Sodium-23 NMR




Home and Applets > Periodic Table > Sodium
Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Na-23 3/2 100 10.4 9.25E-2 9.25E-2 -26.451 NaCl
. . . . . . . .

Directory of solid-state Na-23 NMR references
Single Crystal Crystalline Powder
Micro-Porous, Na2HPO4 NaH2PO4, Na2SO4, Na2SO3, NaCl, NaNO3, NaNO2...
Amorphous Powder

Solid-state sodium NMR references

  1. T. Gullion
    Dipolar recoupling of I = 1/2, S = 3/2 spin pairs with SEDOR for static and spinning samples,
    Magn. Reson. Chem. 45, S65-S67 (2008).
     
  2. M. Xu and K. D. M. Harris
    Triple-quantum 23Na MAS NMR spectroscopy as a technique for probing polymorphism in sodium salts,
    Cryst. Growth Des. 8, 6-10 (2008).
     
  3. W. Stroiek, C. M. Felise, H. Eckert, B. Ewald, and R. Kniep
    Site discrimination in the crystalline borophosphate Na5B2P3O13 using advanced solid-state NMR techniques,
    Solid State NMR 32, 89-98 (2007).
     
  4. C. M. Widdifield, J. A. Tang, C. L. B. Macdonald, and R. W. Schurko
    Investigation of structure and dynamics in the sodium metallocenes CpNa and CpNa·THF via solid-state NMR, X-ray diffraction and computational modelling,
    Magn. Res. Chem. 45, S116-S128 (2007).
     
  5. Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
    Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
    J. Non-Cryst. Solids 353, 2582-2590 (2007).
     
  6. J. F. Zhu, N. Mosey, T. Woo, and Y. N. Huang
    Study of the adsorption of toluene in zeolite LiNa-Y by solid-state NMR Spectroscopy,
    J. Phys. Chem. C 111, 13427-13436 (2007).
     
  7. M. T. Rinke, L. Zhang, and H. Eckert
    Structural integration of tellurium oxide into mixed-network-former glasses: connectivity distribution in the system NaPO3-TeO2,
    ChemPhysChem. 8, 1988-1998 (2007).
     
  8. J. Trebosc, B. Hu, J. P. Amoureux, and Z. Gan
    Through-space R3-HETCOR experiments between spin-1/2 and half-integer quadrupolar nuclei in solid-state NMR,
    J. Magn. Reson. 186, 220-227 (2007).
    jean-paul.amoureux@univ-lillel.fr
     
  9. G. Mali
    Spin-locking and recoupling of homonuclear dipolar interaction between spin-3/2 nuclei under magic-angle sample spinning,
    J. Magn. Reson. 185, 318-325 (2007).
    gregor.mali@ki.si
     
  10. F. Angeli, M. Gaillard, P. Jollivet, and T. Charpentier
    Contribution of 43Ca MAS NMR for probing the structural configuration of calcium in glass,
    Chem. Phys. Lett. 440, 324-328 (2007).
    frederic.angeli@cea.fr
     
  11. J. Trebosc, J.-P. Amoureux, and Z. H. Gan
    Comparison of high-resolution solid-state NMR MQMAS and STMAS methods for half-integer quadrupolar nuclei,
    Solid State NMR 31, 1-9 (2007).
    jean-paul.amoureux@univ-lille1.fr
     
  12. P. Florian, E. M. Anghel, and C. Bessada
    Structural description of the Na2B4O7-Na3AlF6-TiO2 system. 2. A multinuclear NMR approach of melts and solids,
    J. Phys. Chem. B 111, 968-978 (2007).
    bessada@cnrs-orleans.fr
     
  13. M. Eden, D. Zhou, and J. H. Yu
    Improved double-quantum NMR correlation spectroscopy of dipolar-coupled quadrupolar spins,
    Chem. Phys. Lett. 431, 397-403 (2006).
    mattias@physc.su.se
     
  14. C. Martineau, M. Body, C. Legein, G. Silly, J. Y. Buzaré, and F. Fayon
    Multinuclear high-resolution NMR study of compounds from the ternary system NaF-CaF2-AlF3: From determination to modeling of NMR parameters,
    Inorg. Chem. 45, 10215-10223 (2006).
    charlotte.martineau.etu@univ-lemans.fr
     
  15. D. L. Bryce, S. Adiga, E. K. Elliott, and G. W. Gokel
    Solid-state 23Na NMR study of sodium lariat ether receptors exhibiting cation-π interactions,
    J. Phys. Chem. A 110, 13568-13577 (2006).
     
