Vanadium-51 NMR




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Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
V-50 6 0.24 21.0 5.55E-2 1.33E-4 -9.970 VOCl3
V-51 7/2 99.76 -5.2 0.38 0.38 -26.289

Directory of solid-state V-51 NMR references
Single Crystal Crystalline Powder
Complex, Oxide, V2O5
Amorphous Powder

Solid-state vanadium NMR references

  1. Dieter Rehder, Tatyana Polenova, and Michael Buhl
    Vanadium-51 NMR,
    Annu. Rep. NMR Spectros. 62, 49-114 (2007).
     
  2. Kristopher J. Ooms, Stephanie E. Bolte, Jason J. Smee, Bharat Baruah, Debbie C. Crans, and Tatyana Polenova
    Investigating the vanadium environments in hydroxylamido V(V) dipicolinate complexes using 51V NMR spectroscopy and density functional theory,
    Inorg. Chem. 46, 9285-9293 (2007).
     
  3. Z. Szalay and J. Rohonczy
    A multinuclear NMR study of sodium-borovanadophosphate glasses,
    J. Non-Cryst. Solids 353, 295-301 (2007).
    rohonczy@chem.elte.hu
     
  4. K. Scheurell, G. Scholz, and E. Kemnitz
    Structural study of VOx doped aluminium fluoride and aluminium oxide catalysts,
    Solid State Chem. 180, 749-758 (2007).
    erhard.kemnitz@chemie.hu-berlin.de
     
  5. S. Ferdov, Z. Lin, and R. A. S. Ferreira
    Incorporation of mixed valence vanadium in the microporous titanosilicate AM-2,
    Microporous Mesoporous Mater. 96, 363-368 (2006).
    zlin@dq.ua.pt
     
  6. Becky Gee
    Vanadium-51 solid state NMR electric field gradient tensors: A DFT embedded ion and isolated cluster study of crystalline vanadium oxides,
    Solid State Nucl. Magn. Reson. 30, 171-181 (2006).
    bgee@liu.edu
     
  7. S. Shylesh and A. P. Singh
    Vanadium-containing ethane-silica hybrid periodic mesoporous organosilicas: Synthesis, structural characterization and catalytic applications,
    Microporous Mesoporous Mater. 94, 127-138 (2006).
    ap.singh@ncl.res.in
     
  8. T. Radhika and S. Sugunan
    Structural and catalytic investigation of vanadia supported on ceria promoted with high surface area rice husk silica,
    J. Phys. Chem. A 250, 169-176 (2006).
    ssg@cusat.ac.in
     
  9. N. Pooransingh-Margolis, R. Renirie, Z. Hasan, R. Wever, A. J. Vega, and T. Polenova
    51V solid-state magic angle spinning NMR spectroscopy of vanadium chloroperoxidase,
    J. Am. Chem. Soc. 128, 5190-5208 (2006).
    tpolenov@chem.udel.edu
     
  10. D. Capsoni, M. Bini, V. Massarotti, P. Mustarelli, F. Belotti, and P. Galinetto
    Cation distribution in LiMgVO4 and LiZnVO4: Structural and spectroscopic study,
    J. Phys. Chem. B 110, 5409-5415 (2006).
    vincenzo.massarotti@unipv.it
     
  11. K. Nakamura, D. Nishioka, Y. Michihiro, M. Vijayakumar, S. Selvasekarapandian, and T. Kanashiro
    7Li and 51V NMR study on Li+ ionic diffusion in lithium intercalated LixV2O5,
    Solid State Ionics 177, 129-135 (2006).
    koichi@pm.tokushima-u.ac.jp
     
  12. Stanislaw Dzwigaj and Michel Che
    Oxidation state of vanadium introduced in dealuminated zeolite by impregnation with VIVOSO4 solution: influence of preparation parameters,
    J. Phys. Chem. B 109, 22167-22174 (2005).
     
