Chlorine-35 and chlorine-37 NMR




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Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Cl-35 3/2 75.53 -8.165 4.70E-3 3.55E-3 -9.798 NaCl
Cl-37 3/2 24.47 -6.435 2.71E-3 6.63E-4 -8.156

Solid-state chlorine NMR references

  1. F. A. Perras and D. L. Bryce
    Direct investigation of covalently bound chlorine in organic compounds by solid-state 35Cl NMR spectroscopy and exact spectral line-shape simulations,
    Angew. Chem. Int. Ed. 51, 4227-4230 (2012).
    Abstract
     
  2. Rebecca P. Chapman, Jennifer R. Hiscock, Philip A. Gale, and David L. Bryce
    A solid-state 35/37Cl NMR study of a chloride ion receptor and a GIPAW-DFT study of chlorine NMR interaction tensors in organic hydrochlorides,
    Can. J. Chem. 89, 822-834 (2011).
    Abstract
     
  3. L. Ramu, K. P. Ramesh, D. Ramananda, and R. Chandramani
    Temperature and pressure dependence of 35Cl NQR and spin lattice relaxation time in 2,3-dichloroanisole,
    Magn. Reson. Chem. 48, 593-599 (2010).
    Abstract
     
  4. Ivan Hung and Zhehong Gan
    On the practical aspects of recording wideline QCPMG NMR spectra,
    J. Magn. Reson. 204, 256-265 (2010).
    Abstract
     
  5. Luke A. O’Dell, Aaron J. Rossini, and Robert W. Schurko
    Acquisition of ultra-wideline NMR spectra from quadrupolar nuclei by frequency stepped WURST–QCPMG,
    Chem. Phys. Lett. 468, 330-335 (2009).
    Abstract
     
  6. Ivan Hung, Kiran Shetty, Paul D. Ellis, William W. Brey, and Zhehong Gan
    High-field QCPMG NMR of large quadrupolar patterns using resistive magnets,
    Solid State Nucl. Magn. Reson. 36, 159-163 (2009).
    Abstract
     
  7. C. M. Widdifield, R. P. Chapman, and D. L. Bryce
    Chlorine, bromine, and iodine solid-state NMR spectroscopy,
    Annu. Rep. Nucl. Magn. Reson. Spectrosc. 66, 195-326 (2009).
    Abstract
     
  8. R. P. Chapman, C. M. Widdifield, and D. L. Bryce
    Solid-state NMR of quadrupolar halogen nuclei,
    Prog. Nucl. Magn. Reson. Spectrosc. 55, 215-237 (2009).
    Abstract
     
  9. R. P. Chapman and D. L. Bryce
    Application of multinuclear magnetic resonance and gauge-including projector-augmented wave calculations to the study of solid group 13 chlorides,
    Phys. Chem. Chem. Phys. 11, 6987-6998 (2009).
    Abstract
     
  10. A. J. Rossini, R. W. Mills, G. A. Briscoe, E. L. Norton, S. J. Geier, I. Hung, S. Zheng, J. Autschbach, and R. W. Schurko
    Solid-state chlorine NMR of group IV transition metal organometallic complexes,
    J. Am. Chem. Soc. 131, 3317-3330 (2009).
    abstract
     
  11. H. Hamaed, J. M. Pawlowski, B. F. T. Cooper, R. Fu, S. H. Eichhorn, and R. W. Schurko
    Application of solid-state 35Cl NMR to the structural characterization of hydrochloride pharmaceuticals and their polymorphs,
    J. Am. Chem. Soc. 130, 11056-11065 (2008).
     
  12. R. Bhattacharyya and L. Frydman
    Quadrupolar nuclear magnetic resonance spectroscopy in solids using frequency-swept echoing pulses,
    J. Chem. Phys. 127, 194503/1-194503/8 (2007).
     
  13. R. P. Chapman and D. L. Bryce
    A high-field solid-state 35/37Cl NMR and quantum chemical investigation of the chlorine quadrupolar and chemical shift tensors in amino acid hydrochlorides,
    Phys. Chem. Chem. Phys. 9, 6219-6230 (2007).
     
  14. David L. Bryce and Elijah B. Bultz
    Alkaline earth chloride hydrates: Chlorine quadrupolar and chemical shift tensors by solid-state NMR spectroscopy and plane wave pseudopotential calculations,
    Chem. Eur. J. 13, 4786-4796 (2007).
    dbryce@uottawa.ca
     
  15. D. L. Bryce and G. D. Sward
    Chlorine-35/37 NMR spectroscopy of solid amino acid hydrochlorides: Refinement of hydrogen-bonded proton positions using experiment and theory,
    J. Phys. Chem. B 110, 26461-26470 (2006).
     
