Magnesium-25 NMR




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Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Mg-25 5/2 10.13 19.94 2.67E-3 2.71E-4 6.1195 MgCl2
. . . . . . . .

Solid-state magnesium NMR references

  1. K. Shimoda, Y. Tobu, M. Hatakeyama, T. Nemoto, and K. Saito
    Structural investigation of Mg local environments in silicate glasses by ultra-high field 25Mg 3QMAS NMR spectroscopy,
    Am. Mineral. 92, 695-698 (2007).
     
  2. A. Wong, R. Ida, X. Mo, Z. H. Gan, J. Poh, and G. Wu
    Solid-state 25Mg NMR spectroscopic and computational studies of organic compounds. Square-pyramidal magnesium(II) ions in aqua(magnesium) phthalocyanine and chlorophyll a,
    J. Phys. Chem. A 110, 10084-10090 (2006).
    gangwu@chem.queensu.ca
     
  3. N. G. Dowell, S. E. Ashbrook, and S. Wimperis
    Satellite-transition MAS NMR of low-gamma nuclei at natural abundance: sensitivity, practical implementation, and application to 39K (I = 3/2) and 25Mg (I = 5/2),
    J. Phys. Chem. B 108, 13292-13299 (2004).
    s.wimperis@exeter.ac.uk
     
  4. A. S. Lipton, R. W. Heck, J. A. Sears, and P. D. Ellis
    Low temperature solid-state NMR experiments of half-integer quadrupolar nuclides: caveats and data analysis,
    J. Magn. Reson. 168, 66-74 (2004).
    paul.ellis@pnl.gov
     
  5. M. D. Glinchuk, A. N. Morozovskaya, A. M. Slipenyuk, and I. P. Bykov
    Peculiarities of the radiospectroscopy line shape in nanomaterials,
    Appl. Magn. Reson. 24, 333-342 (2003).
    glin@materials.kiev.ua
     
  6. Ivan Hung and Robert W. Schurko
    Solid-state 25Mg QCPMG NMR of bis(cyclopentadienyl)magnesium,
    Solid State NMR 24, 78-93 (2003).
    rschurko@uwindsor.ca
     
  7. G. Wu, A. Wong, and S. N. Wang
    Solid-state 25Mg NMR, X-ray crystallographic, and quantum mechanical study of bis(pyridine)-(5,10,15,20-tetraphenylporphyrinato)magnesium(II),
    Can. J. Chem. 81, 275-283 (2003).
    gangwu@chem.queensu.ca
     
  8. T. J. Bastow
    Electric field gradients at the M-site in MCO3: M = Mg, Ca, Sr and Ba,
    Chem. Phys. Lett. 354, 156-159 (2002).
    bastow@cmst.csiro.au
     
  9. T. J. Bastow
    25Mg NMR determination of Knight shift, spin-lattice relaxation and electric field gradient in MgB2,
    Solid State Commun. 124, 269-273 (2002).
    bastow@mst.csiro.au
     
  10. S. Kroeker, P. S. Neuhoff, and J. F. Stebbins
    Enhanced resolution and quantitation from ultrahigh field NMR spectroscopy of glasses,
    J. Non-Cryst. Solids 293-295, 440-445 (2001).
    stebbins@pangea.stanford.edu
     
  11. F. H. Larsen, J. Skibsted, H. J. Jakobsen, and N. C. Nielsen
    Solid-state QCPMG NMR of low-gamma quadrupolar metal nuclei in natural abundance,
    J. Am. Chem. Soc. 122, 7080-7086 (2000).
     
  12. S. Sham and G. Wu
    Solid-state 25Mg NMR study of inner-sphere Mg2+ binding complexes,
    Inorg. Chem. 39, 4-5 (2000).
    gangwu@chem.queensu.ca
     

Related bibliography

  1. T. Iijima and M. Mizuno
    Effect of molecular dynamics and modulated structure on 2H NMR spectrum studied in [Mg(H2O)6][SiF6],
    Chem. Phys. Lett. 380, 736-741 (2003).
    IIJIMA.Takahiro@nims.go.jp
     

More solid-state Mg-25 NMR references.


 
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