Lithium-6 and lithium-7 NMR




Home and Applets > Periodic Table > Lithium
Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Li-6 1 7.42 -0.0808 8.50E-3 6.31E-4 -14.716 LiCl
Li-7 3/2 92.58 -4.01 0.29 0.27 -38.863

Directory of solid-state Li-6 and lithium-7 NMR references
Single Crystal Crystalline Powder
Oxide, Zeolite
Amorphous Powder

Solid-state lithium NMR references

  1. L. S. Cahill, C. W. Kirby, and G. R. Goward
    6Li{31P} rotational-echo, double-resonance studies of lithium ion site dynamics in Li3V2(PO4)3,
    J. Phys. Chem. C 112, 2215-2221 (2008).
     
  2. M. Wilkening and P. Heitjans
    Li jump process in h-Li0.7TiS2 studied by two-time 7Li spin-alignment echo NMR and comparison with results on two-dimensional diffusion from nuclear magnetic relaxation,
    Phys. Rev. B 77, 24311/1-24311/13 (2008).
     
  3. M. Wilkening, D. Gebauer, and P. Heitjans
    Diffusion parameters in single-crystalline Li3N as probed by 6Li and 7Li spin-alignment echo NMR spectroscopy in comparison with results from 8Li β-radiation detected NMR,
    J. Phys.: Condens. Matter 20, 22201/1-22201/5 (2008).
     
  4. G. T. K. Fey, P. Muralidharan, Y. D. Cho, P. C. Chang, H. M. Kao
    Electrochemical performance and 7Li NMR studies on an inverse spinel LiNi1/3Co1/3Mn1/3VO4 for Li-ion batteries,
    J. Power Sources 174, 1142-1146 (2007).
     
  5. Paul Heitjans, Muayad Masoud, Armin Feldhoff, and Martin Wilkening
    NMR and impedance studies of nanocrystalline and amorphous ion conductors: lithium niobate as a model system,
    Faraday Discuss. 134, 67-82 (2007).
     
  6. J. Wontcheu, W. Bensch, M. Wilkening, P. Heitjans, S. Indris, P. Sideris, C. P. Grey, S. Mankovsky, and H. Ebert
    Tuning the structural and physical properties of Cr2Ti3Se8 by lithium intercalation: A study of the magnetic properties and investigation of ion mobility with NMR spectroscopy,
    J. Am. Chem. Soc. 130, 288-299 (2007).
     
  7. M. Wilkening, W. Iwaniak, J. Heine, V. Epp, A. Kleinert, M. Behrens, G. Nuspl, W. Bensch, and P. Heitjans
    Microscopic Li self-diffusion parameters in the lithiated anode material Li4+xTi5O12 (0 ≤ x ≤ 3) measured by 7Li solid state NMR ,
    Phys. Chem. Chem. Phys. 9, 6199-6202 (2007).
     
  8. D. L. Zeng, J. Cabana, J. L. Breger, W. S. Yoon, and C. P. Grey
    Cation ordering in Li[NixMnxCo(1-2x)]O2-layered cathode materials: A nuclear magnetic resonance (NMR), pair distribution function, X-ray absorption spectroscopy, and electrochemical study,
    Chem. Mater. 19, 6277-6289 (2007).
     
  9. Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
    Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
    J. Non-Cryst. Solids 353, 2582-2590 (2007).
     
  10. J. F. Zhu, N. Mosey, T. Woo, and Y. N. Huang
    Study of the adsorption of toluene in zeolite LiNa-Y by solid-state NMR Spectroscopy,
    J. Phys. Chem. C 111, 13427-13436 (2007).
     
  11. S. P. Puls and H. Eckert
    Spatial distribution of lithium ions in glasses studied by 7Li{6Li} spin echo double resonance,
    Phys. Chem. Chem. Phys. 9, 3992-3998 (2007).
     
  12. C. Lu, J. Z. Hu, J. H. Kwak, Z. G. Yang, R. M. Ren, T. Markmaitree, and L. L. Shaw
    Study the effects of mechanical activation on Li-N-H systems with 1H and 6Li solid-state NMR,
    J. Power Sources 170, 419-424 (2007).
     
  13. M. Wilkening, C. Mühle, M. Jansen, and P. Heitjans
    Microscopic access to long-range diffusion parameters of the fast ion conductor Li7BiO6 by solid state 7Li stimulated echo NMR,
    J. Phys. Chem. B 111, 8691-8694 (2007).
     
