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> Periodic Table
> Vanadium
| Isotope | Spin | Natural abundance(%) |
Quadrupole moment (10-30m2) |
Relative sensitivity |
Absolute sensitivity |
NMR frequency (MHz) at a field of 2.3488T |
Reference sample |
|---|---|---|---|---|---|---|---|
| V-50 | 6 | 0.24 | 21.0 | 5.55E-2 | 1.33E-4 | -9.970 | VOCl3 |
| V-51 | 7/2 | 99.76 | -5.2 | 0.38 | 0.38 | -26.289 |
| Directory of solid-state V-51 NMR references | ||
|---|---|---|
| Single Crystal |
Crystalline Powder Complex, Oxide, V2O5 |
Amorphous Powder |
Solid-state vanadium NMR references
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Dieter Rehder, Tatyana Polenova, and Michael Buhl
Vanadium-51 NMR,
Annu. Rep. NMR Spectros. 62, 49-114 (2007).
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Kristopher J. Ooms, Stephanie E. Bolte, Jason J. Smee, Bharat Baruah,
Debbie C. Crans, and Tatyana Polenova
Investigating the vanadium environments in hydroxylamido V(V) dipicolinate complexes using 51V NMR spectroscopy and density functional theory,
Inorg. Chem. 46, 9285-9293 (2007).
-
Z. Szalay and J. Rohonczy
A multinuclear NMR study of sodium-borovanadophosphate glasses,
J. Non-Cryst. Solids 353, 295-301 (2007).
rohonczy@chem.elte.hu
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K. Scheurell, G. Scholz, and E. Kemnitz
Structural study of VOx doped aluminium fluoride and aluminium oxide catalysts,
Solid State Chem. 180, 749-758 (2007).
erhard.kemnitz@chemie.hu-berlin.de
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S. Ferdov, Z. Lin, and R. A. S. Ferreira
Incorporation of mixed valence vanadium in the microporous titanosilicate AM-2,
Microporous Mesoporous Mater. 96, 363-368 (2006).
zlin@dq.ua.pt
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Becky Gee
Vanadium-51 solid state NMR electric field gradient tensors: A DFT embedded ion and isolated cluster study of crystalline vanadium oxides,
Solid State Nucl. Magn. Reson. 30, 171-181 (2006).
bgee@liu.edu
-
S. Shylesh and A. P. Singh
Vanadium-containing ethane-silica hybrid periodic mesoporous organosilicas: Synthesis, structural characterization and catalytic applications,
Microporous Mesoporous Mater. 94, 127-138 (2006).
ap.singh@ncl.res.in
-
T. Radhika and S. Sugunan
Structural and catalytic investigation of vanadia supported on ceria promoted with high surface area rice husk silica,
J. Phys. Chem. A 250, 169-176 (2006).
ssg@cusat.ac.in
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N. Pooransingh-Margolis, R. Renirie, Z. Hasan, R. Wever, A. J. Vega,
and T. Polenova
51V solid-state magic angle spinning NMR spectroscopy of vanadium chloroperoxidase,
J. Am. Chem. Soc. 128, 5190-5208 (2006).
tpolenov@chem.udel.edu
-
D. Capsoni, M. Bini, V. Massarotti, P. Mustarelli, F. Belotti, and P. Galinetto
Cation distribution in LiMgVO4 and LiZnVO4: Structural and spectroscopic study,
J. Phys. Chem. B 110, 5409-5415 (2006).
vincenzo.massarotti@unipv.it
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K. Nakamura, D. Nishioka, Y. Michihiro, M. Vijayakumar, S. Selvasekarapandian,
and T. Kanashiro
7Li and 51V NMR study on Li+ ionic diffusion in lithium intercalated LixV2O5,
Solid State Ionics 177, 129-135 (2006).
koichi@pm.tokushima-u.ac.jp
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Stanislaw Dzwigaj and Michel Che
Oxidation state of vanadium introduced in dealuminated zeolite by impregnation with VIVOSO4 solution: influence of preparation parameters,
J. Phys. Chem. B 109, 22167-22174 (2005).
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O. Durupthy, M. Jaber, N. Steunou, J. Maquet, G. T. Chandrappa, and J. Livage
Vanadium oxide foams: An insight into the structure of the vanadium oxide walls,
Chem. Mater. 17, 6395-6402 (2005).
durupthy@ccr.jussieu.fr; steunou@ccr.jussieu.fr
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R. Michalak and H. A. H. Mohammad
51V-NMR and 51T1(T) of charge ordering and spin gap in alpha'-NaV2O5,
Solid State NMR 26, 187-196 (2004).
rudim@engr.colostate.edu
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P. E. Stallworth, X. Guo, E. Tatham, S. G. Greenbaum, M. Arrabito,
S. Bodoarado, and N. Penazzi
A solid-state 51V NMR characterization of vanadium sites in LiCoxNi1-xVO4,
Solid State Ionics 170, 181-186 (2004).
