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> Lithium
| Isotope | Spin | Natural abundance(%) |
Quadrupole moment (10-30m2) |
Relative sensitivity |
Absolute sensitivity |
NMR frequency (MHz) at a field of 2.3488T |
Reference sample |
|---|---|---|---|---|---|---|---|
| Li-6 | 1 | 7.42 | -0.0808 | 8.50E-3 | 6.31E-4 | -14.716 | LiCl |
| Li-7 | 3/2 | 92.58 | -4.01 | 0.29 | 0.27 | -38.863 |
| Directory of solid-state Li-6 and lithium-7 NMR references | ||
|---|---|---|
| Single Crystal |
Crystalline Powder Oxide, Zeolite |
Amorphous Powder |
Solid-state lithium NMR references
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L. S. Cahill, C. W. Kirby, and G. R. Goward
6Li{31P} rotational-echo, double-resonance studies of lithium ion site dynamics in Li3V2(PO4)3,
J. Phys. Chem. C 112, 2215-2221 (2008).
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M. Wilkening and P. Heitjans
Li jump process in h-Li0.7TiS2 studied by two-time 7Li spin-alignment echo NMR and comparison with results on two-dimensional diffusion from nuclear magnetic relaxation,
Phys. Rev. B 77, 24311/1-24311/13 (2008).
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M. Wilkening, D. Gebauer, and P. Heitjans
Diffusion parameters in single-crystalline Li3N as probed by 6Li and 7Li spin-alignment echo NMR spectroscopy in comparison with results from 8Li β-radiation detected NMR,
J. Phys.: Condens. Matter 20, 22201/1-22201/5 (2008).
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G. T. K. Fey, P. Muralidharan, Y. D. Cho, P. C. Chang, H. M. Kao
Electrochemical performance and 7Li NMR studies on an inverse spinel LiNi1/3Co1/3Mn1/3VO4 for Li-ion batteries,
J. Power Sources 174, 1142-1146 (2007).
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Paul Heitjans, Muayad Masoud, Armin Feldhoff, and Martin Wilkening
NMR and impedance studies of nanocrystalline and amorphous ion conductors: lithium niobate as a model system,
Faraday Discuss. 134, 67-82 (2007).
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J. Wontcheu, W. Bensch, M. Wilkening, P. Heitjans, S. Indris, P. Sideris,
C. P. Grey, S. Mankovsky, and H. Ebert
Tuning the structural and physical properties of Cr2Ti3Se8 by lithium intercalation: A study of the magnetic properties and investigation of ion mobility with NMR spectroscopy,
J. Am. Chem. Soc. 130, 288-299 (2007).
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M. Wilkening, W. Iwaniak, J. Heine, V. Epp, A. Kleinert, M. Behrens,
G. Nuspl, W. Bensch, and P. Heitjans
Microscopic Li self-diffusion parameters in the lithiated anode material Li4+xTi5O12 (0 ≤ x ≤ 3) measured by 7Li solid state NMR ,
Phys. Chem. Chem. Phys. 9, 6199-6202 (2007).
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D. L. Zeng, J. Cabana, J. L. Breger, W. S. Yoon, and C. P. Grey
Cation ordering in Li[NixMnxCo(1-2x)]O2-layered cathode materials: A nuclear magnetic resonance (NMR), pair distribution function, X-ray absorption spectroscopy, and electrochemical study,
Chem. Mater. 19, 6277-6289 (2007).
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Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
J. Non-Cryst. Solids 353, 2582-2590 (2007).
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J. F. Zhu, N. Mosey, T. Woo, and Y. N. Huang
Study of the adsorption of toluene in zeolite LiNa-Y by solid-state NMR Spectroscopy,
J. Phys. Chem. C 111, 13427-13436 (2007).
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S. P. Puls and H. Eckert
Spatial distribution of lithium ions in glasses studied by 7Li{6Li} spin echo double resonance,
Phys. Chem. Chem. Phys. 9, 3992-3998 (2007).
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C. Lu, J. Z. Hu, J. H. Kwak, Z. G. Yang, R. M. Ren, T. Markmaitree, and L. L. Shaw
Study the effects of mechanical activation on Li-N-H systems with 1H and 6Li solid-state NMR,
J. Power Sources 170, 419-424 (2007).
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M. Wilkening, C. Mühle, M. Jansen, and P. Heitjans
Microscopic access to long-range diffusion parameters of the fast ion conductor Li7BiO6 by solid state 7Li stimulated echo NMR,
J. Phys. Chem. B 111, 8691-8694 (2007).
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L. van-Wullen, T. Echelmeyer, H. W. Meyer, and D. Wilmer
The mechanism of Li-ion transport in the garnet Li5La3Nb2O12,
Phys. Chem. Chem. Phys. 9, 3298-3303 (2007).
