Bromine-79 and bromine-81 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Br-79 3/2 50.54 31.3 7.86E-2 3.97E-2 -25.053 NaBr
Br-81 3/2 49.46 26.2 9.85E-2 4.87E-2 -27.006

Solid-state bromine NMR references

  1. Pinhui Chen, Brice J. Albert, Chukun Gao, Nicholas Alaniva, Lauren E. Price, Faith J. Scott, Edward P. Saliba, Erika L. Sesti, Patrick T. Judge, Edward W. Fisher, and Alexander B. Barnes
    Magic angle spinning spheres,
    Sci. Adv. 4, 1-7 (2018).
  2. Frédéric A. Perras, Cory M. Widdifield, and David L. Bryce
    QUEST—QUadrupolar Exact SofTware: A fast graphical program for the exact simulation of NMR and NQR spectra for quadrupolar nuclei,
    Solid State Nucl. Magn. Reson. 45-46, 36-44 (2012).
  3. C. M. Widdifield and D. L. Bryce
    Solid-state 79/81Br NMR and gauge-including projector-augmented wave study of structure, symmetry, and hydration state in alkaline earth metal bromides,
    J. Phys. Chem. A 114, 2102-2116 (2010).
  4. Kent R. Thurber and Robert Tycko
    Measurement of sample temperatures under magic-angle spinning from the chemical shift and spin-lattice relaxation rate of 79Br in KBr powder,
    J. Magn. Reson. 196, 84-87 (2009).
  5. C. M. Widdifield and D. L. Bryce
    Crystallographic structure refinement with quadrupolar nuclei: a combined solid-state NMR and GIPAW DFT example using MgBr2,
    Phys. Chem. Chem. Phys. 11, 7120-7122 (2009).
  6. C. M. Widdifield, R. P. Chapman, and D. L. Bryce
    Chlorine, bromine, and iodine solid-state NMR spectroscopy,
    Annu. Rep. Nucl. Magn. Reson. Spectrosc. 66, 195-326 (2009).
  7. R. P. Chapman, C. M. Widdifield, and D. L. Bryce
    Solid-state NMR of quadrupolar halogen nuclei,
    Prog. Nucl. Magn. Reson. Spectrosc. 55, 215-237 (2009).
  8. J. Persons and G. S. Harbison
    Slow turning reveals enormous quadrupolar interactions (STREAQI),
    J. Magn. Reson. 186, 347-351 (2007).
  9. D. L. Bryce and G. D. Sward
    Solid-state NMR spectroscopy of the quadrupolar halogens: chlorine-35/37, bromine-79/81, and iodine-127,
    Magn. Reson. Chem. 44, 409-450 (2006).
  10. D. L. Bryce, G. M. Bernard, M. Gee, M. D. Lumsden, K. Eichele, and R. Wasylishen
    Practical aspects of modern routine solid-state multinuclear magnetic resonance spectroscopy: one-dimensional experiments,
    Can. J. Anal. Sci. Spectrosc. 46, 46-82 (2001).
  11. S. Hayashi and K. Hayamizu
    Effect of spinning on chemical shifts in magic-angle-spinning nuclear magnetic resonance,
    J. Chem. Phys. 92, 2818-2827 (1990).
  12. P. Brenni, D. Brinkmann, H. Huber, M. Mali, J. Roos, and H. Arend
    Detection of a second Br site in K2Pt(CN)4 Br0.3 3.2H2O (KCP) by 81Br and 39K NMR,
    Solid State Commun. 47, 415-418 (1983).
  13. J. S. Frye and G. E. Maciel
    Setting the magic angle using a quadrupolar nuclide,
    J. Magn. Reson. 48, 125-131 (1982).

Related bibliography

  1. B. Nagasaka, S. Takeda, and N. Nakamura
    Residual dipolar splittings in 13C CP/MAS NMR spectra due to quadrupolar halogen nuclei in uracil halides,
    Chem. Phys. Lett. 222, 486-492 (1994).

More solid-state Br-79/81 NMR references.

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