Scandium-45 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Sc-45 7/2 100 -22.0 0.30 0.30 -24.290 Sc(NO3)3

Solid-state scandium NMR references

  1. Nasima Kanwal, Henri Colaux, Daniel M. Dawson, Yusuke Nishiyama, and Sharon E. Ashbrook
    Sensitivity improvement in 5QMAS NMR experiments using FAM-N pulses,
    Solid State Nucl. Magn. Reson. 100, 1-10 (2019).
  2. Henri Colaux, Daniel M. Dawson, and Sharon E. Ashbrook
    Investigating FAM-N pulses for signal enhancement in MQMAS NMR of quadrupolar nuclei,
    Solid State Nucl. Magn. Reson. 84, 89-102 (2017).
    Open access
  3. Marcos de Oliveira, Jr., Tássia S. Gonçalves, Cynthia Ferrari, Claudio José Magon, Paulo S. Pizani, Andrea S. S. de Camargo, and Hellmut Eckert
    Structure−property relations in fluorophosphate glasses: An integrated spectroscopic strategy,
    J. Phys. Chem. C 121, 2968-2986 (2017).
    Abstract
  4. R. Giovine, Ch. Volkringer, S. E. Ashbrook, J. Trébosc, D. McKay, Th. Loiseau, J.-P. Amoureux, O. Lafon, and F. Pourpoint
    Solid-state NMR spectroscopy proves the presence of penta-coordinated Sc sites in MIL-100(Sc),
    Chem. Eur. J. 23, 9525-9534 (2017).
    Abstract
  5. Thomas Braeuniger, Andreas J. Hofmann, Igor L. Moudrakovski, Constantin Hoch, and Wolfgang Schnick
    A 45Sc-NMR and DFT calculation study of crystalline scandium compounds,
    Solid State Sciences 51, 1-7 (2016).
    Abstract
  6. Itaru Okinawa and Hitoshi Takamura
    45Sc NMR spectroscopy and first-principles calculation on the symmetry of ScO6 polyhedra in BaO–Sc2O3-based oxides,
    Dalton Trans. 43, 9714-9721 (2014).
    Abstract
  7. Karen E. Johnston, Martin R. Mitchell, Frédéric Blanc, Philip Lightfoot, and Sharon E. Ashbrook
    Structural study of La1-xYxScO3, combining neutron diffraction, solid-state NMR, and first-principles DFT calculations,
    J. Phys. Chem. C 117, 2252-2265 (2013).
    Abstract
  8. C. Merkens, O. Pecher, F. Steuber, S. Eisenhut, A. Görne, F. Haarmann, and U. Englert
    Crystal-to-crystal transformations in a seven-coordinated scandium complex,
    Z. Anorg. Allg. Chem. 639, 340-346 (2013).
    Abstract
  9. C. Vinod Chandran, Jérôme Cuny, Régis Gautier, Laurent Le Pollès, Chris J. Pickard, and Thomas Bräuniger
    Improving sensitivity and resolution of MQMAS spectra: A 45Sc-NMR case study of scandium sulphate pentahydrate,
    J. Magn. Reson. 203, 226-235 (2010).
    Abstract
  10. M. D. Alba, P. Chain, P. Florian, and D. Massiot
    45Sc spectroscopy of solids: Interpretation of quadrupole interaction parameters and chemical shifts,
    J. Phys. Chem. C 114, 12125-12132 (2010).
    Abstract
  11. L. A. O'Dell, K. J. Harris, and R. W. Schurko
    Optimized excitation pulses for the acquisition of static NMR powder patterns from half-integer quadrupolar nuclei,
    J. Magn. Reson. 203, 156-166 (2010).
    Abstract
  12. Ivan Hung, Julien Trébosc, Gina L. Hoatson, Robert L. Vold, Jean-Paul Amoureux, and Zhehong Gan
    Q-shear transformation for MQMAS and STMAS NMR spectra,
    J. Magn. Reson. 201, 81-86 (2009).
    Abstract
  13. Kimberly E. Kelsey, Jonathan F. Stebbins, David M. Singer, Gordon E. Brown Jr., Jed L. Mosenfelder, and Paul D. Asimow
    Cation field strength effects on high pressure aluminosilicate glass structure: Multinuclear NMR and La XAFS results,
    Geochim. Cosmochim. Acta 73, 3914-3933 (2009).
    Abstract
  14. T. Harmening, H. Eckert, and R. Pöttgen
    Defects in half-Heusler type antimonides ScTSb (T = Ni, Pd, Pt) ,
    Solid State Sciences 11, 900-906 (2009).
    Abstract
  15. T. Harmening, H. Eckert, D. Johrendt, and R. Pöttgen
    Centrosymmetric silicide ScNiSi3 - Structure, chemical bonding, and 45Sc solid state NMR,
    Solid State Sciences 10, 544-549 (2008).
  16. T. Brauniger and P. K. Madhu
    Fast amplitude-modulated pulse trains with frequency sweep (SW-FAM) in solid-state NMR of spin-7/2 nuclei,
    J. Magn. Reson. 193, 102-109 (2008).
  17. D. Khabibulin, K. Romanenko, M. Zuev, and O. Lapina
    Solid state NMR characterization of individual compounds and solid solutions formed in Sc2O3-V2O5-Nb2O5-Ta2O5 system,
    Magn. Reson. Chem. 45, 962-970 (2008).
  18. Namjun Kim, Jonathan F. Stebbins, Simona Quartieri, and Roberta Oberti
