Scandium-45 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Sc-45 7/2 100 -22.0 0.30 0.30 -24.290 Sc(NO3)3

Solid-state scandium NMR references

  1. Nasima Kanwal, Henri Colaux, Daniel M. Dawson, Yusuke Nishiyama, and Sharon E. Ashbrook
    Sensitivity improvement in 5QMAS NMR experiments using FAM-N pulses,
    Solid State Nucl. Magn. Reson. 100, 1-10 (2019).
  2. Henri Colaux, Daniel M. Dawson, and Sharon E. Ashbrook
    Investigating FAM-N pulses for signal enhancement in MQMAS NMR of quadrupolar nuclei,
    Solid State Nucl. Magn. Reson. 84, 89-102 (2017).
    Open access
  3. Marcos de Oliveira, Jr., Tássia S. Gonçalves, Cynthia Ferrari, Claudio José Magon, Paulo S. Pizani, Andrea S. S. de Camargo, and Hellmut Eckert
    Structure−property relations in fluorophosphate glasses: An integrated spectroscopic strategy,
    J. Phys. Chem. C 121, 2968-2986 (2017).
  4. R. Giovine, Ch. Volkringer, S. E. Ashbrook, J. Trébosc, D. McKay, Th. Loiseau, J.-P. Amoureux, O. Lafon, and F. Pourpoint
    Solid-state NMR spectroscopy proves the presence of penta-coordinated Sc sites in MIL-100(Sc),
    Chem. Eur. J. 23, 9525-9534 (2017).
  5. Thomas Braeuniger, Andreas J. Hofmann, Igor L. Moudrakovski, Constantin Hoch, and Wolfgang Schnick
    A 45Sc-NMR and DFT calculation study of crystalline scandium compounds,
    Solid State Sciences 51, 1-7 (2016).
  6. Itaru Okinawa and Hitoshi Takamura
    45Sc NMR spectroscopy and first-principles calculation on the symmetry of ScO6 polyhedra in BaO–Sc2O3-based oxides,
    Dalton Trans. 43, 9714-9721 (2014).
  7. Karen E. Johnston, Martin R. Mitchell, Frédéric Blanc, Philip Lightfoot, and Sharon E. Ashbrook
    Structural study of La1-xYxScO3, combining neutron diffraction, solid-state NMR, and first-principles DFT calculations,
    J. Phys. Chem. C 117, 2252-2265 (2013).
  8. C. Merkens, O. Pecher, F. Steuber, S. Eisenhut, A. Görne, F. Haarmann, and U. Englert
    Crystal-to-crystal transformations in a seven-coordinated scandium complex,
    Z. Anorg. Allg. Chem. 639, 340-346 (2013).
  9. C. Vinod Chandran, Jérôme Cuny, Régis Gautier, Laurent Le Pollès, Chris J. Pickard, and Thomas Bräuniger
    Improving sensitivity and resolution of MQMAS spectra: A 45Sc-NMR case study of scandium sulphate pentahydrate,
    J. Magn. Reson. 203, 226-235 (2010).
  10. M. D. Alba, P. Chain, P. Florian, and D. Massiot
    45Sc spectroscopy of solids: Interpretation of quadrupole interaction parameters and chemical shifts,
    J. Phys. Chem. C 114, 12125-12132 (2010).
  11. L. A. O'Dell, K. J. Harris, and R. W. Schurko
    Optimized excitation pulses for the acquisition of static NMR powder patterns from half-integer quadrupolar nuclei,
    J. Magn. Reson. 203, 156-166 (2010).
  12. Ivan Hung, Julien Trébosc, Gina L. Hoatson, Robert L. Vold, Jean-Paul Amoureux, and Zhehong Gan
    Q-shear transformation for MQMAS and STMAS NMR spectra,
    J. Magn. Reson. 201, 81-86 (2009).
  13. Kimberly E. Kelsey, Jonathan F. Stebbins, David M. Singer, Gordon E. Brown Jr., Jed L. Mosenfelder, and Paul D. Asimow
    Cation field strength effects on high pressure aluminosilicate glass structure: Multinuclear NMR and La XAFS results,
    Geochim. Cosmochim. Acta 73, 3914-3933 (2009).
  14. T. Harmening, H. Eckert, and R. Pöttgen
    Defects in half-Heusler type antimonides ScTSb (T = Ni, Pd, Pt) ,
    Solid State Sciences 11, 900-906 (2009).
  15. T. Harmening, H. Eckert, D. Johrendt, and R. Pöttgen
    Centrosymmetric silicide ScNiSi3 - Structure, chemical bonding, and 45Sc solid state NMR,
    Solid State Sciences 10, 544-549 (2008).
  16. T. Brauniger and P. K. Madhu
    Fast amplitude-modulated pulse trains with frequency sweep (SW-FAM) in solid-state NMR of spin-7/2 nuclei,
    J. Magn. Reson. 193, 102-109 (2008).
  17. D. Khabibulin, K. Romanenko, M. Zuev, and O. Lapina
    Solid state NMR characterization of individual compounds and solid solutions formed in Sc2O3-V2O5-Nb2O5-Ta2O5 system,
    Magn. Reson. Chem. 45, 962-970 (2008).
  18. Namjun Kim, Jonathan F. Stebbins, Simona Quartieri, and Roberta Oberti
