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> Rubidium
| Isotope | Spin | Natural abundance(%) |
Quadrupole moment (10-30m2) |
Relative sensitivity |
Absolute sensitivity |
NMR frequency (MHz) at a field of 2.3488T |
Reference sample |
|---|---|---|---|---|---|---|---|
| Rb-85 | 5/2 | 72.15 | 27.6 | 1.05E-2 | 7.57E-3 | -9.655 | RbCl |
| Rb-87 | 3/2 | 27.85 | 13.35 | 0.17 | 4.87E-2 | -32.721 |
| Directory of solid-state Rb-85 and Rb-87 NMR references | ||
|---|---|---|
| Single Crystal |
Crystalline Powder Rb2CrO4, RbVO3, Salt |
Amorphous Powder |
Solid-state rubidium NMR references
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L. A. O'Dell, K. J. Harris, and R. W. Schurko
Optimized excitation pulses for the acquisition of static NMR powder patterns from half-integer quadrupolar nuclei,
J. Magn. Reson. 203, 156-166 (2010).
Abstract
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Krishna K. Dey, Jason T. Ash, Nicole M. Trease, and Philip J. Grandinetti
Trading sensitivity for information: Carr–Purcell–Meiboom–Gill acquisition in solid-state NMR,
J. Chem. Phys. 133, 054501/1-054501/10 (2008).
Abstract
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Joel A. Tang, Luke A. O’Dell, Pedro M. Aguiar, Bryan E. G. Lucier,
Dimitris Sakellariou, and Robert W. Schurko
Application of static microcoils and WURST pulses for solid-state ultra-wideline NMR spectroscopy of quadrupolar nuclei ,
Chem. Phys. Lett. 466, 227-234 (2008).
Abstract
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Luke A. O’Dell and Robert W. Schurko
QCPMG using adiabatic pulses for faster acquisition of ultra-wideline NMR spectra,
Chem. Phys. Lett. 464, 97-102 (2008).
Abstract
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M. J. Thrippleton, T. J. Ball, and S. Wimperis
Satellite transitions acquired in real time by magic angle spinning (STARTMAS): "Ultrafast" high-resolution MAS NMR spectroscopy of spin I = 3/2 nuclei ,
J. Chem. Phys. 128, 34507/1-34507/9 (2008).
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Krishna K. Dey, S. Prasad, Jason T. Ash, Michael Deschamps, and Philip J. Grandinetti
Spectral editing in solid-state MAS NMR of quadrupolar nuclei using selective satellite inversion,
J. Magn. Reson. 185, 326-330 (2007).
Abstract
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R. Bhattacharyya and L. Frydman
Quadrupolar nuclear magnetic resonance spectroscopy in solids using frequency-swept echoing pulses,
J. Chem. Phys. 127, 194503/1-194503/8 (2007).
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Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
J. Non-Cryst. Solids 353, 2582-2590 (2007).
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T. J. Ball and S. Wimperis
Use of SPAM and FAM pulses in high-resolution MAS NMR spectroscopy of quadrupolar nuclei,
J. Magn. Reson. 187, 343-351 (2007).
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J. Trebosc, J.-P. Amoureux, and Z. H. Gan
Comparison of high-resolution solid-state NMR MQMAS and STMAS methods for half-integer quadrupolar nuclei,
Solid State NMR 31, 1-9 (2007).
jean-paul.amoureux@univ-lille1.fr
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R. Siegel, T. T. Nakashima, and R. E. Wasylishen
Sensitivity enhancement of NMR spectra of half-integer spin quadrupolar nuclei in solids using hyperbolic secant pulses,
J. Magn. Reson. 184, 85-100 (2007).
Roderick.wasylishen@ualberta.ca
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T. Vosegaard, C. Kehlet, N. Khaneja, S. J. Glaser, and N. C. Nielsen
Improved excitation schemes for multiple-quantum magic-angle spinning for quadrupolar nuclei designed using optimal control theory,
J. Am. Chem. Soc. 127, 13768-13769 (2005).
tv@ehem.au.dk; nen@chem.au.dk
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S. E. Ashbrook and S. Wimperis
Rotor-synchronized acquisition of quadrupolar satellite-transition NMR spectra: practical aspects and double-quantum filtration,
J. Magn. Reson. 177, 44-55 (2005).
s.wimperis@exeter.ac.uk
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N. Malicki, L. Mafra, A.-A. Quoineaud, J. Rocha, F. Thibault-Starzyk, and C. Fernandez
Multiplex MQMAS NMR of quadrupolar nuclei,
Solid State NMR 28, 13-21 (2005).
christian.fernandez@ensicaen.fr
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J.-P. Amoureux, L. Delevoye, G. Fink, F. Taulelle, A. Flambard, and L. Montagne
Implementing SPAM into STMAS: a net sensitivity improvement in high-resolution NMR of quadrupolar nuclei,
J. Magn. Reson. 175, 285-299 (2005).
jean-paul.amoureux@univ-lille1.fr
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B. O. Skadtchenko, M. Trudeau, R. W. Schurko, A. Y. H. Lo,
and D. M. Antonelli
Electronic properties and solid-state 87Rb and 13C NMR studies of mesoporous tantalum oxide rubidium fulleride composites,
Chem. Mater. 17, 1467-1478 (2005).
