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> Niobium
| Isotope | Spin | Natural abundance(%) |
Quadrupole moment (10-30m2) |
Relative sensitivity |
Absolute sensitivity |
NMR frequency (MHz) at a field of 2.3488T |
Reference sample |
|---|---|---|---|---|---|---|---|
| Nb-93 | 9/2 | 100 | -32.0 | 0.48 | 0.48 | -24.442 | K[NbCl6] |
| . | . | . | . | . | . | . | . |
Solid-state niobium NMR references
-
A. Flambard, L. Montagne, L. Delevoye, and S. Steuernagel
93Nb and 17O NMR chemical shifts of niobiophosphate compounds,
Solid State NMR 32, 34-43 (2007).
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M. Vijayakumar, G. L. Hoatson, and R. L. Vold
Identification of polar nanoclusters in PbMg1/3Nb2/3O3 from NMR spectra,
Phys. Rev. B 75, 104104/1-104104/5 (2007).
gina@physics.wm.edu
-
J. P. Amoureux and J. Trébosc
Resolution enhancement in 1D solid-state NMR spectra of spin-9/2 quadrupolar nuclei,
J. Magn. Reson. 180, 311-317 (2006).
jean-paul.amoureux@univ-lille1.fr
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L. J. Smith and C. Seith
Site-selective QPASS for the isolation of large quadrupolar coupling environments,
J. Magn. Reson. 179, 164-168 (2006).
lusmith@clarku.edu
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O. B. Lapina, D. F. Khabibulin, K. V. Romanenko, Z. H. Gan, M. G. Zuev,
V. N. Krasil'nikov, and V. E. Fedorov
93Nb NMR chemical shift scale for niobia systems,
Solid State NMR 28, 204-224 (2005).
olga@catalysis.nsk.su
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A. Y. H. Lo, T. E. Bitterwolf, C. L. B. Macdonald, and R. W. Schurko
Solid-state 93Nb and 13C NMR investigations of half-sandwich niobium(I) and niobium(V) cyclopentadienyl complexes,
J. Phys. Chem. A 109, 7073-7087 (2005).
rschurko@uwindsor.ca
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V. V. Laguta, M. D. Glinchuk, I. P. Bykov, R. Blinc, and B. Zalar
NMR study of ionic shifts and polar ordering in the relaxor ferroelectric Pb(Sc1/2Nb1/2)O3,
Phys. Rev. B 69, 54103/1-54103/9 (2004).
-
D. H. Zhou, G. L. Hoatson, and R. L. Vold
Local structure in perovskite relaxor ferroelectrics: high-resolution 93Nb 3QMAS NMR,
J. Magn. Reson. 167, 242-252 (2004).
gina@nmr.physics.wm.edu; rlv@nmr.physics.wm.edu
-
E. Schellkes, X. Hong, M. Holz, U. Huniar, R. Ahlrichs, and W. Freyland
High temperature 93Nb NMR and Raman spectroscopic investigation of the structure and dynamics of solid and liquid NbCl5-alkali chloride solutions,
Phys. Chem. Chem. Phys. 5, 5536-5543 (2003).
Werner.Freyland@chem-bio.uni-karlsruhe.de
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C. M. Morais, M. Lopes, C. Fernandez, and J. Rocha
Assessing the potential of fast amplitude modulation pulses for improving triple-quantum magic angle spinning NMR spectra of half-integer quadrupolar nuclei,
Magn. Reson. Chem. 41, 679-688 (2003).
rocha@dq.ua.pt
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H. T. Kwak, S. Prasad, T. Clark, P. J. Grandinetti
Enhancing sensitivity of quadrupolar nuclei in solid-state NMR with multiple rotor assisted population transfers,
Solid State NMR 24, 71-77 (2003).
http://www.grandinetti.org/Contact
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L. S. Du, R. W. Schurko, N. Kim, and C. P. Grey
Solid-state 93Nb, 19F, and 113Cd nuclear magnetic resonance study of niobium oxyfluorides: characterization of local distortions and oxygen/fluorine ordering,
J. Phys. Chem. A 106, 7876-7886 (2002).
cgrey@notes.cc.sunysb.edu
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S. E. Ashbrook and S. Wimperis
Satellite-transition MAS NMR of spin I = 3/2, 5/2, 7/2, and 9/2 nuclei: sensitivity, resolution, and practical implementation,
J. Magn. Reson. 156, 269-281 (2002).
s.wimperis@exeter.ac.uk
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R. Blinc and T. Apih
NMR in multidimensionally modulated incommensurate and CDW systems,
Prog. Nucl. Magn. Reson. Spectrosc. 41, 49-82 (2002).
