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> Potassium
| Isotope | Spin | Natural abundance(%) |
Quadrupole moment (10-30m2) |
Relative sensitivity |
Absolute sensitivity |
NMR frequency (MHz) at a field of 2.3488T |
Reference sample |
|---|---|---|---|---|---|---|---|
| K-39 | 3/2 | 93.1 | 5.85 | 5.08E-4 | 4.73E-4 | -4.667 | KCl |
| K-41 | 3/2 | 6.88 | 7.11 | 8.40E-5 | 5.78E-6 | -2.561 |
Solid-state potassium NMR references
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G. M. Bowers, D. L. Bish, and R. J. Kirkpatrick
Cation exchange at the mineral-water interface: H3O+/K+ competition at the surface of vano-muscovite,
Langmuir 24, 10240-10244 (2008).
Abstract
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G. M. Bowers, D. L. Bish, and R. J. Kirkpatrick
H2O and cation structure and dynamics in expandable clays: 2H and 39K NMR investigations of hectorite,
J. Phys. Chem. C 112, 6430-6438 (2008).
-
Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
J. Non-Cryst. Solids 353, 2582-2590 (2007).
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P. K. Lee, R. P. Chapman, L. Zhang, J. Hu, L. J. Barbour, E. K. Elliott,
G. W. Gokel, and D. L. Bryce
K-39 quadrupolar and shemical shift tensors for organic potassium complexes and diatomic molecules,
J. Phys. Chem. A 111, 12859-12863 (2007).
-
I. L. Moudrakovski and J. A. Ripmeester
39K NMR of solid potassium salts at 21 T: Effect of quadrupolar and chemical shift tensors,
J. Phys. Chem. B 111, 491-495 (2007).
igor.moudrakovski@nrc-cnrc.gc.ca
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P. Duxson, J. L. Provis, G. C. Lukey, J. S. J. van Deventer, F. Separovic,
and Z. H. Gan
39K NMR of free potassium in geopolymers,
Ind. Eng. Chem. Res. 45, 9208-9210 (2006).
jannie@unimelb.edu.au
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C. M. Widdifield and R. W. Schurko
A solid-state 39K and 13C NMR study of polymeric potassium metallocenes,
J. Phys. Chem. A 109, 6865-6876 (2005).
rschurko@uwindsor.ca
-
A. Wong, R. D. Whitehead, Z. H. Gan, and G. Wu
A solid-state NMR and computational study of sodium and potassium tetraphenylborates: 23Na and 39K NMR signatures for systems containing cation-pi interactions,
J. Phys. Chem. A 108, 10551-10559 (2004).
gangwu@chem.queensu.ca
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N. G. Dowell, S. E. Ashbrook, and S. Wimperis
Satellite-transition MAS NMR of low-gamma nuclei at natural abundance: sensitivity, practical implementation, and application to 39K (I = 3/2) and 25Mg (I = 5/2),
J. Phys. Chem. B 108, 13292-13299 (2004).
s.wimperis@exeter.ac.uk
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R. W. Schurko, I. Hung, and C. M. Widdifield
Signal enhancement in NMR spectra of half-integer quadrupolar nuclei via DFS-QCPMG and RAPT-QCPMG pulse sequences,
Chem. Phys. Lett. 379, 1-10 (2003).
rschurko@uwindsor.ca
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G. Wu, A. Wong, Z. Gan, and J. T. Davis
Direct detection of potassium cations bound to G-quadruplex structures by solid-state 39K NMR at 19.6 T,
J. Am. Chem. Soc. 125, 7182-7183 (2003).
gangwu@chem.queensu.ca
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J. F. Stebbins, L.-S. Du, S. Kroeker, P. Neuhoff, D. Rice,
J. Frye, and H. J. Jakobsen
New opportunities for high-resolution solid-state NMR spectroscopy of oxide materials at 21.1- and 18.8-T fields,
Solid State NMR 21, 105-115 (2002).
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A. R. Lim, D. Y. Jeong, and H. M. Park
39K NMR in a KHSO4 single crystal,
J. Phys.: Condens. Matter 13, 3511-3517 (2001).
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F. H. Larsen, J. Skibsted, H. J. Jakobsen, and N. C. Nielsen
Solid-state QCPMG NMR of low-gamma quadrupolar metal nuclei in natural abundance,
J. Am. Chem. Soc. 122, 7080-7086 (2000).
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K. Endo, M. Kenmotsu, J. Frye, K. Honda, S. Kitagawa,
and K. Deguchi
Structure analysis of KxRb1-xX (X = Br, I) mixed crystals by 87Rb and 39K NMR and X-ray diffraction methods,
J. Phys. Chem. Solids 57, 1609-1614 (1996).
-
T. J. Bastow
Powder determination of 39K nuclear quadrupole coupling,
J. Chem. Soc., Faraday Trans. 87, 2453-2455 (1991).
More solid-state K-39/41 NMR references.
Solid-state NMR bibliography for
- Aluminum-27 (鋁)
- Antimony-121/123 (銻)
- Arsenic-75 (砷)
- Barium-135/137 (鋇)
- Beryllium-9 (鈹)
- Bismuth-209 (鉍)
- Boron-10/11 (硼)
- Bromine-79/81 (溴)
- Calcium-43 (鈣)
- Cesium-133 (銫)
- Chlorine-35/37 (氯)
- Chromium-53 (鉻)
- Cobalt-59 (鈷)
- Copper-63/65 (銅)
- Deuterium-2 (氘)
- Gallium-69/71 (鎵)
- Germanium-73 (鍺)
- Gold-197 (金)
- Hafnium-177/179 (鉿)
- Indium-113-115 (銦)
- Iodine-127 (碘)
- Iridium-191/193 (銥)
- Krypton-83 (氪)
- Lanthanum-139 (鑭)
- Lithium-6/7 (鋰)
- Magnesium-25 (鎂)
- Manganese-55 (錳)
- Mercury-201 (銾)
- Molybdenum-95/97 (鉬)
- Neon-21 (氖)
- Nickel-61 (鎳)
- Niobium-93 (鈮)
- Nitrogen-14 (氮)
- Osmium-189 (鋨)
- Oxygen-17 (氧)
- Palladium-105 (鈀)
- Potassium-39/41 (鉀)
- Rhenium-185/187 (錸)
- Rubidium-85/87 (銣)
- Ruthenium-99/101 (釕)
- Scandium-45 (鈧)
- Sodium-23 (鈉)
- Strontium-87 (鍶)
- Sulfur-33 (硫)
- Tantalum-181 (鉭)
- Titanium-47/49 (鈦)
- Vanadium-51 (釩)
- Xenon-131 (氥)
- Zinc-67 (鋅)
- Zirconium-91 (鋯)
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