Calcium-43 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Ca-43 7/2 0.145 -4.08 6.40E-3 9.28E-6 6.728 CaCl2

Solid-state calcium NMR references

  1. Danielle Laurencin, Yang Li, Melinda Duer, Dinu Iuga, Christel Gervais, and Christian Bonhomme
    A 43Ca nuclear magnetic resonance perspective on octacalcium phosphate and its hybrid derivatives,
    Magn. Reson. Chem. 59, 1048-1061 (2021).
  2. H. Colas, L. Bonhomme-Coury, C. Coelho Diogo, F. Tielens, F. Babonneau, C. Gervais, D. Bazin, D. Laurencin, M. E. Smith, J. V. Hanna, M. Daudon, and C. Bonhomme
    Whewellite, CaC2O4·H2O: structural study by a combined NMR, crystallography and modelling approach,
    CrystEngComm 15, 8840-8847 (2013).
  3. Danielle Laurencin and Mark E. Smith
    Development of 43Ca solid state NMR spectroscopy as a probe of local structure in inorganic and molecular materials,
    Prog. Nucl. Magn. Reson. Spectrosc. 68, 1-40 (2013).
  4. Yu-Chieh Huang, Yun Mou, Tim Wen-Tin Tsai, Yu-Ju Wu, Hsin-Kuan Lee, Shing-Jong Huang, and Jerry C. C. Chan
    Calcium-43 NMR studies of polymorphic transition of Calcite to Aragonite,
    J. Phys. Chem. B 116, 14295-14301 (2012).
  5. A. Wong, P. M. Aguiar, T. Charpentier, and D. Sakellariou
    A low-cost strategy for 43Ca solid-state NMR spectroscopy,
    Chem. Sci. 2, 815-818 (2011).
  6. D. L. Bryce
    Calcium binding environments probed by 43Ca NMR spectroscopy,
    Dalton Trans. 39, 8593-8602 (2010).
  7. Alan Wong, Danielle Laurencin, Ray Dupree, and Mark E. Smith
    Two-dimensional 43Ca–1H correlation solid-state NMR spectroscopy,
    Solid State Nucl. Magn. Reson. 35, 32-36 (2009).
  8. G. M. Bowers and R. J. Kirkpatrick
    Natural abundance 43Ca NMR spectroscopy of tobermorite and jennite: Models for the C-S-H structure,
    J. Am. Ceram. Soc. 92, 545-548 (2009).
  9. D. L. Bryce, E. B. Bultz, and D. Aebi
    Calcium-43 chemical shift tensors as probes of calcium binding environments. Insight into the structure of the Vaterite CaCO3 polymorph by 43Ca solid-state NMR spectroscopy.,
    J. Am. Chem. Soc. 130, 9282-9292 (2008).
  10. D. Laurencin, A. Wong, R. Dupree, and M. E. Smith
    Natural abundance 43Ca solid-state NMR characterisation of hydroxyapatite: identification of the two calcium sites,
    Magn. Reson. Chem. 46, 347-350 (2008).
  11. D. Laurencin, A. Wong, J. V. Hanna, R. Dupree, and M. E. Smith
    A high-resolution 43Ca solid-state NMR study of the calcium sites of hydroxyapatite,
    J. Am. Chem. Soc. 130, 2412-24113 (2008).
  12. Kenneth J. D. MacKenzie, Mark E. Smith, and Alan Wong
    A multinuclear MAS NMR study of calcium-containing aluminosilicate inorganic polymers,
    J. Mater. Chem. 17, 5090-5096 (2007).
  13. F. Angeli, M. Gaillard, P. Jollivet, and T. Charpentier
    Contribution of 43Ca MAS NMR for probing the structural configuration of calcium in glass,
    Chem. Phys. Lett. 440, 324-328 (2007).
  14. K. Shimoda, Y. Tobu, Y. Shimoikeda, T. Nemoto, and K. Saito
    Multiple Ca2+ environments in silicate glasses by high-resolution 43Ca MQMAS NMR technique at high and ultra-high (21.8 T) magnetic fields,
    J. Magn. Reson. 186, 156-159 (2007).
  15. K. Shimoda, Y. Tobu, K. Kanehashi, K. Saito, and T. Nemoto
    First evidence of multiple Ca sites in amorphous slag structure: Multiple-quantum MAS NMR spectroscopy on calcium-43 at high magnetic field,
    Solid State Nucl. Magn. Reson. 30, 198-202 (2006).
  16. A. Wong, A. P. Howes, R. Dupree, and M. E. Smith
    Natural abundance 43Ca NMR study of calcium-containing organic solids: A model study for Ca-binding biomaterials,
    Chem. Phys. Lett. 427, 201-205 (2006).
  17. Z. J. Lin, M. E. Smith, F. E. Sowrey, and R. J. Newport
    Probing the local structural environment of calcium by natural-abundance solid-state 43Ca NMR,
    Phys. Rev. B 69, 224107/1-224107/7 (2004).
  18. S. Marchand, A. Trokiner, A. Yakubovskii, P. Monod, A. Knizhnik, and Y. Eckstein
    43Ca NMR study of the doping effects in the high temperature superconductor (La1-xCax)(Ba1.75-xLa0.25+x)Cu3Oy,
    C. R. Acad. Sci. Paris, Chimie 4, 819-824 (2001).
  19. A. Trokiner, P.-V. Bellot, Y. Zhdanov, and A. Yakubovskii
    NMR determination of the Sternheimer antishielding factor of Ca2+,
    Solid State Nucl. Magn. Reson. 16, 171-175 (2000).
  20. R. Dupree, A. P. Howes, and S. C. Kohn
    Natural abundance solid state 43Ca NMR,
    Chem. Phys. Lett. 276, 399-404 (1997).
  21. A. Trokiner, L. Le Noc, A. Yakubovskii, K. N. Mykhalyov, and S. V. Verkhovskii
    43Ca NMR study of bismuth-based high-Tc superconductors,
    Z. Naturforsch. 49a, 373-378 (1993).

More solid-state Ca-43 NMR references.

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