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> Magnesium
| Isotope | Spin | Natural abundance(%) |
Quadrupole moment (10-30m2) |
Relative sensitivity |
Absolute sensitivity |
NMR frequency (MHz) at a field of 2.3488T |
Reference sample |
|---|---|---|---|---|---|---|---|
| Mg-25 | 5/2 | 10.13 | 19.94 | 2.67E-3 | 2.71E-4 | 6.1195 | MgCl2 |
| . | . | . | . | . | . | . | . |
Solid-state magnesium NMR references
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K. Shimoda, Y. Tobu, M. Hatakeyama, T. Nemoto, and K. Saito
Structural investigation of Mg local environments in silicate glasses by ultra-high field 25Mg 3QMAS NMR spectroscopy,
Am. Mineral. 92, 695-698 (2007).
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A. Wong, R. Ida, X. Mo, Z. H. Gan, J. Poh, and G. Wu
Solid-state 25Mg NMR spectroscopic and computational studies of organic compounds. Square-pyramidal magnesium(II) ions in aqua(magnesium) phthalocyanine and chlorophyll a,
J. Phys. Chem. A 110, 10084-10090 (2006).
gangwu@chem.queensu.ca
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N. G. Dowell, S. E. Ashbrook, and S. Wimperis
Satellite-transition MAS NMR of low-gamma nuclei at natural abundance: sensitivity, practical implementation, and application to 39K (I = 3/2) and 25Mg (I = 5/2),
J. Phys. Chem. B 108, 13292-13299 (2004).
s.wimperis@exeter.ac.uk
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A. S. Lipton, R. W. Heck, J. A. Sears, and P. D. Ellis
Low temperature solid-state NMR experiments of half-integer quadrupolar nuclides: caveats and data analysis,
J. Magn. Reson. 168, 66-74 (2004).
paul.ellis@pnl.gov
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M. D. Glinchuk, A. N. Morozovskaya, A. M. Slipenyuk, and I. P. Bykov
Peculiarities of the radiospectroscopy line shape in nanomaterials,
Appl. Magn. Reson. 24, 333-342 (2003).
glin@materials.kiev.ua
-
Ivan Hung and Robert W. Schurko
Solid-state 25Mg QCPMG NMR of bis(cyclopentadienyl)magnesium,
Solid State NMR 24, 78-93 (2003).
rschurko@uwindsor.ca
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G. Wu, A. Wong, and S. N. Wang
Solid-state 25Mg NMR, X-ray crystallographic, and quantum mechanical study of bis(pyridine)-(5,10,15,20-tetraphenylporphyrinato)magnesium(II),
Can. J. Chem. 81, 275-283 (2003).
gangwu@chem.queensu.ca
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T. J. Bastow
Electric field gradients at the M-site in MCO3: M = Mg, Ca, Sr and Ba,
Chem. Phys. Lett. 354, 156-159 (2002).
bastow@cmst.csiro.au
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T. J. Bastow
25Mg NMR determination of Knight shift, spin-lattice relaxation and electric field gradient in MgB2,
Solid State Commun. 124, 269-273 (2002).
bastow@mst.csiro.au
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S. Kroeker, P. S. Neuhoff, and J. F. Stebbins
Enhanced resolution and quantitation from ultrahigh field NMR spectroscopy of glasses,
J. Non-Cryst. Solids 293-295, 440-445 (2001).
stebbins@pangea.stanford.edu
-
F. H. Larsen, J. Skibsted, H. J. Jakobsen, and N. C. Nielsen
Solid-state QCPMG NMR of low-gamma quadrupolar metal nuclei in natural abundance,
J. Am. Chem. Soc. 122, 7080-7086 (2000).
-
S. Sham and G. Wu
Solid-state 25Mg NMR study of inner-sphere Mg2+ binding complexes,
Inorg. Chem. 39, 4-5 (2000).
gangwu@chem.queensu.ca
Related bibliography
-
T. Iijima and M. Mizuno
Effect of molecular dynamics and modulated structure on 2H NMR spectrum studied in [Mg(H2O)6][SiF6],
Chem. Phys. Lett. 380, 736-741 (2003).
IIJIMA.Takahiro@nims.go.jp
More solid-state Mg-25 NMR references.
Solid-state NMR bibliography for
- Aluminum-27 (鋁)
- Antimony-121/123 (銻)
- Arsenic-75 (砷)
- Barium-135/137 (鋇)
- Beryllium-9 (鈹)
- Bismuth-209 (鉍)
- Boron-11 (硼)
- Bromine-79/81 (溴)
- Calcium-43 (鈣)
- Cesium-133 (銫)
- Chlorine-35/37 (氯)
- Chromium-53 (鉻)
- Cobalt-59 (鈷)
- Copper-63/65 (銅)
- Deuterium-2 (氘)
- Gallium-69/71 (鎵)
- Germanium-73 (鍺)
- Gold-197 (金)
- Hafnium-177/179 (鉿)
- Indium-113-115 (銦)
- Iodine-127 (碘)
- Iridium-191/193 (銥)
- Krypton-83 (氪)
- Lanthanum-139 (鑭)
- Lithium-6/7 (鋰)
- Magnesium-25 (鎂)
- Manganese-55 (錳)
- Mercury-201 (銾)
- Molybdenum-95/97 (鉬)
- Neon-21 (氖)
- Nickel-61 (鎳)
- Niobium-93 (鈮)
- Nitrogen-14 (氮)
- Osmium-189 (鋨)
- Oxygen-17 (氧)
- Palladium-105 (鈀)
- Potassium-39/41 (鉀)
- Rhenium-185/187 (錸)
- Rubidium-85/87 (銣)
- Ruthenium-99/101 (釕)
- Scandium-45 (鈧)
- Sodium-23 (鈉)
- Strontium-87 (鍶)
- Sulfur-33 (硫)
- Tantalum-181 (鉭)
- Titanium-47/49 (鈦)
- Vanadium-51 (釩)
- Xenon-131 (氥)
- Zinc-67 (鋅)
- Zirconium-91 (鋯)
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