    Scandium-45 NMR of pyrope-grossular garnets: Resolution of multiple scandium sites and comparison with X-ray diffraction and X-ray absorption spectroscopy,
    Am. Mineral. 92, 1875-1880 (2007).
  19. D. Mohr, A. S. S. de-Camargo, C. C. de-Araujo, and H. Eckert
    Local environment of scandium in aluminophosphate laser glasses: structural studies by solid state NMR spectroscopy,
    J. Mater. Chem. 17, 3733-3738 (2007).
  20. L. Zhang, C. Fehse, H. Eckert, C. Vogt, R. D. Hoffmann, and R. Pöttgen
    Solid state NMR spectroscopy as a probe of structure and bonding in the carbides Sc3TC4 (T = Co, Ni, Ru, Rh, Os, Ir),
    Solid State Sci. 9, 699-705 (2007).
  21. C. P. Sebastian, H. Eckert, and R. Pottgen
    The stannides ScNi1.54(1)Sn and ScNi1.85(1)Sn - Structures, 45Sc NMR and 119Sn Mossbauer spectroscopy,
    Solid State Sci. 9, 357-361 (2007).
  22. A. Y. H. Lo, V. Sudarsan, S. Sivakumar, F. van-Veggel, and R. W. Schurko
    Multinuclear solid-state NMR spectroscopy of doped lanthanum fluoride nanoparticles,
    J. Am. Chem. Soc. 129, 4687-4700 (2007).
  23. N. Kim, C.-H. Hsieh, and J. F. Stebbins
    Scandium coordination in solid oxides and stabilized zirconia: 45Sc NMR,
    Chem. Mater. 18, 3855-3859 (2006).
  24. A. J. Rossini and R. W. Schurko
    Experimental and theoretical studies of 45Sc NMR interactions in solids,
    J. Am. Chem. Soc. 128, 10391-10402 (2006).
  25. T. J. Bastow, T. Mathews, and J. R. Sellar
    Al2O3 solubility in the fast ion conductor 0.88ZrO2-(0.12-x)Sc2O3-xAl2O3 determined by 27Al NMR,
    Solid State Ionics 175, 415-417 (2004).
  26. H. S. Park, I. Bull, L. M. Peng, G. Y. J. Victor, C. P. Grey, and J. B. Parise
    Synthesis and structure determination of a new organically templated scandium fluorophosphate framework and its indium analogue,
    Chem. Mater. 16, 5350-5356 (2004).
  27. V. V. Laguta, M. D. Glinchuk, I. P. Bykov, R. Blinc, and B. Zalar
    NMR study of ionic shifts and polar ordering in the relaxor ferroelectric Pb(Sc1/2Nb1/2)O3,
    Phys. Rev. B 69, 54103/1-54103/9 (2004).
  28. T. Bräuniger, K. Ramaswamy, and P. K. Madhu
    Enhancement of the central-transition signal in static and magic-angle-spinning NMR of quadrupolar nuclei by frequency-swept fast amplitude-modulated pulses,
    Chem. Phys. Lett. 383, 403-410 (2004).
  29. T. J. Bastow and S. Celotto
    Clustering and formation of nano-precipitates in dilute aluminium and magnesium alloys,
    Mater. Sci. Eng. C 23, 757-762 (2003).
  30. C. M. Morais, M. Lopes, C. Fernandez, and J. Rocha
    Assessing the potential of fast amplitude modulation pulses for improving triple-quantum magic angle spinning NMR spectra of half-integer quadrupolar nuclei,
    Magn. Reson. Chem. 41, 679-688 (2003).
  31. P. K. Madhu, O. G. Johannessen, K. J. Pike, R. Dupree, M. E. Smith, and M. H. Levitt
    Application of amplitude-modulated radiofrequency fields to the magic-angle spinning NMR of spin-7/2 nuclei,
    J. Magn. Reson. 163, 310-317 (2003).
  32. D. Riou, F. Fayon, and D. Massiot
    Hydrothermal synthesis, structure determination, and solid-state NMR study of the first organically templated scandium phosphate,
    Chem. Mater. 14, 2416-2420 (2002).
  33. C. Tien, E. V. Charnaya, S. Y. Sun, R. R. Wu, S. N. Ivanov, and E. N. Khazanov
    27Al and 45Sc NMR studies of the Y3ScxAl5-xO12 mixed garnets,
    phys. stat. sol. (b) 233, 222-229 (2002).
  34. S. E. Ashbrook and S. Wimperis
    Satellite-transition MAS NMR of spin I = 3/2, 5/2, 7/2, and 9/2 nuclei: sensitivity, resolution, and practical implementation,
    J. Magn. Reson. 156, 269-281 (2002).
  35. J. A. Davies and S. Dutremez
    Solid state NMR studies of d-block and p-block metal nuclei: applications to organometallic and coordination chemistry,
    Coord. Chem. Rev. 114, 201-247 (1992).
  36. A. R. Thompson and E. Oldfield
    Solid-state scandium-45, yttrium-89, and lanthanum-139 NMR spectroscopy,
    J. Chem. Soc., Chem. Commun. 27-29 (1987).

Related bibliography

  1. Catherine E. Housecroft
    Scandium 1993,
    Coord. Chem. Rev. 146, 37-41 (1995).

More solid-state Sc-45 NMR references.

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