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R. Böhmer and F. Qi
Spin relaxation and ultra-slow Li motion in an aluminosilicate glass ceramic,
Solid State NMR 31, 28-34 (2007).
Roland.Bohmer@Uni-Dortmund.de
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Z. Stoeva, B. Jager, R. Gomez, S. Messaoudi, M. Ben-Yahia, X. Rocquefelte,
G. B. Hix, W. Wolf, J. J. Titman, R. Gautier, P. Herzig, D. H. Gregory
Crystal chemistry and electronic structure of the metallic lithium ion conductor, LiNiN,
J. Am. Chem. Soc. 129, 1912-1920 (2007).
d.gregory@chem.gla.ac.uk
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M. Wilkening, R. Amade, W. Iwaniak, and P. Heitjans
Ultraslow Li diffusion in spinel-type structured Li4Ti5O12 - A comparison of results from solid state NMR and impedance spectroscopy,
Phys. Chem. Chem. Phys. 9, 1239-1246 (2007).
wilkening@pci.uni-hannover.de; heitjans@pci.uni-hannover.de
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S. Indris, P. Heitjans, R. Uecker, and T. Bredow
Local electronic structure in a LiAlO2 single crystal studied with 7Li NMR spectroscopy and comparison with quantum chemical calculations,
Phys. Rev. B 74, 245120/1-245120/5 (2006).
sindris@ms.cc.sunysb.edu; heitjans@pci.uni-hannover.de
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M. Wilkening and P. Heitjans
Extremely slow cation exchange processes in Li4SiO4 probed directly by two-time 7Li stimulated-echo nuclear magnetic resonance spectroscopy,
J. Phys.: Condens. Matter 18, 9849-9862 (2006).
wilkening@pci.uni-hannover.de; heitjans@pci.uni-hannover.de
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L. van-Wüllen, N. Sofina, L. Hildebrandt, C. Muhle, and M. Jansen
NMR studies of cation transport in the crystalline ion conductors MCF3SO3 (M = Li, Na) and Li7TaO6,
Solid State Ionics 177, 1665-1672 (2006).
wullen@uni-muenster.de; m.jansen@fkf.mpg.de
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K. Gotoh, M. Maeda, A. Nagai, A. Goto, M. Tansho, K. Hashi, T. Shimizu, and H. Ishida
Properties of a novel hard-carbon optimized to large size Li ion secondary battery studied by 7Li NMR,
J. Power Sources 162, 1322-1328 (2006).
kgotoh@cc.okayama-u.ac.jp
-
K. Yamada, K. Kumano, and T. Okuda
Lithium superionic conductors Li3InBr6 and LiInBr4 studied by 7Li, 115In NMR,
Solid State Ionics 177, 1691-1695 (2006).
k5yama@cit.nihon-u.ac.jp
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S. Jost, M. Kühnen, and H. Günther
7Li and 13C solid-state NMR spectra of lithium cuprates,
Magn. Reson. Chem. 44, 909-916 (2006).
guenmr@chemie.uni-siegen.de
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S. P. Puls and H. Eckert
Site discrimination in mixed-alkali glasses studied by cross-polarization NMR,
J. Phys. Chem. B 110, 14253-14261 (2006).
eckerth@uni-muenster.de
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M. Letellier, F. Chevallier, and F. Béguin
In situ 7Li NMR during lithium electrochemical insertion into graphite and a carbon/carbon composite,
J. Phys. Chem. Solids 67, 1228-1232 (2006).
letel@cnrs-orleans.fr
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Martin Wilkening, Wilfried Küchler, and Paul Heitjans
From ultraslow to fast lithium diffusion in the 2D ion conductor Li0.7TiS2 probed directly by stimulated-echo NMR and nuclear magnetic relaxation,
Phys. Rev. Lett. 97, 65901/1-65901/4 (2006).
wilkening@pci.uni-hannover.de; heitjans@pci.uni-hannover.de
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K. Nakamura, H. Ohno, K. Okamura, Y. Michihiro, T. Moriga,
I. Nakabayashi, and T. Kanashiro
7Li NMR study on Li+ ionic diffusion and phase transition in LixCoO2,
Solid State Ionics 177, 821-826 (2006).
koichi@pm.tokushima-u.ac.jp
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P. D. Battle, C. P. Grey, J. A. Rodgers, and J. Sloan
Structural chemistry of Ln2BaLiRuO7 (Ln = La, Pr),
Solid State Sci. 8, 280-288 (2006).
