Barium-135 and barium-137 NMR




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Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Ba-135 3/2 6.59 16.0 4.90E-3 3.22E-4 -9.934 BaCl2
Ba-137 3/2 11.32 24.5 6.86E-3 7.76E-4 -11.113

Solid-state barium NMR references

  1. Andre Sutrisno, Cheng Lu, R. H. Lipson, and Yining Huang
    Combined 135/137Ba solid-state NMR at an ultrahigh magnetic field and computational study of β-barium borate,
    J. Phys. Chem. C 113, 21196-21201 (2009).
    Abstract
     
  2. P. Sedykh, J. Haase, D. Michel, and E. V. Charnaya
    Investigation of barium titanate nanoparticles by 137Ba NMR,
    Ferroelectrics 363, 215-226 (2008).
     
  3. Christel Gervais, Delphine Veautier, Mark E. Smith, Florence Babonneau, Philippe Belleville, and Clément Sanchez
    Solid state 47,49Ti, 87Sr and 137Ba NMR characterisation of mixed barium/strontium titanate perovskites,
    Solid-State NMR 26, 147-152 (2004).
    gervais@ccr.jussieu.fr
     
  4. T. J. Bastow
    Electric field gradients at the M-site in MCO3: M = Mg, Ca, Sr and Ba,
    Chem. Phys. Lett. 354, 156-159 (2002).
    bastow@cmst.csiro.au
     
  5. K. J. D. MacKenzie and R. H. Meinhold
    Prospects for 137Ba MAS NMR spectroscopy of ceramics and related inorganic materials,
    Ceram. Int. 26, 87-92 (2000).
    k.mackenzie@irl.cri.nz
     
  6. T. J. Bastow and S. N. Stuart
    Electric quadrupole interaction of 137Ba in barium fluorohalides,
    Solid State NMR 6, 95-100 (1996).
     
  7. O. Kanert, H. Schulz, and J. Albers
    NMR study of the cubic-to-tetragonal phase transition in BaTiO3,
    Solid State Commun. 91, 465-469 (1994).
     
  8. S. F. Dec, M. F. Davis, G. E. Maciel, C. E. Bronnimann, J. J. Fitzgerald, and S. S. Han
    Solid-state multinuclear NMR studies of ferroelectric, piezoelectric, and related materials,
    Inorg. Chem. 32, 955-959 (1993).
     
  9. T. J. Bastow
    An NMR study of 137Ba and 47,49Ti in ferroelectric BaTiO3,
    J. Phys.: Condens. Matter 1, 4985-4991 (1989).
     
 

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