    Scandium-45 NMR of pyrope-grossular garnets: Resolution of multiple scandium sites and comparison with X-ray diffraction and X-ray absorption spectroscopy,
    Am. Mineral. 92, 1875-1880 (2007).
    Abstract
  19. D. Mohr, A. S. S. de-Camargo, C. C. de-Araujo, and H. Eckert
    Local environment of scandium in aluminophosphate laser glasses: structural studies by solid state NMR spectroscopy,
    J. Mater. Chem. 17, 3733-3738 (2007).
  20. L. Zhang, C. Fehse, H. Eckert, C. Vogt, R. D. Hoffmann, and R. Pöttgen
    Solid state NMR spectroscopy as a probe of structure and bonding in the carbides Sc3TC4 (T = Co, Ni, Ru, Rh, Os, Ir),
    Solid State Sci. 9, 699-705 (2007).
  21. C. P. Sebastian, H. Eckert, and R. Pottgen
    The stannides ScNi1.54(1)Sn and ScNi1.85(1)Sn - Structures, 45Sc NMR and 119Sn Mossbauer spectroscopy,
    Solid State Sci. 9, 357-361 (2007).
  22. A. Y. H. Lo, V. Sudarsan, S. Sivakumar, F. van-Veggel, and R. W. Schurko
    Multinuclear solid-state NMR spectroscopy of doped lanthanum fluoride nanoparticles,
    J. Am. Chem. Soc. 129, 4687-4700 (2007).
  23. N. Kim, C.-H. Hsieh, and J. F. Stebbins
    Scandium coordination in solid oxides and stabilized zirconia: 45Sc NMR,
    Chem. Mater. 18, 3855-3859 (2006).
  24. A. J. Rossini and R. W. Schurko
    Experimental and theoretical studies of 45Sc NMR interactions in solids,
    J. Am. Chem. Soc. 128, 10391-10402 (2006).
  25. T. J. Bastow, T. Mathews, and J. R. Sellar
    Al2O3 solubility in the fast ion conductor 0.88ZrO2-(0.12-x)Sc2O3-xAl2O3 determined by 27Al NMR,
    Solid State Ionics 175, 415-417 (2004).
  26. H. S. Park, I. Bull, L. M. Peng, G. Y. J. Victor, C. P. Grey, and J. B. Parise
    Synthesis and structure determination of a new organically templated scandium fluorophosphate framework and its indium analogue,
    Chem. Mater. 16, 5350-5356 (2004).
  27. V. V. Laguta, M. D. Glinchuk, I. P. Bykov, R. Blinc, and B. Zalar
    NMR study of ionic shifts and polar ordering in the relaxor ferroelectric Pb(Sc1/2Nb1/2)O3,
    Phys. Rev. B 69, 54103/1-54103/9 (2004).
  28. T. Bräuniger, K. Ramaswamy, and P. K. Madhu
    Enhancement of the central-transition signal in static and magic-angle-spinning NMR of quadrupolar nuclei by frequency-swept fast amplitude-modulated pulses,
    Chem. Phys. Lett. 383, 403-410 (2004).
  29. T. J. Bastow and S. Celotto
    Clustering and formation of nano-precipitates in dilute aluminium and magnesium alloys,
    Mater. Sci. Eng. C 23, 757-762 (2003).
  30. C. M. Morais, M. Lopes, C. Fernandez, and J. Rocha
    Assessing the potential of fast amplitude modulation pulses for improving triple-quantum magic angle spinning NMR spectra of half-integer quadrupolar nuclei,
    Magn. Reson. Chem. 41, 679-688 (2003).
  31. P. K. Madhu, O. G. Johannessen, K. J. Pike, R. Dupree, M. E. Smith, and M. H. Levitt
    Application of amplitude-modulated radiofrequency fields to the magic-angle spinning NMR of spin-7/2 nuclei,
    J. Magn. Reson. 163, 310-317 (2003).
  32. D. Riou, F. Fayon, and D. Massiot
    Hydrothermal synthesis, structure determination, and solid-state NMR study of the first organically templated scandium phosphate,
    Chem. Mater. 14, 2416-2420 (2002).
  33. C. Tien, E. V. Charnaya, S. Y. Sun, R. R. Wu, S. N. Ivanov, and E. N. Khazanov
    27Al and 45Sc NMR studies of the Y3ScxAl5-xO12 mixed garnets,
    phys. stat. sol. (b) 233, 222-229 (2002).
  34. S. E. Ashbrook and S. Wimperis
    Satellite-transition MAS NMR of spin I = 3/2, 5/2, 7/2, and 9/2 nuclei: sensitivity, resolution, and practical implementation,
    J. Magn. Reson. 156, 269-281 (2002).
  35. J. A. Davies and S. Dutremez
    Solid state NMR studies of d-block and p-block metal nuclei: applications to organometallic and coordination chemistry,
    Coord. Chem. Rev. 114, 201-247 (1992).
  36. A. R. Thompson and E. Oldfield
    Solid-state scandium-45, yttrium-89, and lanthanum-139 NMR spectroscopy,
    J. Chem. Soc., Chem. Commun. 27-29 (1987).

Related bibliography

  1. Catherine E. Housecroft
    Scandium 1993,
    Coord. Chem. Rev. 146, 37-41 (1995).

More solid-state Sc-45 NMR references.

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