peter.battle@chem.ox.ac.uk
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L. S. Cahill, R. P. Chapman, J. F. Britten, and G. R. Goward
7Li NMR and two-dimensional exchange study of lithium dynamics in monoclinic Li3V2(PO4)3,
J. Phys. Chem. B 110, 7171-7177 (2006).
goward@mcmaster.ca
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K. Arbi, M. A. Paris, and J. Sanz
Lithium exchange processes in the conduction network of the nasicon LiTi2-xZrx(PO4)3 series (0 <= x <= 2),
J. Phys. Chem. B 110, 6454-6457 (2006).
jsanz@icmm.csic.es
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D. Capsoni, M. Bini, V. Massarotti, P. Mustarelli, F. Belotti, and P. Galinetto
Cation distribution in LiMgVO4 and LiZnVO4: Structural and spectroscopic study,
J. Phys. Chem. B 110, 5409-5415 (2006).
vincenzo.massarotti@unipv.it
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A. Y. H. Lo, R. W. Schurko, M. Vettraino, B. O. Skadtchenko, M. Trudeau,
and D. M. Antonelli
Solid-state 23Na and 7Li NMR investigations of sodium- and lithium-reduced mesoporous titanium oxides,
Inorg. Chem. 45, 1828-1838 (2006).
rschurko@uwindsor.ca; danton@uwindsor.ca
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C. Chazel, M. Ménétrier, L. Croguennec, and C. Delmas
Coupled ion/electron hopping in LixNiO2: A 7Li NMR study,
Inorg. Chem. 45, 1184-1191 (2006).
menetrier@icmcb-bordeaux.cnrs.fr
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K. Nakamura, D. Nishioka, Y. Michihiro, M. Vijayakumar, S. Selvasekarapandian,
and T. Kanashiro
7Li and 51V NMR study on Li+ ionic diffusion in lithium intercalated LixV2O5,
Solid State Ionics 177, 129-135 (2006).
koichi@pm.tokushima-u.ac.jp
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F. Qi, C. Rier, R. Bohmer, W. Franke and P. Heitjans
Ion hopping in crystalline and glassy spodumene LiAlSi2O6: 7Li spin-lattice relaxation and 7Li echo NMR spectroscopy,
Phys. Rev. B 72, 104301/1-104301/11 (2005).
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C. Chazel, M. Ménétrier, L. Croguennec, and C. Delmas
6/7Li NMR study of the Li1-zNi1+zO2 phases,
Magn. Reson. Chem. 43, 849-857 (2005).
menetrier@icmcb-bordeaux.cnrs.fr
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M. Ménétrier, Y. Shao-Horn, A. Wattiaux, L. Fournes, and C. Delmas
Iron substitution in lithium-overstoichiometric "Li1.1CoO2": Combined 57Fe Mossbauer and 7Li NMR spectroscopies studies,
Chem. Mater. 17, 4653-4659 (2005).
menetrier@icmcb-bordeaux.cnrs.fr
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Martin Wilkening and Paul Heitjans
Ultraslow diffusion in polycrystalline h-LiTiS2 studied by 7Li spin-alignment echo NMR spectroscopy,
Defect Diffus. Forum 237-240, 1182-1187 (2005).
heitjans@pci-uni-honnover.de
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F. Qi, G. Diezemann, H. Böhm, J. Lambert, and R. Böhmer
Simple modeling of dipolar coupled 7Li spins and stimulated-echo spectroscopy of single-crystalline beta-eucryptite,
J. Magn. Reson. 169, 225-239 (2004).
Roland.Bohmer@uni-dortmund.de
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T. Bredow, P. Heitjans, and M. Wilkening
Electric field gradient calculations for LixTiS2 and comparison with 7Li NMR results,
Phys. Rev. B 70, 115111/1-115111/11 (2004).
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C. P. Grey and N. Dupré
NMR studies of cathode materials for lithium-ion rechargeable batteries,
Chem. Rev. 104, 4493-4512 (2004).
cgrey@notes.cc.sunysb.edu
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M. J. Reddy and P. P. Chu
7Li NMR spectroscopy and ion conduction mechanism in mesoporous silica (SBA-15) composite poly(ethylene oxide) electrolyte,
J. Power Sources 135, 1-8 (2004).
pjchu@cc.ncu.edu.tw
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C. Mignon, Y. Millot, and P. P. Man
Piezoelectric signal suppression by a composite-pulse sequence in NMR (PDF article, 191 Kb),
C. R. Chimie 7, 425-430 (2004).
ymillot@ccr.jussieu.fr
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P. Heitjans and S. Indris
Diffusion and ionic conduction in nanocrystalline ceramics,
J. Phys.: Condens. Matter 15, R1257-R1289 (2003).
heitjans@pci.uni-hannover.de; indris@pci.uni-hannover.de
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M. Wilkening, S. Indris, and P. Heitjans
Heterogeneous lithium diffusion in nanocrystalline Li2O:Al2O3 composites,
Phys. Chem. Chem. Phys. 5, 2225-2231 (2003).