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Renée Siegel, T. T. Nakashima, and R. E. Wasylishen
Sensitivity enhancement of MQMAS NMR spectra of spin 3/2 nuclei using hyperbolic secant pulses,
Chem. Phys. Lett. 403, 353-358 (2005).
roderick.wasylishen@ualberta.ca
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R. Siegel, T. T. Nakashima, and R. E. Wasylishen
Signal enhancement of NMR spectra of half-integer quadrupolar nuclei in solids using hyperbolic secant pulses,
Chem. Phys. Lett. 388, 441-445 (2004).
roderick.wasylishen@ualberta.ca
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R. W. Schurko, I. Hung, and C. M. Widdifield
Signal enhancement in NMR spectra of half-integer quadrupolar nuclei via DFS-QCPMG and RAPT-QCPMG pulse sequences,
Chem. Phys. Lett. 379, 1-10 (2003).
rschurko@uwindsor.ca
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H. T. Kwak and Z. H. Gan
Double-quantum filtered STMAS,
J. Magn. Reson. 164, 369-372 (2003).
gan@magnet.fsu.edu
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S. E. Ashbrook and S. Wimperis
SCAM-STMAS: satellite-transition MAS NMR of quadrupolar nuclei with self-compensation for magic-angle misset,
J. Magn. Reson. 162, 402-416 (2003).
s.wimperis@exeter.ac.uk
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J.-P. Amoureux, C. Morais, J. Trebosc, J. Rocha, and C. Fernandez
I-STMAS, a new high-resolution solid-state NMR method for half-integer quadrupolar nuclei,
Solid State NMR 23, 213-223 (2003).
jean-paul.amoureux@univ-lille1.fr; christian.fernandez@ismra.fr
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P. K. Madhu, K. J. Pike, R. Dupree, M. H. Levitt, and M. E. Smith
Modulation-aided signal enhancement in the magic angle spinning NMR of spin-5/2 nuclei,
Chem. Phys. Lett. 367, 150-156 (2003).
mhl@soton.ac.uk; m.e.smith.1@warwick.ac.uk
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A. Jerschow and R. Kumar
Calculation of coherence pathway selection and cogwheel cycles,
J. Magn. Reson. 160, 59-64 (2003).
alexej.jerschow@nyu.edu
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R. Lefort, J. W. Wiench, M. Pruski, and J.-P. Amoureux
Optimization of data acquisition and processing in Carr-Purcel-Meiboom-Gill MQMAS NMR,
J. Chem. Phys. 116, 2493-2501 (2002).
mpruski@iastate.edu
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S. Wi, J. W. Logan, D. Sakellariou, J. D. Walls, and A. Pines
Rotary resonance recoupling for half-integer quadrupolar nuclei in solid-state nuclear magnetic resonance spectroscopy,
J. Chem. Phys. 117, 7024-7033 (2002).
pines@cchem.berkeley.edu
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S. E. Ashbrook and S. Wimperis
Satellite-transition MAS NMR of spin I = 3/2, 5/2, 7/2, and 9/2 nuclei: sensitivity, resolution, and practical implementation,
J. Magn. Reson. 156, 269-281 (2002).
s.wimperis@exeter.ac.uk
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D. D. Laws, H.-M. L. Bitter, and A. Jerschow
Solid-state NMR spectroscopic methods in chemistry,
Angew. Chem. Int. Ed. 41, 3096-3129 (2002).
alexej.jerschow@nyu.edu
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D. Massiot, F. Fayon, M. Capron, I. King, S. Le Calvé, B. Alonso,
J.-O. Durand, B. Bujoli, Z. Gan, and G. Hoatson
Modelling one- and two-dimensional solid-state NMR spectra,
Magn. Reson. Chem. 40, 70-76 (2002).
massiot@cnrs-orleans.fr
Solid-state NMR bibliography for
- Aluminum-27 (鋁)
- Antimony-121/123 (銻)
- Arsenic-75 (砷)
- Barium-135/137 (鋇)
- Beryllium-9 (鈹)
- Bismuth-209 (鉍)
- Boron-10/11 (硼)
- Bromine-79/81 (溴)
- Calcium-43 (鈣)
- Cesium-133 (銫)
- Chlorine-35/37 (氯)
- Chromium-53 (鉻)
- Cobalt-59 (鈷)
- Copper-63/65 (銅)
- Deuterium-2 (氘)
- Gallium-69/71 (鎵)
- Germanium-73 (鍺)
- Gold-197 (金)
- Hafnium-177/179 (鉿)
- Indium-113-115 (銦)
- Iodine-127 (碘)
- Iridium-191/193 (銥)
- Krypton-83 (氪)
- Lanthanum-139 (鑭)
- Lithium-6/7 (鋰)
- Magnesium-25 (鎂)
- Manganese-55 (錳)
- Mercury-201 (銾)
- Molybdenum-95/97 (鉬)
- Neon-21 (氖)
- Nickel-61 (鎳)
- Niobium-93 (鈮)
- Nitrogen-14 (氮)
- Osmium-189 (鋨)
- Oxygen-17 (氧)
- Palladium-105 (鈀)
- Potassium-39/41 (鉀)
- Rhenium-185/187 (錸)
- Rubidium-85/87 (銣)
- Ruthenium-99/101 (釕)
- Scandium-45 (鈧)
- Sodium-23 (鈉)
- Strontium-87 (鍶)
- Sulfur-33 (硫)
- Tantalum-181 (鉭)
- Titanium-47/49 (鈦)
- Vanadium-51 (釩)
- Xenon-131 (氥)
- Zinc-67 (鋅)
- Zirconium-91 (鋯)
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