  16. D. L. Bryce, G. D. Sward, and S. Adiga
    Solid-state 35/37Cl NMR spectroscopy of hydrochloride salts of amino acids implicated in chloride ion transport channel selectivity: Opportunities at 900 MHz,
    J. Am. Chem. Soc. 128, 2121-2134 (2006).
    dbryce@uottawa.ca
     
  17. D. L. Bryce and G. D. Sward
    Solid-state NMR spectroscopy of the quadrupolar halogens: chlorine-35/37, bromine-79/81, and iodine-127,
    Magn. Reson. Chem. 44, 409-450 (2006).
    dbryce@uottawa.ca
     
  18. F. Barberon, V. Baroghel-Bouny, H. Zanni, B. Bresson, J.-B. d'Espinose de la Caillerie, L. Malosse, and Z. Gan
    Interactions between chloride and cement-paste materials,
    Magn. Reson. Imaging 23, 267-272 (2005).
    fabien.barberon@espci.fr
     
  19. H. Trill, H. Eckert, and V. I. Srdanov
    NMR study of interacting F centers in Na8[Al6Si6O24]Cl2 sodalite,
    Phys. Rev. B 71, 014412/1-014412/6 (2005).
     
  20. T. O. Sandland, L. S. Du, J. F. Stebbins, and J. D. Webster
    Structure of Cl-containing silicate and aluminosilicate glasses: A 35Cl MAS-NMR study,
    Geochim. Cosmochim. Acta 68, 5059-5069 (2004).
    stebbins@stanford.edu
     
  21. A. Taye and D. Michel
    Phason and amplitudon dynamics in the incommensurate phase of bis(4-chlorophenyl)sulphone,
    Phys. Rev. B 69, 224206/1-224206/7 (2004).
    taye@physik.uni-leipzig.de
     
  22. H. Honda
    Even-odd effect of 35Cl quadrupole coupling constants in solid n-alkylammonium chlorides (C5 - C10),
    Z. Naturforsch. 58a, 623-630 (2003).
    hhonda@yokohama-cu.ac.jp
     
  23. N. Sinyavsky, I. Korneva, and M. Mackowiak
    Determination of rotational angles from two-dimensional exchange NMR and NQR spectra of powder samples,
    J. Mol. Struct. 659, 43-51 (2003).
    mackow@ifmpan.poznan.pl
     
  24. T. Azas, C. Bonhomme, and M. E. Smith
    35Cl quadrupolar constants obtained by solid-state NMR: study of chlorinated Al-O-P clusters, involving OH…Cl hydrogen bonds,
    Solid State NMR 23, 14-27 (2003).
    bonhomme@ccr.jussieu.fr
     
  25. A. Taye and D. Michel
    35Cl nuclear magnetic resonance study in bis(4-chlorophenyl)sulphone [(ClC6H4)2SO2],
    phys. stat. sol. (b) 233, 519-529 (2002).
    michel@physik.uni-leipzig.de; taye@physik.uni-leipzig.de
     
  26. D. L. Bryce, M. Gee, and R. E. Wasylishen
    High-field chlorine NMR spectroscopy of solid organic hydrochloride salts: a sensitive probe of hydrogen bonding environment,
    J. Phys. Chem. A 105, 10413-10421 (2001).
    roderick.wasylishen@ualberta.ca
     
  27. J. Skibsted and H. J. Jakobsen
    35Cl and 37Cl magic-angle spinning NMR spectroscopy in the characterization of inorganic perchlorates,
    Inorg. Chem. 38, 1806-1813 (1999).
    hja@kemi.aau.dk
     
  28. J. P. Yesinowski, M. L. Buess, A. N. Garroway, M. Ziegeweid, and A. Pines
    Detection of 14N and 35Cl in cocaine base and hydrochloride using NQR, NMR, and SQUID techniques,
    Anal. Chem. 67, 2256-2263 (1995).
    Yesinows@nrlfsl.nrl.navy.mil
     
  29. T. L. Weeding and W. S. Veeman
    Characterisation of the structure of inorganic chloride salts with chlorine solid state NMR,
    J. Chem. Soc., Chem. Commun. 947-948 (1989).
     
  30. Th. Erge, D. Michel, J. Petersson, and W. Windsch
    35Cl NMR study in the paraelectric phase of tris-sarcosine calcium chloride,
    Phys. Stat. Sol. a 114, 705-712 (1989).
     

Related bibliography

  1. H. Kampermann, A. D. Bain, and R. S. Dumont
    Residual dipolar coupling in the CP/MAS nuclear magnetic resonance spectra of spin-1/2 nuclei coupled to quadrupolar nuclei application of floquet theory,
    J. Chem. Phys. 116, 2464-2471 (2002).
    bain@mcmaster.ca
     
  2. B. Thomas, S. Paasch, S. Steuernagel, and K. Eichele
    Residual 31P, 35,37Cl dipolar coupling in 31P MAS spectra of chlorocyclophosphazenes,
    Solid State NMR 20, 108-117 (2001).
     
  3. B. Nagasaka, S. Takeda, and N. Nakamura
    Residual dipolar splittings in 13C CP/MAS NMR spectra due to quadrupolar halogen nuclei in uracil halides,
    Chem. Phys. Lett. 222, 486-492 (1994).
     

More solid-state Cl-35/37 NMR references.


 

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