  14. L. van-Wullen, T. Echelmeyer, H. W. Meyer, and D. Wilmer
    The mechanism of Li-ion transport in the garnet Li5La3Nb2O12,
    Phys. Chem. Chem. Phys. 9, 3298-3303 (2007).
     
  15. R. Böhmer and F. Qi
    Spin relaxation and ultra-slow Li motion in an aluminosilicate glass ceramic,
    Solid State NMR 31, 28-34 (2007).
    Roland.Bohmer@Uni-Dortmund.de
     
  16. Z. Stoeva, B. Jager, R. Gomez, S. Messaoudi, M. Ben-Yahia, X. Rocquefelte, G. B. Hix, W. Wolf, J. J. Titman, R. Gautier, P. Herzig, D. H. Gregory
    Crystal chemistry and electronic structure of the metallic lithium ion conductor, LiNiN,
    J. Am. Chem. Soc. 129, 1912-1920 (2007).
    d.gregory@chem.gla.ac.uk
     
  17. M. Wilkening, R. Amade, W. Iwaniak, and P. Heitjans
    Ultraslow Li diffusion in spinel-type structured Li4Ti5O12 - A comparison of results from solid state NMR and impedance spectroscopy,
    Phys. Chem. Chem. Phys. 9, 1239-1246 (2007).
    wilkening@pci.uni-hannover.de; heitjans@pci.uni-hannover.de
     
  18. S. Indris, P. Heitjans, R. Uecker, and T. Bredow
    Local electronic structure in a LiAlO2 single crystal studied with 7Li NMR spectroscopy and comparison with quantum chemical calculations,
    Phys. Rev. B 74, 245120/1-245120/5 (2006).
    sindris@ms.cc.sunysb.edu; heitjans@pci.uni-hannover.de
     
  19. M. Wilkening and P. Heitjans
    Extremely slow cation exchange processes in Li4SiO4 probed directly by two-time 7Li stimulated-echo nuclear magnetic resonance spectroscopy,
    J. Phys.: Condens. Matter 18, 9849-9862 (2006).
    wilkening@pci.uni-hannover.de; heitjans@pci.uni-hannover.de
     
  20. L. van-Wüllen, N. Sofina, L. Hildebrandt, C. Muhle, and M. Jansen
    NMR studies of cation transport in the crystalline ion conductors MCF3SO3 (M = Li, Na) and Li7TaO6,
    Solid State Ionics 177, 1665-1672 (2006).
    wullen@uni-muenster.de; m.jansen@fkf.mpg.de
     
  21. K. Gotoh, M. Maeda, A. Nagai, A. Goto, M. Tansho, K. Hashi, T. Shimizu, and H. Ishida
    Properties of a novel hard-carbon optimized to large size Li ion secondary battery studied by 7Li NMR,
    J. Power Sources 162, 1322-1328 (2006).
    kgotoh@cc.okayama-u.ac.jp
     
  22. K. Yamada, K. Kumano, and T. Okuda
    Lithium superionic conductors Li3InBr6 and LiInBr4 studied by 7Li, 115In NMR,
    Solid State Ionics 177, 1691-1695 (2006).
    k5yama@cit.nihon-u.ac.jp
     
  23. S. Jost, M. Kühnen, and H. Günther
    7Li and 13C solid-state NMR spectra of lithium cuprates,
    Magn. Reson. Chem. 44, 909-916 (2006).
    guenmr@chemie.uni-siegen.de
     
  24. S. P. Puls and H. Eckert
    Site discrimination in mixed-alkali glasses studied by cross-polarization NMR,
    J. Phys. Chem. B 110, 14253-14261 (2006).
    eckerth@uni-muenster.de
     
  25. M. Letellier, F. Chevallier, and F. Béguin
    In situ 7Li NMR during lithium electrochemical insertion into graphite and a carbon/carbon composite,
    J. Phys. Chem. Solids 67, 1228-1232 (2006).
    letel@cnrs-orleans.fr
     
  26. Martin Wilkening, Wilfried Küchler, and Paul Heitjans
    From ultraslow to fast lithium diffusion in the 2D ion conductor Li0.7TiS2 probed directly by stimulated-echo NMR and nuclear magnetic relaxation,
    Phys. Rev. Lett. 97, 65901/1-65901/4 (2006).
    wilkening@pci.uni-hannover.de; heitjans@pci.uni-hannover.de
     
