Rubidium-85 and rubidium-87 NMR




Home and Applets > Periodic Table > Rubidium
Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Rb-85 5/2 72.15 27.6 1.05E-2 7.57E-3 -9.655 RbCl
Rb-87 3/2 27.85 13.35 0.17 4.87E-2 -32.721

Directory of solid-state Rb-85 and Rb-87 NMR references
Single Crystal Crystalline Powder
Rb2CrO4, RbVO3, Salt
Amorphous Powder

Solid-state rubidium NMR references

  1. R. Bhattacharyya and L. Frydman
    Quadrupolar nuclear magnetic resonance spectroscopy in solids using frequency-swept echoing pulses,
    J. Chem. Phys. 127, 194503/1-194503/8 (2007).
     
  2. Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
    Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
    J. Non-Cryst. Solids 353, 2582-2590 (2007).
     
  3. T. J. Ball and S. Wimperis
    Use of SPAM and FAM pulses in high-resolution MAS NMR spectroscopy of quadrupolar nuclei,
    J. Magn. Reson. 187, 343-351 (2007).
     
  4. J. Trebosc, J.-P. Amoureux, and Z. H. Gan
    Comparison of high-resolution solid-state NMR MQMAS and STMAS methods for half-integer quadrupolar nuclei,
    Solid State NMR 31, 1-9 (2007).
    jean-paul.amoureux@univ-lille1.fr
     
  5. R. Siegel, T. T. Nakashima, and R. E. Wasylishen
    Sensitivity enhancement of NMR spectra of half-integer spin quadrupolar nuclei in solids using hyperbolic secant pulses,
    J. Magn. Reson. 184, 85-100 (2007).
    Roderick.wasylishen@ualberta.ca
     
  6. T. Vosegaard, C. Kehlet, N. Khaneja, S. J. Glaser, and N. C. Nielsen
    Improved excitation schemes for multiple-quantum magic-angle spinning for quadrupolar nuclei designed using optimal control theory,
    J. Am. Chem. Soc. 127, 13768-13769 (2005).
    tv@ehem.au.dk; nen@chem.au.dk
     
  7. S. E. Ashbrook and S. Wimperis
    Rotor-synchronized acquisition of quadrupolar satellite-transition NMR spectra: practical aspects and double-quantum filtration,
    J. Magn. Reson. 177, 44-55 (2005).
    s.wimperis@exeter.ac.uk
     
  8. N. Malicki, L. Mafra, A.-A. Quoineaud, J. Rocha, F. Thibault-Starzyk, and C. Fernandez
    Multiplex MQMAS NMR of quadrupolar nuclei,
    Solid State NMR 28, 13-21 (2005).
    christian.fernandez@ensicaen.fr
     
  9. J.-P. Amoureux, L. Delevoye, G. Fink, F. Taulelle, A. Flambard, and L. Montagne
    Implementing SPAM into STMAS: a net sensitivity improvement in high-resolution NMR of quadrupolar nuclei,
    J. Magn. Reson. 175, 285-299 (2005).
    jean-paul.amoureux@univ-lille1.fr
     
  10. B. O. Skadtchenko, M. Trudeau, R. W. Schurko, A. Y. H. Lo, and D. M. Antonelli
    Electronic properties and solid-state 87Rb and 13C NMR studies of mesoporous tantalum oxide rubidium fulleride composites,
    Chem. Mater. 17, 1467-1478 (2005).
     
  11. Renée Siegel, T. T. Nakashima, and R. E. Wasylishen
    Sensitivity enhancement of MQMAS NMR spectra of spin 3/2 nuclei using hyperbolic secant pulses,
    Chem. Phys. Lett. 403, 353-358 (2005).
    roderick.wasylishen@ualberta.ca
     
  12. R. Siegel, T. T. Nakashima, and R. E. Wasylishen
    Signal enhancement of NMR spectra of half-integer quadrupolar nuclei in solids using hyperbolic secant pulses,
    Chem. Phys. Lett. 388, 441-445 (2004).
    roderick.wasylishen@ualberta.ca
     
  13. R. W. Schurko, I. Hung, and C. M. Widdifield
    Signal enhancement in NMR spectra of half-integer quadrupolar nuclei via DFS-QCPMG and RAPT-QCPMG pulse sequences,
    Chem. Phys. Lett. 379, 1-10 (2003).
    rschurko@uwindsor.ca
     
  14. H. T. Kwak and Z. H. Gan
    Double-quantum filtered STMAS,
    J. Magn. Reson. 164, 369-372 (2003).
    gan@magnet.fsu.edu
     
  15. S. E. Ashbrook and S. Wimperis
    SCAM-STMAS: satellite-transition MAS NMR of quadrupolar nuclei with self-compensation for magic-angle misset,
    J. Magn. Reson. 162, 402-416 (2003).
    s.wimperis@exeter.ac.uk
     
  16. J.-P. Amoureux, C. Morais, J. Trebosc, J. Rocha, and C. Fernandez
    I-STMAS, a new high-resolution solid-state NMR method for half-integer quadrupolar nuclei,
    Solid State NMR 23, 213-223 (2003).
    jean-paul.amoureux@univ-lille1.fr; christian.fernandez@ismra.fr
     
  17. P. K. Madhu, K. J. Pike, R. Dupree, M. H. Levitt, and M. E. Smith
    Modulation-aided signal enhancement in the magic angle spinning NMR of spin-5/2 nuclei,
    Chem. Phys. Lett. 367, 150-156 (2003).
    mhl@soton.ac.uk; m.e.smith.1@warwick.ac.uk
     
  18. A. Jerschow and R. Kumar
    Calculation of coherence pathway selection and cogwheel cycles,
    J. Magn. Reson. 160, 59-64 (2003).
    alexej.jerschow@nyu.edu
     
  19. R. Lefort, J. W. Wiench, M. Pruski, and J.-P. Amoureux
    Optimization of data acquisition and processing in Carr-Purcel-Meiboom-Gill MQMAS NMR,
    J. Chem. Phys. 116, 2493-2501 (2002).
    mpruski@iastate.edu
     
  20. S. Wi, J. W. Logan, D. Sakellariou, J. D. Walls, and A. Pines
    Rotary resonance recoupling for half-integer quadrupolar nuclei in solid-state nuclear magnetic resonance spectroscopy,
    J. Chem. Phys. 117, 7024-7033 (2002).
    pines@cchem.berkeley.edu
     
  21. S. E. Ashbrook and S. Wimperis
    Satellite-transition MAS NMR of spin I = 3/2, 5/2, 7/2, and 9/2 nuclei: sensitivity, resolution, and practical implementation,
    J. Magn. Reson. 156, 269-281 (2002).
    s.wimperis@exeter.ac.uk
     
  22. D. D. Laws, H.-M. L. Bitter, and A. Jerschow
    Solid-state NMR spectroscopic methods in chemistry,
    Angew. Chem. Int. Ed. 41, 3096-3129 (2002).
    alexej.jerschow@nyu.edu
     
  23. D. Massiot, F. Fayon, M. Capron, I. King, S. Le Calvé, B. Alonso, J.-O. Durand, B. Bujoli, Z. Gan, and G. Hoatson
    Modelling one- and two-dimensional solid-state NMR spectra,
    Magn. Reson. Chem. 40, 70-76 (2002).
    massiot@cnrs-orleans.fr
     
 
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