Molybdenum-95 and molybdenum-97 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Mo-95 5/2 15.72 -2.2 3.23E-3 5.07E-4 -6.514 Na2MoO4
Mo-97 5/2 9.46 25.5 3.43E-3 3.24E-4 6.652

Solid-state molybdenum NMR references

  1. Hiroki Nagashima, Julien Trébosc, Yoshihiro Kon, Kazuhiko Sato, Olivier Lafon, and Jean-Paul Amoureux
    Observation of low-γ quadrupolar nuclei by surface-enhanced NMR spectroscopy,
    J. Am. Chem. Soc. 142, 10659-10672 (2020).
  2. S. Kroeker, C. S. Higman, V. K. Michaelis, N. B. Svenda, and S. Schuller
    Precipitation of mixed-alkali molybdates during HLW vitrification,
    Mater. Res. Soc. Symp. Proc. 1265, AA03-03-09 (2010).
  3. Scott Kroeker, Ian Farnan, Sophie Schuller, and Thierry Advocat
    95Mo NMR study of crystallization in model nuclear waste glasses,
    Mater. Res. Soc. Symp. Proc. 1124, 1124Q03-06 (2009).
  4. M. A. M. Forgeron and R. E. Wasylishen
    Molybdenum magnetic shielding and quadrupolar tensors for a series of molybdate salts: a solid-state 95Mo NMR study,
    Phys. Chem. Chem. Phys. 10, 574-581 (2008).
  5. S. H. Santagneli, C. C. de-Araujo, W. Strojek, H. Eckert, G. Poirier, S. J. L. Ribeiro, and Y. Messaddeq
    Structural studies of NaPO3-MoO3 glasses by solid-state nuclear magnetic resonance and raman spectroscopy,
    J. Phys. Chem. B 111, 10109-10117 (2007).
  6. A. Montesinos-Castellanos, E. Lima, J. A. de-los-Reyes, and L. Lara
    Fractal dimension of MoP-Al2O3 catalysts and their activity in hydrodesulfurization of dibenzothiophene,
    J. Phys. Chem. B 111, 13898-13904 (2007).
  7. M. A. M. Forgeron and R. E. Wasylishen
    A solid-state 95Mo NMR and computational investigation of dodecahedral and square antiprismatic octacyanomolybdate(IV) anions: Is the point-charge approximation an accurate probe of local symmetry?,
    J. Am. Chem. Soc. 128, 7817-7827 (2006).
  8. S. Colis, D. Stoeffler, C. Meny, T. Fix, C. Leuvrey, G. Pourroy, A. Dinia, and P. Panissod
    Structural defects in Sr2FeMoO6 double perovskite: Experimental versus theoretical approach,
    J. Appl. Phys. 98, 33905/1-33905/11 (2005).
  9. J.-B. d'Espinose de Lacaillerie, F. Barberon, K. V. Romanenko, O. B. Lapina, L. Le Pollès, R. Gautier, and Z. Gan
    95Mo magic angle spinning NMR at high field: Improved measurements and structural analysis of the quadrupole interaction in monomolybdates and isopolymolybdates,
    J. Phys. Chem. B 109, 14033-14042 (2005).
  10. D. Zajac, Cz. Kapusta, P. C. Riedi, M. Sikora, C. J. Oates, D. Rybicki, J. M. De Teresa, D. Serrate, C. Marquina, and M. R. Ibarra
    NMR study of (Sr, Ba, La)2Fe1+yMo1-yO6 double perovskites,
    Acta Phys. Pol. A 106, 759-765 (2004).
  11. D. L. Bryce and R. E. Wasylishen
    A 95Mo and 13C solid-state NMR and relativistic DFT investigation of mesitylenetricarbonyl molybdenum(0) - a typical transition metal piano-stool complex,
    Phys. Chem. Chem. Phys. 4, 3591-3600 (2002).
  12. T. J. Bastow
    95Mo NMR: hyperfine interactions in MoO3, MoS2, MoSe2, Mo3Se4, MoSi2 and Mo2C,
    Solid State Nucl. Magn. Reson. 12, 191-199 (1998).
  13. K. Eichele, R. E. Wasylishen, and J. H. Nelson
    Solid state 95Mo NMR studies of some prototypal molybdenum compounds: sodium molybdate dihydrate, hexacarbonylmolybdenum, and pentacarbonyl phosphine molybdenum(0) complexes,
    J. Phys. Chem. A 101, 5463-5468 (1997).
  14. O. H. Han, C. Y. Lin, and G. L. Haller
    Hydration effects of Al2(MoO4)3 and AlPO4 phases in hydrotraiting catalysts studied by solid state NMR spectroscopy,
    Catal. Lett. 14, 1-9 (1992).
  15. J. C. Edwards and P. D. Ellis
    Solid-state 95Mo NMR study of hydrodesulfurization catalysts. 2. Investigation of reduced/sulfided molybdena-alumina catalysts and the effect of promoter ions on "fresh" and reduced/sulfided molybdena-alumina catalysts,
    Langmuir 7, 2117-2134 (1991).

Related bibliography

  1. Jérôme Cuny, Eric Furet, Régis Gautier, Laurent Le Pollès, Chris J. Pickard, and Jean-Baptiste d’Espinose de Lacaillerie
    Density functional theory calculations of 95Mo NMR parameters in solid-state compounds,
    ChemPhysChem 1265, 3320-3329 (2009).
  2. Raisa I. Maksimovskaya and Gennady M. Maksimov
    95Mo and 17O NMR studies of aqueous molybdate solutions,
    Inorg. Chem. 46, 3688-3695 (2007).
  3. Michael J. Morris
    Molybdenum 1993,
    Coord. Chem. Rev. 146, 43-97 (1995).
  4. Martin Minelli, John H.Enemark, Robert T. C. Brownlee, Maxwell J. O’connor, and Anthony G.Wedd
    The nuclear magnetic resonance properties of chromium, molybdenum and tungsten compounds,
    Coord. Chem. Rev. 68, 169-278 (1985).

More solid-state Mo-95/97 NMR references.

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