heitjans@pci.uni-hannover.de
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C. P. Grey and Y. J. Lee
Lithium MAS NMR studies of cathode materials for lithium-ion batteries,
Solid State Sci. 5, 883-894 (2003).
cgrey@sbchem.sunysb.edu
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R. Q. Fu, Z. R. Ma, J. P. Zheng, G. Au, E. J. Plichta, and C. H. Ye
High-resolution 7Li solid-state NMR study of LixV2O5 cathode electrodes for Li-rechargeable batteries,
J. Phys. Chem. B 107, 9730-9735 (2003).
rfu@magnet.fsu.edu
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N. A. Sergeev and A. M. Panich
Simple two-pulse time-reversal sequence for quadrupole-coupled spin system,
Z. Naturforsch. 58a, 33-35 (2003).
sergeev@wmf.univ.szczecin.pl
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M. Wilkening, D. Bork, S. Indris, and P. Heitjans
Diffusion in amorphous LiNbO3 studied by 7Li NMR -- comparison with the nano- and microcrystalline material,
Phys. Chem. Chem. Phys. 4, 3246-3251 (2002).
heitjans@mbox.pci.uni-hannover.de
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H. Du, V. V. Terskikh, C. I. Ratcliffe, and J. A. Ripmeester
Distinguishing surface versus buried cation sites in aluminosilicate mesoporous materials,
J. Am. Chem. Soc. 124, 4216-4217 (2002).
chris.ratcliffe@nrc.ca
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F. Qi, T. Jörg, and R. Böhmer
Stimulated-echo NMR spectroscopy of 9Be and 7li in solids: method and application to ion conductors,
Solid State NMR 22, 484-500 (2002).
roland.bohmer@uni-dortmund.de
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R. Siegel, J. Hirschinger, D. Carlier, S. Matar, M. Ménétrier, and C. Delmas
59Co and 6,7Li MAS NMR in polytypes O2 and O3 of LiCoO2,
J. Phys. Chem. B 105, 4166-4174 (2001).
hirschinger@chimie.u-strasbg.fr
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R. Böhmer
Multiple-time correlation functions in spin-3/2 solid-state NMR spectroscopy,
J. Magn. Reson. 147, 78-88 (2000).
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R. Böhmer, T. Jörg, F. Qi, and A. Titze
Stimulated 7Li echo NMR spectroscopy of slow ionic motions in a solid electrolyte,
Chem. Phys. Lett. 316, 419-424 (2000).
bohmer@aak.chemie.uni-mainz.de
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H. W. Shin, S. H. Choh, T. H. Yeom, K. S. Hong, and D. Y. Han
1D nutation NMR of 7Li in LiTaO3 and LiNbO3 single crystals and powders,
J. Korean Phys. Soc. 32, S662-S664 (1998).
Solid-state NMR bibliography for
- Aluminum-27 (鋁)
- Antimony-121/123 (銻)
- Arsenic-75 (砷)
- Barium-135/137 (鋇)
- Beryllium-9 (鈹)
- Bismuth-209 (鉍)
- Boron-11 (硼)
- Bromine-79/81 (溴)
- Calcium-43 (鈣)
- Cesium-133 (銫)
- Chlorine-35/37 (氯)
- Chromium-53 (鉻)
- Cobalt-59 (鈷)
- Copper-63/65 (銅)
- Deuterium-2 (氘)
- Gallium-69/71 (鎵)
- Germanium-73 (鍺)
- Gold-197 (金)
- Hafnium-177/179 (鉿)
- Indium-113-115 (銦)
- Iodine-127 (碘)
- Iridium-191/193 (銥)
- Krypton-83 (氪)
- Lanthanum-139 (鑭)
- Lithium-6/7 (鋰)
- Magnesium-25 (鎂)
- Manganese-55 (錳)
- Mercury-201 (銾)
- Molybdenum-95/97 (鉬)
- Neon-21 (氖)
- Nickel-61 (鎳)
- Niobium-93 (鈮)
- Nitrogen-14 (氮)
- Osmium-189 (鋨)
- Oxygen-17 (氧)
- Palladium-105 (鈀)
- Potassium-39/41 (鉀)
- Rhenium-185/187 (錸)
- Rubidium-85/87 (銣)
- Ruthenium-99/101 (釕)
- Scandium-45 (鈧)
- Sodium-23 (鈉)
- Strontium-87 (鍶)
- Sulfur-33 (硫)
- Tantalum-181 (鉭)
- Titanium-47/49 (鈦)
- Vanadium-51 (釩)
- Xenon-131 (氥)
- Zinc-67 (鋅)
- Zirconium-91 (鋯)
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- Last updated May 13, 2008
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