steve.greenbaum@hunter.cuny.edu
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B. A. Gee and A. Wong
Vanadium-51 MAS and static NMR studies of the binary V2O5-WO3 system,
J. Phys. Chem. B 107, 8382-8387 (2003).
bgee@liu.edu
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O. B. Lapina, A. A. Shubin, D. F. Khabibulin, V. V. Terskikh,
P. R. Bodart, and J.-P. Amoureux
Solid-state 51V NMR for characterization of vanadium-containing systems,
Catal. Today 78, 91-104 (2003).
olga@catalysis.nsk.su
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U. G. Nielsen, H. J. Jakobsen, and J. Skibsted
Small 51V chemical shift anisotropy for LaVO4 from MQMAS and MAS NMR spectroscopy,
Solid State NMR 23, 107-115 (2003).
jskib@chem.au.dk
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B. Sulikowski, Z. Olejniczak, E. Wloch, J. Rakoczy, R. X. Valenzuela, and V. Cortés Corberán
Oxidative dehydrogenation of isobutane on MCM-41 mesoporous molecular sieves,
Appl. Catal. A 232, 189-202 (2002).
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U. G. Nielsen, A. Boisen, M. Brorson, C. J. H. Jacobsen,
H. J. Jakobsen, and J. Skibsted
Aluminum orthovanadate (AlVO4): Synthesis and characterization by 27Al and 51V MAS and MQMAS NMR spectroscopy,
Inorg. Chem. 41, 6432-6439 (2002).
jskib@chem.au.dk
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C. J. Fontenot, J. W. Wiench, G. L. Schrader, and M. Pruski
17O MAS and 3QMAS NMR investigation of crystalline V2O5 and layered V2O5 nH2O gels,
J. Am. Chem. Soc. 124, 8435-8444 (2002).
mpruski@iastate.edu
-
N. Kim and C. P. Grey
Probing oxygen motion in disordered anionic conductors with 17O and 51V MAS NMR spectroscopy,
Science 297, 1317-1320 (2002).
-
U. G. Nielsen, J. Skibsted, and H. J. Jakobsen
ß-VO2 - a V(IV) or a mixed-valence V(III)-V(V) oxide - studied by 51V MAS NMR spectroscopy,
Chem. Phys. Lett. 356, 73-78 (2002).
hja@chem.au.dk
-
Becky Gee
Homonuclear vanadium-51 dipolar couplings in inorganic solids obtained via Hahn spin echo decay NMR spectroscopy,
Solid State NMR 19, 73-86 (2001).
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J. Spengler, F. Anderle, E. Bosch, R. K. Grasselli, B. Pillep,
P. Behrens, O. B. Lapina, A. A. Shubin, H.-J. Eberle, and H. Knözinger
Antimony oxide-modified vanadia-based catalysts -- Physical characterization and catalytic properties,
J. Phys. Chem. B 105, 10772-10783 (2001).
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R. D. Gougeon, E. B. Brouwer, P. R. Bodart, L. Delmotte, C. Marichal,
J.-M. Chézeau, and R. K. Harris
Solid-state NMR studies of the as-synthesized AlPO4-5/TPAF microporous aluminophosphate,
J. Phys. Chem. B 105, 12249-12256 (2001).
r.k.harris@durham.ac.uk
Related bibliography
-
Ashok K. Kakkar and Muhammad S. Khan
Vanadium 1990,
Coord. Chem. Rev. 146, 203-210 (1995).
Solid-state NMR bibliography for
- Aluminum-27 (鋁)
- Antimony-121/123 (銻)
- Arsenic-75 (砷)
- Barium-135/137 (鋇)
- Beryllium-9 (鈹)
- Bismuth-209 (鉍)
- Boron-11 (硼)
- Bromine-79/81 (溴)
- Calcium-43 (鈣)
- Cesium-133 (銫)
- Chlorine-35/37 (氯)
- Chromium-53 (鉻)
- Cobalt-59 (鈷)
- Copper-63/65 (銅)
- Deuterium-2 (氘)
- Gallium-69/71 (鎵)
- Germanium-73 (鍺)
- Gold-197 (金)
- Hafnium-177/179 (鉿)
- Indium-113-115 (銦)
- Iodine-127 (碘)
- Iridium-191/193 (銥)
- Krypton-83 (氪)
- Lanthanum-139 (鑭)
- Lithium-6/7 (鋰)
- Magnesium-25 (鎂)
- Manganese-55 (錳)
- Mercury-201 (銾)
- Molybdenum-95/97 (鉬)
- Neon-21 (氖)
- Nickel-61 (鎳)
- Niobium-93 (鈮)
- Nitrogen-14 (氮)
- Osmium-189 (鋨)
- Oxygen-17 (氧)
- Palladium-105 (鈀)
- Potassium-39/41 (鉀)
- Rhenium-185/187 (錸)
- Rubidium-85/87 (銣)
- Ruthenium-99/101 (釕)
- Scandium-45 (鈧)
- Sodium-23 (鈉)
- Strontium-87 (鍶)
- Sulfur-33 (硫)
- Tantalum-181 (鉭)
- Titanium-47/49 (鈦)
- Vanadium-51 (釩)
- Xenon-131 (氥)
- Zinc-67 (鋅)
- Zirconium-91 (鋯)
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