  13. O. Durupthy, M. Jaber, N. Steunou, J. Maquet, G. T. Chandrappa, and J. Livage
    Vanadium oxide foams: An insight into the structure of the vanadium oxide walls,
    Chem. Mater. 17, 6395-6402 (2005).
    durupthy@ccr.jussieu.fr; steunou@ccr.jussieu.fr
     
  14. R. Michalak and H. A. H. Mohammad
    51V-NMR and 51T1(T) of charge ordering and spin gap in alpha'-NaV2O5,
    Solid State NMR 26, 187-196 (2004).
    rudim@engr.colostate.edu
     
  15. P. E. Stallworth, X. Guo, E. Tatham, S. G. Greenbaum, M. Arrabito, S. Bodoarado, and N. Penazzi
    A solid-state 51V NMR characterization of vanadium sites in LiCoxNi1-xVO4,
    Solid State Ionics 170, 181-186 (2004).
    steve.greenbaum@hunter.cuny.edu
     
  16. B. A. Gee and A. Wong
    Vanadium-51 MAS and static NMR studies of the binary V2O5-WO3 system,
    J. Phys. Chem. B 107, 8382-8387 (2003).
    bgee@liu.edu
     
  17. O. B. Lapina, A. A. Shubin, D. F. Khabibulin, V. V. Terskikh, P. R. Bodart, and J.-P. Amoureux
    Solid-state 51V NMR for characterization of vanadium-containing systems,
    Catal. Today 78, 91-104 (2003).
    olga@catalysis.nsk.su
     
  18. U. G. Nielsen, H. J. Jakobsen, and J. Skibsted
    Small 51V chemical shift anisotropy for LaVO4 from MQMAS and MAS NMR spectroscopy,
    Solid State NMR 23, 107-115 (2003).
    jskib@chem.au.dk
     
  19. B. Sulikowski, Z. Olejniczak, E. Wloch, J. Rakoczy, R. X. Valenzuela, and V. Cortés Corberán
    Oxidative dehydrogenation of isobutane on MCM-41 mesoporous molecular sieves,
    Appl. Catal. A 232, 189-202 (2002).
     
  20. U. G. Nielsen, A. Boisen, M. Brorson, C. J. H. Jacobsen, H. J. Jakobsen, and J. Skibsted
    Aluminum orthovanadate (AlVO4): Synthesis and characterization by 27Al and 51V MAS and MQMAS NMR spectroscopy,
    Inorg. Chem. 41, 6432-6439 (2002).
    jskib@chem.au.dk
     
  21. C. J. Fontenot, J. W. Wiench, G. L. Schrader, and M. Pruski
    17O MAS and 3QMAS NMR investigation of crystalline V2O5 and layered V2O5 nH2O gels,
    J. Am. Chem. Soc. 124, 8435-8444 (2002).
    mpruski@iastate.edu
     
  22. N. Kim and C. P. Grey
    Probing oxygen motion in disordered anionic conductors with 17O and 51V MAS NMR spectroscopy,
    Science 297, 1317-1320 (2002).
     
  23. U. G. Nielsen, J. Skibsted, and H. J. Jakobsen
    ß-VO2 - a V(IV) or a mixed-valence V(III)-V(V) oxide - studied by 51V MAS NMR spectroscopy,
    Chem. Phys. Lett. 356, 73-78 (2002).
    hja@chem.au.dk
     
  24. Becky Gee
    Homonuclear vanadium-51 dipolar couplings in inorganic solids obtained via Hahn spin echo decay NMR spectroscopy,
    Solid State NMR 19, 73-86 (2001).
     
  25. J. Spengler, F. Anderle, E. Bosch, R. K. Grasselli, B. Pillep, P. Behrens, O. B. Lapina, A. A. Shubin, H.-J. Eberle, and H. Knözinger
    Antimony oxide-modified vanadia-based catalysts -- Physical characterization and catalytic properties,
    J. Phys. Chem. B 105, 10772-10783 (2001).
     
  26. R. D. Gougeon, E. B. Brouwer, P. R. Bodart, L. Delmotte, C. Marichal, J.-M. Chézeau, and R. K. Harris
    Solid-state NMR studies of the as-synthesized AlPO4-5/TPAF microporous aluminophosphate,
    J. Phys. Chem. B 105, 12249-12256 (2001).
    r.k.harris@durham.ac.uk
     

Related bibliography

  1. Ashok K. Kakkar and Muhammad S. Khan
    Vanadium 1990,
    Coord. Chem. Rev. 146, 203-210 (1995).
     
 
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