robert.blinc@ijs.si
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D. Massiot, F. Fayon, M. Capron, I. King, S. Le Calvé, B. Alonso, J.-O. Durand, B. Bujoli, Z. Gan, and G. Hoatson
Modelling one- and two-dimensional solid-state NMR spectra,
Magn. Reson. Chem. 40, 70-76 (2002).
massiot@cnrs-orleans.fr
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H. M. Kao and K. H. Lii
The first observation of heteronuclear two-bond J-coupling in the solid state: Crystal structure and solid-state NMR spectroscopy of Rb4(NbO)2(Si8O21),
Inorg. Chem. 41, 5644-5646 (2002).
hmkao@cc.ncu.edu.tw; liikh@cc.ncu.edu.tw
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G. L. Hoatson, D. H. H. Zhou, F. Fayon, D. Massiot, and R. L. Vold
93Nb magic angle spinning NMR study of perovskite relaxor ferroelectrics (1-x)Pb(Mg1/3Nb2/3)O3-xPb(Sc1/2Nb1/2)O3,
Phys. Rev. B 66, 224103/1-224103/13 (2002).
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S. Prasad, P. Zhao, J. Huang, J. J. Fitzgerald, and J. S. Shore
Niobium-93 MQMAS NMR spectroscopy study of alkali and lead niobates,
Solid State NMR 19, 45-62 (2001).
jay_shore@sdstate.edu
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John J. Fitzgerald, Subramanian Prasad, Jiong Huang, and Jay S. Shore
Solid-state 93Nb NMR and 93Nb nutation studies of polycrystalline Pb(Mg1/3Nb2/3)O3 and (1 - x)Pb(Mg1/3Nb2/3)O3/xPbTiO3 solid-solution relaxor ferroelectrics,
J. Am. Chem. Soc. 122, 2556-2566 (2000).
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P. R. Bodart, J.-P. Amoureux, Y. Dumazy, and R. Lefort
Theoretical and experimental study of quadrupolar echoes for half-integer spins in static solid-state NMR,
Mol. Phys. 98, 1545-1551 (2000).
Related bibliography
-
Terence P. Kee
Niobium and tantalum 1993,
Coord. Chem. Rev. 146, 17-36 (1995).
More solid-state Nb-93 NMR references.
Solid-state NMR bibliography for
- Aluminum-27 (鋁)
- Antimony-121/123 (銻)
- Arsenic-75 (砷)
- Barium-135/137 (鋇)
- Beryllium-9 (鈹)
- Bismuth-209 (鉍)
- Boron-11 (硼)
- Bromine-79/81 (溴)
- Calcium-43 (鈣)
- Cesium-133 (銫)
- Chlorine-35/37 (氯)
- Chromium-53 (鉻)
- Cobalt-59 (鈷)
- Copper-63/65 (銅)
- Deuterium-2 (氘)
- Gallium-69/71 (鎵)
- Germanium-73 (鍺)
- Gold-197 (金)
- Hafnium-177/179 (鉿)
- Indium-113-115 (銦)
- Iodine-127 (碘)
- Iridium-191/193 (銥)
- Krypton-83 (氪)
- Lanthanum-139 (鑭)
- Lithium-6/7 (鋰)
- Magnesium-25 (鎂)
- Manganese-55 (錳)
- Mercury-201 (銾)
- Molybdenum-95/97 (鉬)
- Neon-21 (氖)
- Nickel-61 (鎳)
- Niobium-93 (鈮)
- Nitrogen-14 (氮)
- Osmium-189 (鋨)
- Oxygen-17 (氧)
- Palladium-105 (鈀)
- Potassium-39/41 (鉀)
- Rhenium-185/187 (錸)
- Rubidium-85/87 (銣)
- Ruthenium-99/101 (釕)
- Scandium-45 (鈧)
- Sodium-23 (鈉)
- Strontium-87 (鍶)
- Sulfur-33 (硫)
- Tantalum-181 (鉭)
- Titanium-47/49 (鈦)
- Vanadium-51 (釩)
- Xenon-131 (氥)
- Zinc-67 (鋅)
- Zirconium-91 (鋯)
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