  27. K. Nakamura, H. Ohno, K. Okamura, Y. Michihiro, T. Moriga, I. Nakabayashi, and T. Kanashiro
    7Li NMR study on Li+ ionic diffusion and phase transition in LixCoO2,
    Solid State Ionics 177, 821-826 (2006).
    koichi@pm.tokushima-u.ac.jp
     
  28. P. D. Battle, C. P. Grey, J. A. Rodgers, and J. Sloan
    Structural chemistry of Ln2BaLiRuO7 (Ln = La, Pr),
    Solid State Sci. 8, 280-288 (2006).
    peter.battle@chem.ox.ac.uk
     
  29. L. S. Cahill, R. P. Chapman, J. F. Britten, and G. R. Goward
    7Li NMR and two-dimensional exchange study of lithium dynamics in monoclinic Li3V2(PO4)3,
    J. Phys. Chem. B 110, 7171-7177 (2006).
    goward@mcmaster.ca
     
  30. K. Arbi, M. A. Paris, and J. Sanz
    Lithium exchange processes in the conduction network of the nasicon LiTi2-xZrx(PO4)3 series (0 <= x <= 2),
    J. Phys. Chem. B 110, 6454-6457 (2006).
    jsanz@icmm.csic.es
     
  31. D. Capsoni, M. Bini, V. Massarotti, P. Mustarelli, F. Belotti, and P. Galinetto
    Cation distribution in LiMgVO4 and LiZnVO4: Structural and spectroscopic study,
    J. Phys. Chem. B 110, 5409-5415 (2006).
    vincenzo.massarotti@unipv.it
     
  32. A. Y. H. Lo, R. W. Schurko, M. Vettraino, B. O. Skadtchenko, M. Trudeau, and D. M. Antonelli
    Solid-state 23Na and 7Li NMR investigations of sodium- and lithium-reduced mesoporous titanium oxides,
    Inorg. Chem. 45, 1828-1838 (2006).
    rschurko@uwindsor.ca; danton@uwindsor.ca
     
  33. C. Chazel, M. Ménétrier, L. Croguennec, and C. Delmas
    Coupled ion/electron hopping in LixNiO2: A 7Li NMR study,
    Inorg. Chem. 45, 1184-1191 (2006).
    menetrier@icmcb-bordeaux.cnrs.fr
     
  34. K. Nakamura, D. Nishioka, Y. Michihiro, M. Vijayakumar, S. Selvasekarapandian, and T. Kanashiro
    7Li and 51V NMR study on Li+ ionic diffusion in lithium intercalated LixV2O5,
    Solid State Ionics 177, 129-135 (2006).
    koichi@pm.tokushima-u.ac.jp
     
  35. F. Qi, C. Rier, R. Bohmer, W. Franke and P. Heitjans
    Ion hopping in crystalline and glassy spodumene LiAlSi2O6: 7Li spin-lattice relaxation and 7Li echo NMR spectroscopy,
    Phys. Rev. B 72, 104301/1-104301/11 (2005).
     
  36. C. Chazel, M. Ménétrier, L. Croguennec, and C. Delmas
    6/7Li NMR study of the Li1-zNi1+zO2 phases,
    Magn. Reson. Chem. 43, 849-857 (2005).
    menetrier@icmcb-bordeaux.cnrs.fr
     
  37. M. Ménétrier, Y. Shao-Horn, A. Wattiaux, L. Fournes, and C. Delmas
    Iron substitution in lithium-overstoichiometric "Li1.1CoO2": Combined 57Fe Mossbauer and 7Li NMR spectroscopies studies,
    Chem. Mater. 17, 4653-4659 (2005).
    menetrier@icmcb-bordeaux.cnrs.fr
     
  38. Martin Wilkening and Paul Heitjans
    Ultraslow diffusion in polycrystalline h-LiTiS2 studied by 7Li spin-alignment echo NMR spectroscopy,
    Defect Diffus. Forum 237-240, 1182-1187 (2005).
    heitjans@pci-uni-honnover.de
     
  39. F. Qi, G. Diezemann, H. Böhm, J. Lambert, and R. Böhmer
    Simple modeling of dipolar coupled 7Li spins and stimulated-echo spectroscopy of single-crystalline beta-eucryptite,
    J. Magn. Reson. 169, 225-239 (2004).
    Roland.Bohmer@uni-dortmund.de
     
  40. T. Bredow, P. Heitjans, and M. Wilkening
    Electric field gradient calculations for LixTiS2 and comparison with 7Li NMR results,
    Phys. Rev. B 70, 115111/1-115111/11 (2004).
     