  16. S. E. Ashbrook, L. Le-Polles, R. Gautier, C. J. Pickard, and R. I. Walton
    23Na multiple-quantum MAS NMR of the perovskites NaNbO3 and NaTaO3,
    Phys. Chem. Chem. Phys. 8, 3423-3431 (2006).
    sema@st-andrews.ac.uk
     
  17. M. Itoh, I. Yamauchi, T. Kozuka, T. Suzuki, T. Yamauchi, J. Yamaura, and Y. Ueda
    Charge disproportionation and metal-insulator transition in the quasi-one-dimensional conductor βNa0.33V2O5: 23Na NMR study of a single crystal,
    Phys. Rev. B 74, 54434/1-54434/14 (2006).
     
  18. X. Y. Wen, X. J. Ai, J. X. Dong, J. Yang, C. H. Ye, and F. Deng
    Reaction of layered sodium disilicate SKS-6 with calcium chloride solution as revealed by solid state NMR spectroscopy: Exploring the calcium ion extracting mechanism of SKS-6,
    Solid State NMR 30, 89-97 (2006).
    dengf@wipm.ac.cn
     
  19. S. P. Puls and H. Eckert
    Site discrimination in mixed-alkali glasses studied by cross-polarization NMR,
    J. Phys. Chem. B 110, 14253-14261 (2006).
    eckerth@uni-muenster.de
     
  20. F. Muñoz, L. Montagne, L. Delevoye, A. Duran, L. Pascual, S. Cristol, and J. F. Paul
    Phosphate speciation in sodium borosilicate glasses studied by nuclear magnetic resonance,
    J. Non-Cryst. Solids 352, 2958-2968 (2006).
    lionel.montagne@univ-lille1.fr
     
  21. C. C. de-Araujo, W. Strojek, L. Zhang, H. Eckert, G. Poirier, S. J. L. Ribeiro, and Y. Messaddeq
    Structural studies of NaPO3-WO3 glasses by solid state NMR and Raman spectroscopy,
    J. Mater. Chem. 16, 3277-3284 (2006).
    eckerth@uni-muenster.de
     
  22. X. Xu and R. J. Kirkpatrick
    NaCl interaction with interfacially polymerized polyamide films of reverse osmosis membranes: A solid-state 23Na NMR study,
    J. Membrane Sci. 280, 226-233 (2006).
    xiangxu1@illinoisalumni.org; kirkpat@uiuc.edu
     
  23. R. Kharrazian and P. M. Jakob
    Dynamics of 23Na during completely balanced steady-state free precession,
    J. Magn. Reson. 179, 73-84 (2006).
    rakharra@physik.uni-wuerzburg.de
     
  24. M. Edén
    Quadrupolar coupling selective cross-polarization in solid state NMR,
    Phys. Chem. Chem. Phys. 8, 1994-1999 (2006).
    mattias@physc.su.se
     
  25. A. Y. H. Lo, R. W. Schurko, M. Vettraino, B. O. Skadtchenko, M. Trudeau, and D. M. Antonelli
    Solid-state 23Na and 7Li NMR investigations of sodium- and lithium-reduced mesoporous titanium oxides,
    Inorg. Chem. 45, 1828-1838 (2006).
    rschurko@uwindsor.ca; danton@uwindsor.ca
     
  26. M. Nyman, A. J. Celestian, J. B. Parise, G. P. Holland, and T. M. Alam
    Solid-state structural characterization of a rigid framework of lacunary heteropolyniobates,
    Inorg. Chem. 45, 1043-1052 (2006).
    mdnyman@sandia.gov
     
