 96-99 (2009).
  16. L. A. O'Dell and R. W. Schurko
    Static solid-state 14N NMR and computational studies of nitrogen EFG tensors in some crystalline amino acids,
    Phys. Chem. Chem. Phys. 11, 7069-7077 (2009).
  17. L. A. O'Dell and R. W. Schurko
    Fast and simple acquisition of solid-state 14N NMR spectra with signal enhancement via population transfer,
    J. Am. Chem. Soc. 131, 6658-6659 (2009).
  18. R. S. Stein, B. Elena, and L. Emsley
    Improving resolution in proton solid-state NMR by removing nitrogen-14 residual dipolar broadening,
    Chem. Phys. Lett. 458, 391-395 (2008).
  19. N. M. Trease and P. J. Grandinetti
    Solid-state nuclear magnetic resonance in the rotating tilted frame,
    J. Chem. Phys. 128, 52318/1-52318/12 (2008).
  20. S. Cavadini, A. Abraham, and G. Bodenhausen
    Coherence transfer between spy nuclei and nitrogen-14 in solids,
    J. Magn. Reson. 190, 160-164 (2008).
  21. C. A. Fyfe, R. J. Darton, C. Schneider, and F. Scheffler
    Solid-state NMR investigation of the possible existence of "Nanoblocks" in the clear solution synthesis of MFI materials,
    J. Phys. Chem. C 112, 80-88 (2008).
  22. S. Cavadini, S. Antonijevic, A. Lupulescu, and G. Bodenhausen
    Indirect detection of nitrogen-14 in solid-state NMR spectroscopy,
    ChemPhysChem. 8, 1363-1374 (2007).
  23. T. N. Rudakov
    Some aspects of spin-locking effect in nitrogen-14 quadrupolar spin-system,
    Chem. Phys. Lett. 443, 269-273 (2007).
  24. H. J. Jakobsen, A. R. Hove, H. Bildsoe, J. Skibsted, M. Brorson
    Long-term stability of rotor-controlled MAS frequencies to 0.1 Hz proved by 14N MAS NMR experiments and simulations,
    J. Magn. Reson. 185, 159-163 (2007).
  25. Z. H. Gan, J.-P. Amoureux, and J. Trebosc
    Proton-detected 14N MAS NMR using homonuclear decoupled rotary resonance,
    Chem. Phys. Lett. 435, 163-169 (2007).
  26. Z. H. Gan
    13C/14N heteronuclear multiple-quantum correlation with rotary resonance and REDOR dipolar recoupling,
    J. Magn. Reson. 184, 39-43 (2007).
  27. Z. H. Gan
    Measuring multiple carbon-nitrogen distances in natural abundant solids using R-RESPDOR NMR,
    Chem. Commun.4712-4714 (2006).
  28. A. R. Hove, H. Bildsoe, J. Skibsted, M. Brorson, and H. J. Jakobsen
    Probing crystal structures and transformation reactions of ammonium molybdates by 14N MAS NMR spectroscopy,
    Inorg. Chem. 45, 10873-10881 (2006).
  29. H. J. Jakobsen, A. R. Hove, R. G. Hazell, H. Bildsøe, and J. Skibsted
    Solid-state 14N MAS NMR of ammonium ions as a spy to structural insights for ammonium salts,
    Magn. Reson. Chem. 44, 348-356 (2006).
  30. J. P. Yesinowski
    69,71Ga and 14N high-field NMR of gallium nitride films,
    phys. stat. sol. (c) 2, 2399-2402 (2005).
  31. A. P. Purdy, J. P. Yesinowski, and A. T. Hanbicki
    Synthesis, solid-state NMR, and magnetic characterization of h-GaN containing magnetic ions,
    phys. stat. sol. (c) 2, 2437-2440 (2005).
  32. Gerard S. Harbison, Young-Sik Kye, Glenn H. Penner, Michelle Grandin, and Martine Monette
    14N quadrupolar, 14N and 15N chemical shift, and 14N-1H dipolar tensors of sulfamic acid,
    J. Phys. Chem. B 106, 10285-10291 (2002).
  33. M. Punkkinen, A. H. Vuorimäki, E. E. Ylinen, and A. Kaikkonen
    14N NMR echo in NH4ClO4 after the pulse sequence (θ1)x–τ–(θ2)y–t,
    J. Magn. Reson. 130, 287-291 (1998).
  34. E. A. Hill and J. P. Yesinowski
    A slow turning method for measuring large anisotropic interactions in inhomogeneously broadened NMR spectra,
    J. Chem. Phys. 106, 8650-8659 (1997).
  35. E. A. Hill and J. P. Yesinowski
    Solid-state 14N NMR techniques for studying slow molecular motions,
    J. Chem. Phys. 107, 346-354 (1997).
  36. E. A. Hill and J. P. Yesinowski
    Wide-line 14N NMR in solids and reorientation-induced redistribution of isochromats,
    J. Am. Chem. Soc. 118, 6798-6799 (1996).

Related bibliography

  1. Simone Cavadini
    Indirect detection of nitrogen-14 in solid-state NMR spectroscopy,
    Prog. Nucl. Magn. Reson. Spectrosc. 56, 46-77 (2010).
  2. S. Cavadini, S. Antonijevic, A. Lupulescu, and G. Bodenhausen
    Indirect detection of nitrogen-14 in solids via protons by nuclear magnetic resonance spectroscopy,
    J. Magn. Reson. 182, 168-172 (2006).
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