  41. C. P. Grey and N. Dupré
    NMR studies of cathode materials for lithium-ion rechargeable batteries,
    Chem. Rev. 104, 4493-4512 (2004).
    cgrey@notes.cc.sunysb.edu
     
  42. M. J. Reddy and P. P. Chu
    7Li NMR spectroscopy and ion conduction mechanism in mesoporous silica (SBA-15) composite poly(ethylene oxide) electrolyte,
    J. Power Sources 135, 1-8 (2004).
    pjchu@cc.ncu.edu.tw
     
  43. C. Mignon, Y. Millot, and P. P. Man
    Piezoelectric signal suppression by a composite-pulse sequence in NMR (PDF article, 191 Kb),
    C. R. Chimie 7, 425-430 (2004).
    ymillot@ccr.jussieu.fr
     
  44. P. Heitjans and S. Indris
    Diffusion and ionic conduction in nanocrystalline ceramics,
    J. Phys.: Condens. Matter 15, R1257-R1289 (2003).
    heitjans@pci.uni-hannover.de; indris@pci.uni-hannover.de
     
  45. M. Wilkening, S. Indris, and P. Heitjans
    Heterogeneous lithium diffusion in nanocrystalline Li2O:Al2O3 composites,
    Phys. Chem. Chem. Phys. 5, 2225-2231 (2003).
    heitjans@pci.uni-hannover.de
     
  46. C. P. Grey and Y. J. Lee
    Lithium MAS NMR studies of cathode materials for lithium-ion batteries,
    Solid State Sci. 5, 883-894 (2003).
    cgrey@sbchem.sunysb.edu
     
  47. R. Q. Fu, Z. R. Ma, J. P. Zheng, G. Au, E. J. Plichta, and C. H. Ye
    High-resolution 7Li solid-state NMR study of LixV2O5 cathode electrodes for Li-rechargeable batteries,
    J. Phys. Chem. B 107, 9730-9735 (2003).
    rfu@magnet.fsu.edu
     
  48. N. A. Sergeev and A. M. Panich
    Simple two-pulse time-reversal sequence for quadrupole-coupled spin system,
    Z. Naturforsch. 58a, 33-35 (2003).
    sergeev@wmf.univ.szczecin.pl
     
  49. M. Wilkening, D. Bork, S. Indris, and P. Heitjans
    Diffusion in amorphous LiNbO3 studied by 7Li NMR -- comparison with the nano- and microcrystalline material,
    Phys. Chem. Chem. Phys. 4, 3246-3251 (2002).
    heitjans@mbox.pci.uni-hannover.de
     
  50. H. Du, V. V. Terskikh, C. I. Ratcliffe, and J. A. Ripmeester
    Distinguishing surface versus buried cation sites in aluminosilicate mesoporous materials,
    J. Am. Chem. Soc. 124, 4216-4217 (2002).
    chris.ratcliffe@nrc.ca
     
  51. F. Qi, T. Jörg, and R. Böhmer
    Stimulated-echo NMR spectroscopy of 9Be and 7li in solids: method and application to ion conductors,
    Solid State NMR 22, 484-500 (2002).
    roland.bohmer@uni-dortmund.de
     
  52. R. Siegel, J. Hirschinger, D. Carlier, S. Matar, M. Ménétrier, and C. Delmas
    59Co and 6,7Li MAS NMR in polytypes O2 and O3 of LiCoO2,
    J. Phys. Chem. B 105, 4166-4174 (2001).
    hirschinger@chimie.u-strasbg.fr
     
  53. R. Böhmer
    Multiple-time correlation functions in spin-3/2 solid-state NMR spectroscopy,
    J. Magn. Reson. 147, 78-88 (2000).
     
  54. R. Böhmer, T. Jörg, F. Qi, and A. Titze
    Stimulated 7Li echo NMR spectroscopy of slow ionic motions in a solid electrolyte,
    Chem. Phys. Lett. 316, 419-424 (2000).
    bohmer@aak.chemie.uni-mainz.de
     
  55. H. W. Shin, S. H. Choh, T. H. Yeom, K. S. Hong, and D. Y. Han
    1D nutation NMR of 7Li in LiTaO3 and LiNbO3 single crystals and powders,
    J. Korean Phys. Soc. 32, S662-S664 (1998).
     
 
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