  27. M. Kotecha, S. Chaudhuri, C. P. Grey, and L. Frydman
    Dynamic effects in MAS and MQMAS NMR spectra of half-integer quadrupolar nuclei: Calculations and an application to the double perovskite cryolite,
    J. Am. Chem. Soc. 127, 16701-16712 (2005).
    lucio.frydman@weizmann.ac.il
     
  28. C. H. Liao, P. C. Chang, H. M. Kao, and K. H. Lii
    Synthesis, crystal structure, and solid-state NMR spectroscopy of a salt-inclusion stannosilicate: [Na3F][SnSi3O9],
    Inorg. Chem. 44, 9335-9339 (2005).
    hmkao@cc.ncu.edu.tw; liikh@cc.ncu.edu.tw
     
  29. R. Kumar, W. Ling, W. Schoefberger, and A. Jerschow
    Separated quadrupolar field experiment,
    J. Magn. Reson. 172, 209-213 (2005).
    alexej.jerschow@nyu.edu
     
  30. J. D. Epping, W. Strojek, and H. Eckert
    Cation environments and spatial distribution in Na2O-B2O3 glasses: New results from solid state NMR,
    Phys. Chem. Chem. Phys. 7, 2384-2389 (2005).
     
  31. H. Trill, H. Eckert, and V. I. Srdanov
    NMR study of interacting F centers in Na8[Al6Si6O24]Cl2 sodalite,
    Phys. Rev. B 71, 014412/1-014412/6 (2005).
     
  32. J. P. Amoureux, L. Delevoye, S. Steuernagel, Z. Gan, S. Ganapathy, and L. Montagne
    Increasing the sensitivity of 2D high-resolution NMR methods applied to quadrupolar nuclei,
    J. Magn. Reson. 172, 268-278 (2005).
    jean-paul.amoureux@univ-lille1.fr
     
  33. C. Johnson, E. A. Moore, and M. Mortimer
    Periodic ab initio calculation of nuclear quadrupole parameters as an assignment tool in solid-state NMR spectroscopy: applications to 23Na NMR spectra of crystalline materials,
    Solid State NMR 27, 155-164 (2005).
    m.mortimer@open.ac.uk
     
  34. G. Silly, C. Legein, J. Y. Buzaré, and F. Calvayrac
    Electric field gradients in fluoride crystalline powders: correlation of NMR measurements with ab initio calculations,
    Solid State NMR 25, 241-251 (2004).
    gilles.silly@univ-lemans.fr
     
  35. R. Siegel, T. T. Nakashima, and R. E. Wasylishen
    Signal enhancement of NMR spectra of half-integer quadrupolar nuclei in solids using hyperbolic secant pulses,
    Chem. Phys. Lett. 388, 441-445 (2004).
    roderick.wasylishen@ualberta.ca
     
  36. R. W. Schurko, M. J. Willans, B. Skadtchenko, and D. M. Antonelli
    Solid-state 23Na and 13C NMR characterization of Na3C60,
    J. Solid State Chem. 177, 2255-2264 (2004).
    rschurko@uwindsor.ca
     
  37. G. Mali and V. Kaucic
    Enhancing sensitivity or resolution of homonuclear correlation experiment for half-integer quadrupolar nuclei,
    J. Magn. Reson. 171, 48-56 (2004).
    gregor.mali@ki.si
     
  38. A. Wong, R. D. Whitehead, Z. H. Gan, and G. Wu
    A solid-state NMR and computational study of sodium and potassium tetraphenylborates: 23Na and 39K NMR signatures for systems containing cation-pi interactions,
    J. Phys. Chem. A 108, 10551-10559 (2004).
    gangwu@chem.queensu.ca
     
  39. T. G. Ajithkumar, E. R. H. van-Eck, and A. P. M. Kentgens
    Homonuclear correlation experiments for quadrupolar nuclei, spinning away from the magic angle,
    Solid State NMR 26, 180-186 (2004).
    arno.kentgens@nmr.kun.nl
     
