Nitrogen-14 NMR




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Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
N-14 1 99.63 2.044 1.01E-3 1.01E-3 -7.224 CH3NO2
N-15 1/2 0.37 0 1.04E-3 3.85E-6 10.133 MeNO2

Solid-state nitrogen NMR references

  1. L. A. O'Dell and R. W. Schurko
    Static solid-state 14N NMR and computational studies of nitrogen EFG tensors in some crystalline amino acids,
    Phys. Chem. Chem. Phys. 11, 7069-7077 (2009).
    Abstract
     
  2. L. A. O'Dell and R. W. Schurko
    Fast and simple acquisition of solid-state 14N NMR spectra with signal enhancement via population transfer,
    J. Am. Chem. Soc. 131, 6658-6659 (2009).
    Abstract
     
  3. R. S. Stein, B. Elena, and L. Emsley
    Improving resolution in proton solid-state NMR by removing nitrogen-14 residual dipolar broadening,
    Chem. Phys. Lett. 458, 391-395 (2008).
     
  4. N. M. Trease and P. J. Grandinetti
    Solid-state nuclear magnetic resonance in the rotating tilted frame,
    J. Chem. Phys. 128, 52318/1-52318/12 (2008).
     
  5. S. Cavadini, A. Abraham, and G. Bodenhausen
    Coherence transfer between spy nuclei and nitrogen-14 in solids,
    J. Magn. Reson. 190, 160-164 (2008).
     
  6. C. A. Fyfe, R. J. Darton, C. Schneider, and F. Scheffler
    Solid-state NMR investigation of the possible existence of "Nanoblocks" in the clear solution synthesis of MFI materials,
    J. Phys. Chem. C 112, 80-88 (2008).
     
  7. S. Cavadini, S. Antonijevic, A. Lupulescu, and G. Bodenhausen
    Indirect detection of nitrogen-14 in solid-state NMR spectroscopy,
    ChemPhysChem. 8, 1363-1374 (2007).
     
  8. T. N. Rudakov
    Some aspects of spin-locking effect in nitrogen-14 quadrupolar spin-system,
    Chem. Phys. Lett. 443, 269-273 (2007).
     
  9. H. J. Jakobsen, A. R. Hove, H. Bildsoe, J. Skibsted, M. Brorson
    Long-term stability of rotor-controlled MAS frequencies to 0.1 Hz proved by 14N MAS NMR experiments and simulations,
    J. Magn. Reson. 185, 159-163 (2007).
    hja@chem.au.dk
     
  10. Z. H. Gan, J.-P. Amoureux, and J. Trebosc
    Proton-detected 14N MAS NMR using homonuclear decoupled rotary resonance,
    Chem. Phys. Lett. 435, 163-169 (2007).
    gan@magnet.fsu.edu
     
  11. Z. H. Gan
    13C/14N heteronuclear multiple-quantum correlation with rotary resonance and REDOR dipolar recoupling,
    J. Magn. Reson. 184, 39-43 (2007).
    gan@magnet.fsu.edu
     
  12. Z. H. Gan
    Measuring multiple carbon-nitrogen distances in natural abundant solids using R-RESPDOR NMR,
    Chem. Commun.4712-4714 (2006).
    gan@magnet.fsu.edu
     
  13. A. R. Hove, H. Bildsoe, J. Skibsted, M. Brorson, and H. J. Jakobsen
    Probing crystal structures and transformation reactions of ammonium molybdates by 14N MAS NMR spectroscopy,
    Inorg. Chem. 45, 10873-10881 (2006).
    hja@chem.au.dk
     
  14. H. J. Jakobsen, A. R. Hove, R. G. Hazell, H. Bildsøe, and J. Skibsted
    Solid-state 14N MAS NMR of ammonium ions as a spy to structural insights for ammonium salts,
    Magn. Reson. Chem. 44, 348-356 (2006).
    hja@chem.au.dk
     
  15. J. P. Yesinowski
    69,71Ga and 14N high-field NMR of gallium nitride films,
    phys. stat. sol. (c) 2, 2399-2402 (2005).
    yesinows@ccs.nrl.navy.mil
     
  16. A. P. Purdy, J. P. Yesinowski, and A. T. Hanbicki
    Synthesis, solid-state NMR, and magnetic characterization of h-GaN containing magnetic ions,
    phys. stat. sol. (c) 2, 2437-2440 (2005).
    purdy1@ccs.nrl.navy.mil
     
  17. Gerard S. Harbison, Young-Sik Kye, Glenn H. Penner, Michelle Grandin, and Martine Monette
    14N quadrupolar, 14N and 15N chemical shift, and 14N-1H dipolar tensors of sulfamic acid,
    J. Phys. Chem. B 106, 10285-10291 (2002).
    Abstract
     
  18. M. Punkkinen, A. H. Vuorimäki, E. E. Ylinen, and A. Kaikkonen
    14N NMR echo in NH4ClO4 after the pulse sequence (θ1)x–τ–(θ2)y–t,
    J. Magn. Reson. 130, 287-291 (1998).
     
  19. E. A. Hill and J. P. Yesinowski
    A slow turning method for measuring large anisotropic interactions in inhomogeneously broadened NMR spectra,
    J. Chem. Phys. 106, 8650-8659 (1997).
     
  20. E. A. Hill and J. P. Yesinowski
    Solid-state 14N NMR techniques for studying slow molecular motions,
    J. Chem. Phys. 107, 346-354 (1997).
     
  21. E. A. Hill and J. P. Yesinowski
    Wide-line 14N NMR in solids and reorientation-induced redistribution of isochromats,
    J. Am. Chem. Soc. 118, 6798-6799 (1996).
     

Related bibliography

  1. Simone Cavadini
    Indirect detection of nitrogen-14 in solid-state NMR spectroscopy,
    Prog. Nucl. Magn. Reson. Spectrosc. 56, 46-77 (2010).
    Abstract
     
  2. S. Cavadini, S. Antonijevic, A. Lupulescu, and G. Bodenhausen
    Indirect detection of nitrogen-14 in solids via protons by nuclear magnetic resonance spectroscopy,
    J. Magn. Reson. 182, 168-172 (2006).
    Sasa.Antonijevic@epfl.ch
     
 
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