  40. A. Goldbourt, E. Vinogradov, G. Goobes, and S. Vega
    High resolution heteronuclear correlation NMR spectroscopy between quadrupolar nuclei and protons in the solid state,
    J. Magn. Reson. 169, 342-350 (2004).
    shimon.vega@weizmann.ac.il
     
  41. Z. H. Gan and H. T. Kwak
    Enhancing MQMAS sensitivity using signals from multiple coherence transfer pathways,
    J. Magn. Reson. 168, 346-351 (2004).
    gan@magnet.fsu.edu
     
  42. H. X. Yang, R. I. Walton, S. Antonijevic, S. Wimperis, and A. C. Hannon
    Local order of amorphous zeolite precursors from 29Si[1H] CPMAS and 27Al and 23Na MQMAS NMR and evidence for the nature of medium-range order from neutron diffraction,
    J. Phys. Chem. B 108, 8208-8217 (2004).
    r.i.walton@exeter.ac.uk
     
  43. G. Mali and F. Taulelle
    Detecting proximities between quadrupolar nuclei by double-quantum NMR,
    Chem. Commun. 868-869 (2004).
    gregor.mali@ki.si
     
  44. S. E. Ashbrook and S. Wimperis
    Spin-locking of half-integer quadrupolar nuclei in nuclear magnetic resonance of solids: Creation and evolution of coherences,
    J. Chem. Phys. 120, 2719-2731 (2004).
    s.wimperis@exeter.ac.uk
     
  45. T. Bräuniger, K. Ramaswamy, and P. K. Madhu
    Enhancement of the central-transition signal in static and magic-angle-spinning NMR of quadrupolar nuclei by frequency-swept fast amplitude-modulated pulses,
    Chem. Phys. Lett. 383, 403-410 (2004).
    braeuniger@physik.uni-halle.de; madhu@tifr.res.in
     
  46. Z. H. Liu, F. Deng, and S. W. Ding
    Effects of pulse strength, width, and sample spinning speed on the spectral spin diffusion of multiquantum coherences of spin-3/2 quadrupolar nuclei,
    J. Chem. Phys. 120, 740-748 (2004).
    dengf@wipm.ac.cn; ding@mail.nsysu.edu.tw
     
  47. A. Wong, G. Wu
    Selective binding of monovalent cations to the stacking G-quartet structure formed by guanosine 5'-monophosphate: A solid-state NMR study,
    J. Am. Chem. Soc. 125, 13895-13905 (2003).
    gangwu@chem.queensu.ca
     
  48. M. Edén and L. Frydman
    Homonuclear NMR correlations between half-integer quadrupolar nuclei undergoing magic-angle spinning,
    J. Phys. Chem. B 107, 14598-14611 (2003).
    Lucio.Frydman@weizinann.ac.il
     
  49. A. D. Bain
    Exact calculation, using angular momentum, of combined Zeeman and quadrupolar interactions in NMR,
    Molec. Phys. 101, 3163-3175 (2003).
    bain@mcmaster.ca
     
  50. C. M. Morais, M. Lopes, C. Fernandez, and J. Rocha
    Assessing the potential of fast amplitude modulation pulses for improving triple-quantum magic angle spinning NMR spectra of half-integer quadrupolar nuclei,
    Magn. Reson. Chem. 41, 679-688 (2003).
    rocha@dq.ua.pt
     
  51. X. J. Ai, L. Chen, J. X. Dong, C. H. Ye, and F. Deng
    Variation of sodium coordination during the hydration processes of layered sodium disilicates as studied by 23Na MQMAS and 1H <-> 23Na CP/MAS NMR spectroscopy,
    J. Mater. Chem. 13, 614-621 (2003).
    dengf@wipm.ac.cn
     
  52. M. J. Willans and R. W. Schurko
    A solid-state NMR and ab initio study of sodium metallocenes,
    J. Phys. Chem. B 107, 5144-5161 (2003).
    rschurko@uwindsor.ca
     
 
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